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Novel chemical catalytic and photocatalytic processes for the direct conversion of methane and CO2 to products

Grant number: 18/01258-5
Support Opportunities:Research Projects - Thematic Grants
Duration: November 01, 2018 - October 31, 2024
Field of knowledge:Engineering - Chemical Engineering - Chemical Process Industries
Principal Investigator:José Maria Correa Bueno
Grantee:José Maria Correa Bueno
Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
Pesquisadores principais:
Cauê Ribeiro de Oliveira ; Dalmo Mandelli ; Daniela Zanchet ; Leandro Pierroni Martins
Associated researchers:Adriana Paula Ferreira Palhares ; Alejandro López Castillo ; Alice Medeiros de Lima ; Cristiane Sanchez Farinas ; Diogo Paschoalini Volanti ; Elaine Cristina Paris ; Ernesto Antonio Urquieta Gonzalez ; Felipe Fernando Furlan ; Janaina Fernandes Gomes ; Jean Marcel Ribeiro Gallo ; Joao Batista Oliveira dos Santos ; José Manoel Marconcini ; Jose Mansur Assaf ; Luiz Henrique Capparelli Mattoso ; Maria Alice Martins ; Patrícia Moreira Lima ; Priscila Destro ; Waldir Avansi Junior
Associated grant(s):23/01634-5 - Metal-Organic Frameworks (MOFs) as catalysts for sustainable oxidation of hydrocarbons derived from petroleum (methane and other alkanes) and natural (terpenes), AP.R
19/12486-1 - Multi-User Equipment approved in grant 2018/01258-5: gas chromatograph, AP.EMU
19/03226-6 - Use of computational methods to understand the activation of methane and CO2 on the surface of copper-based catalysts: visit by Prof. David Willock for lecture, course, scientific meeting and estabilishing collaboration, AV.EXT
+ associated grants 19/00848-6 - Biorefineries and new pathways for the development of sustainable catalytic processes, AV.EXT
19/11507-5 - Multi-user equipament approved in grant 2018/01258-5: gas cromatograph, AP.EMU
19/09219-1 - Multi-User Equipment approved in grant 2018/01258-5: high pressure system, AP.EMU
19/06436-1 - Multi-User Equipment approved in grant 2018/01258-5: thermobalance, AP.EMU - associated grants
Associated scholarship(s):22/05381-1 - ZnO/NiO-type heterostructures derived from metal-organic frameworks for the detection of microbial volatile organic compounds, BP.DR
23/08424-6 - Development of photocatalytic routes for the reduction of CO2 in supercritical media., BP.DR
23/10329-1 - Production of value-added organic compounds (C2+) through the dry electrochemical reform of CH4 in supercritical CO2., BP.PD
+ associated scholarships 23/18451-0 - Development of a new process for direct methane oxidation to methanol using Cu-Zeolites catalysts, BP.PD
23/15042-2 - Exploiting metal-support interactions to tune the properties of iron oxide catalysts, BP.IC
23/11946-4 - Analysis of Safety in the Partial Oxidation of Methane to Methanol: Evaluation of Flammability with Different Oxidizing Agents, BP.IC
23/08875-8 - Metal-Organic Frameworks (MOFs) as heterogeneous catalysts towards oxygenated products by direct methane oxidation, BP.DD
22/07347-5 - STUDY OF REDOX REVERSIBILITY OF COPPER-BASED CATALYSTS FOR APPLICATION IN A PHOTO-THERMOCATALYTIC SYSTEM FOR "DAY-AND-NIGHT" CO2 HYDROGENATION., BP.DR
21/14904-5 - CO2 hydrogenation over nanoparticles obtained from post modification MOF's decomposition, BP.PD
22/12387-6 - Obtaining zeolites by combining dry gel and seed synthesis methods, BP.IC
22/09325-9 - Characterization of transition metal oxides targeting catalytic applications, BP.IC
22/05343-2 - Theoretical studies of zeolites with Cu and Fe, for the direct conversion of methane to products, BP.PD
21/09394-8 - Texture modification of Mo-V mixed oxides as catalysts for oxidation reactions: application in the oxidative dehydrogenation of propane to propene., BP.PD
22/03824-3 - Synthesis of nanostructured oxide supports using colloidal methods, BP.IC
21/09775-1 - New multifunctional metal-organic framework catalysts for mild oxidation of methane to methanol, BP.PD
21/10885-6 - Hybrid Metal Oxide Cluster@MOF catalysts: design, synthesis by atomic layer deposition, and catalytic methane oxidation, BP.DD
20/12986-1 - Design of nickel catalysts supported on 1D TiO2/Nb2O5 nanostructures, BP.DD
21/00622-8 - Production of carbon nanotubes by the catalytic decomposition of methane, BP.IC
20/08575-6 - Electronic modulation of Pt atomically dispersed on oxides aiming catalytic applications, BP.DD
20/15949-0 - Novel chemical catalytic and photocatalytic processes for the direct conversion of methane and CO2 to products, BP.TT
20/09628-6 - Development of heterostructured semiconducting nanoparticles for methane conversion by photocatalytic process, BP.PD
20/00691-7 - From single atom to supported nanoparticles catalysts: the use of metal complexes to produce a new class of catalysts for methane and CO2 conversion, BP.PD
19/21496-0 - Photoelectrochemical system design for CO2 and CH4 conversion to valuable products, BP.PD
20/05233-7 - Advanced composites based on semiconductor metal oxide and carbon structures for volatile organic compounds sensing, BP.DD
20/04021-6 - New catalytic and photocatalytic processes for the direct conversion of methane and CO2 into products, BP.TT
19/23205-3 - Theoretical study of the complex kinetics of catalytic processes, BP.DR
19/27018-3 - Pore engineering of zeolites as a strategy to improve the performance and minimize deactivation by coke in methanol reactions, BP.DD
19/27334-2 - Novel chemical catalytic processes for the direct conversion of methane and CO2 to products, BP.TT
19/12345-9 - ZnO sensors modified with Mn3O4 or In2O3 obtained by combining the ultrasonic spray and hydrothermal microwave assisted methods, BP.MS
19/11058-6 - Gas sensors based on carbon composites from the catalytic decomposition reaction of methane, BP.PD
19/17719-4 - Hybrid metal oxide cluster@MOF catalysts: design, synthesis by atomic layer deposition, and catalytic methane oxidation, BP.DD
19/10689-2 - Preparation of reaction systems for photocatalytic methane-to-methanol selective oxidation, BP.DD
19/12201-7 - Selected zeolite structures as supports for transition metal oxides for selective conversion of methane into value added chemicals, BP.PD
19/13170-8 - New Multifunctional Metal-Organic Framework Catalysts for Mild Oxidation of Methane to Methanol, BP.PD
19/06836-0 - Colloidal synthesis of AU alloys and performance in catalytic oxidation of CH4, BP.IC
19/09078-9 - Study of catalysts derived from chabazite for application in reactions of hydrogenation of CO2 to products, BP.IC
19/11800-4 - Synthesis of Ni catalysts from organometallic complexes for methane bireforming reaction, BP.DD
19/06427-2 - Novel chemical catalytic processes for the direct conversion of methane to products, BP.TT
19/02642-6 - Synthesis of nanostructured oxide supports using colloidal methods, BP.IC
18/26459-3 - Zeolites exchanged with CuxOy single sites for the methane partial oxidation to methanol: the effect of zeolite structure and other metal oxides in the single site activity, BP.DD
16/21515-7 - Development of magnesium oxide with zinc and titanium heterostructure for application in artificial photosynthesis processes, BP.PD
15/12304-0 - Evaluation of the photocatalytic activity of g-C3N4/Nb2O5 heterojunctions in the abatement of pollutants in gas phase, BP.PD - associated scholarships

Abstract

In 20 years we are expected to reach the Natural Gas Golden Age, when methane will play a leading role as primary industrial feedstock. Hence, this proposal aims to develop fundamental and applied knowledge for the catalytic conversion of CH4 by oxidative routes, as well as the utilization of CO2 a greenhouse gas present in natural gas (and also by product of methane reforming). It is proposed a coordinated and integrated between groups acting in various Research Line (RL): the group of chemical catalysis (RL-1) and photocatalysis (RL-2) aiming to address the significant challenges in the CH4 partial oxidation to methanol. RL-1 involves design, preparation and characterization of Cu and Fe-based structured catalysts, construction of reactors, and catalytic tests. In RL-1, the promising catalysts will be described with DFT calculations for modeling of catalysts active sites and interaction of reactants. The RL-2 will develop photocatalysts based on TiO2, g-C3N4, ZnO, BiVO4, and BiWO3. The catalytic activity will be studies seeking the development of experimental setups to analyze the controlling ability of these oxidation reactions in laboratory and pilot scales. Alternatively, to methanol, in RL-3, methane will be used as a feedstock to the production of carbon-based materials, which will be modified aiming to achieve adequate properties for applications. As it regards to the CO2 utilization, RL-4 will be studying the methane bi-reforming of a mixture of CH4 and CO2 into syngas (CO + H2). The RL-5 will focus on the hydrogenation of CO2 into methanol. Techno-economic analysis and environmental assessment will also be applied in the studies of RL-1, RL-4 and RL-5. (AU)

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Scientific publications (92)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DE MENDONCA, VAGNER R.; LOPES, OSMANDO F.; AVANSI JR, WALDIR; ARENAL, RAUL; RIBEIRO, CAUE. Insights into formation of anatase TiO2 nanoparticles from peroxo titanium complex degradation under microwave-assisted hydrothermal treatment. CERAMICS INTERNATIONAL, v. 45, n. 17, B, p. 22998-23006, . (18/01258-5, 15/14330-8)
GENTIL, TUANI C.; PINHEIRO, VICTOR S.; SOUZA, FELIPE M.; DE ARAUJO, MARCOS L.; MANDELLI, DALMO; BATISTA, BRUNO L.; DOS SANTOS, MAURO C.. Acetol as a high-performance molecule for oxidation in alkaline direct liquid fuel cell. RENEWABLE ENERGY, v. 165, n. 1, p. 37-42, . (17/22976-0, 17/21846-6, 15/10314-8, 18/18675-8, 18/01258-5, 17/10118-0, 17/26288-1)
ROCHA, KLEPER DE O.; MACEDO, WAGNER C.; MARQUES, CLELIA M. P.; BUENO, JOSE M. C.. Pt/Al2O3La2O3 catalysts stable at high temperature in air, prepared using a ``one-pot{''} sol-gel process: Synthesis, characterization, and catalytic activity in the partial oxidation of CH4. Chemical Engineering Science, v. 229, . (18/01258-5)
FINGER, PEDRO H.; OSMARI, TAYNARA A.; COSTA, MATHEUS S.; BUENO, JOSE MARIA C.; GALLO, JEAN MARCEL R.. The role of the interface between Cu and metal oxides in the ethanol dehydrogenation. APPLIED CATALYSIS A-GENERAL, v. 589, . (17/11027-8, 16/02128-2, 18/01258-5)
VIEIRA, LUIZ H.; POSSATO, LUIZ G.; CHAVES, THIAGO F.; LEE, JASON J.; SULMONETTI, TAYLOR P.; JONES, CHRISTOPHER W.; MARTINS, LEANDRO. Insights into Redox Dynamics of Vanadium Species Impregnated in Layered Siliceous Zeolitic Structures during Methanol Oxidation Reactions. CHEMCATCHEM, v. 12, n. 1, p. 141-151, . (18/01258-5, 17/00860-0, 14/20116-6)
PERFECTO, TARCISIO M.; ZITO, CECILIA A.; VOLANTI, DIOGO P.. Effect of NiS nanosheets on the butanone sensing performance of ZnO hollow spheres under humidity conditions. SENSORS AND ACTUATORS B-CHEMICAL, v. 334, . (20/06421-1, 16/25267-8, 18/01258-5, 18/00033-0, 17/01267-1)
VIEIRA, LUIZ H.; LOPEZ-CASTILLO, ALEJANDRO; JONES, CHRISTOPHER W.; MARTINS, LEANDRO. Exploring the multifunctionality and accessibility of vanadosilicates to produce acrylic acid in one-pot glycerol oxydehydration. APPLIED CATALYSIS A-GENERAL, v. 602, . (18/01258-5, 17/00860-0, 19/12501-0, 19/17156-0, 14/20116-6)
FERNANDES, LUCIANA SARMENTO; MANDELLI, DALMO; CARVALHO, WAGNER A.; CAYTAN, ELSA; FISCHMEISTER, CEDRIC; BRUNEAU, CHRISTIAN. Cross metathesis of (-)-beta-pinene, (-)-limonene and terpenoids derived from limonene with internal olefins. APPLIED CATALYSIS A-GENERAL, v. 623, . (17/24931-4, 16/05006-5, 15/26787-2, 19/18981-4, 18/01258-5)
SILVA, LAURA L.; STELLATO, MICHAEL J.; RODRIGUES, MARIANA V.; HARE, BRYAN J.; KENVIN, JEFFREY C.; BOMMARIUS, ANDREAS S.; MARTINS, LEANDRO; SIEVERS, CARSTEN. Reduced deactivation of mechanochemically delaminated hierarchical zeolite MCM-22 catalysts during 4-propylphenol cracking. JOURNAL OF CATALYSIS, v. 411, p. 6-pg., . (17/21965-5, 18/20670-4, 18/01258-5)
KOMATSU, JENNY S.; SOUZA, FELIPE M.; PINHEIRO, VICTOR S.; BOHNSTEDT, PAULA; DE PAPE, POL W. G.; MANDELLI, DALMO; SANTOS, MAURO C.; CARVALHO, WAGNER A.. Cotton fabric derived alpha Fe magnetic porous carbon as electrocatalyst for alkaline direct ethanol fuel cell. CATALYSIS TODAY, v. 381, p. 65-75, . (17/22976-0, 15/10314-8, 17/10118-0, 18/01258-5, 18/26307-9, 17/26288-1, 17/24931-4, 17/21846-6)
ARAUJO, MARCOS LOPES; CORREIA, GILVAN AGUIAR; CARVALHO, WAGNER ALVES; SHUL'PINA, LIDIA SERGEEVNA; KOZLOV, YURIY NIKITOVICH; SHUL'PIN, GEORGIY BORISOVICH; MANDELLI, DALMO. The effect of additives (pyrazine, pyrazole and their derivatives) in the oxidation of 2-butanol with FeCl3-H2O2 in aqueous solutions. CATALYSIS TODAY, v. 381, p. 163-170, . (17/24931-4, 18/01258-5)
VIOTO, GABRIEL C. N.; PERFECTO, TARCISIO M.; ZITO, CECILIA A.; VOLANTI, DIOGO P.. Enhancement of 2-butanone sensing properties of SiO2@CoO core-shell structures. CERAMICS INTERNATIONAL, v. 46, n. 14, p. 22692-22698, . (17/01267-1, 18/01258-5, 18/00033-0, 16/25267-8, 17/13230-5, 18/08271-7)
DE ARAUJO, MARCOS LOPES; CORREIA, GILVAN AGUIAR; CARVALHO, WAGNER ALVES; SHUL'PINA, LIDIA SERGEEVNA; KOZLOV, YURIY NIKITOVICH; SHUL'PINA, GEORGIY BORISOVICH; MANDELLI, DALMO. Transformation of biomass derivatives in aqueous medium: Oxidation of ethanol from sugarcane and acetol from biodiesel glycerol catalyzed by Fe-3(+)- H2O2. MOLECULAR CATALYSIS, v. 500, . (17/24931-4, 18/01258-5)
POSSATO, LUIZ G.; GONCALVES, ROSEMBERGUE G. L.; SANTOS, RODRIGO M. M.; CHAVES, THIAGO F.; BRIOIS, VALERIE; PULCINELLI, SANDRA H.; MARTINS, LEANDRO; SANTILLI, V, CELSO. Sol-gel synthesis of nanocrystalline MgO and its application as support in Ni/MgO catalysts for ethanol steam reforming. Applied Surface Science, v. 542, . (14/11952-5, 16/12752-5, 18/01258-5)
GU, JINZHONG; WAN, SHIMAO; CHENG, XIAOYAN; KIRILLOVA, V, MARINA; KIRILLOV, ALEXANDER M.. Coordination Polymers from 2-Chloroterephthalate Linkers: Synthesis, Structural Diversity, and Catalytic CO2 Fixation. Crystal Growth & Design, v. 21, n. 5, p. 2876-2888, . (18/01258-5)
ZAPELINI, IAGO WILLIAM; CARDOSO, DILSON. Amine-grafted Na-LTA zeolite precursors as basic catalysts for Knoevenagel condensation. Microporous and Mesoporous Materials, v. 324, . (18/01258-5, 18/21136-1)
M. DAWSON; C. RIBEIRO; M. R. MORELLI. A Review of Three-Dimensional Tin Halide Perovskites as Solar Cell Materials. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 25, . (18/01258-5)
FERNANDO B. F. SILVA; GELSON T. S. T. DA SILVA; JULIANA A. TORRES; CAUE RIBEIRO. Tuning the Photocatalytic Activity of Tin Oxide through Mechanical Surface Activation. Journal of the Brazilian Chemical Society, v. 33, n. 7, p. 725-733, . (18/01258-5)
GABRIEL K. MACEDO; EDUARDO HENRIQUE DIAS; CAUE RIBEIRO; OSMANDO F. LOPES. Development of Bismuth Oxyhalides for Organic Pollutant Photodegradation and Water Oxidation: Effect of Synthesis Parameter and Halide Species. Journal of the Brazilian Chemical Society, v. 33, n. 8, p. 948-957, . (18/01258-5, 19/10689-2)
BONON, ANDERSON J.; BAHU, JULIANA O.; KLEIN, BRUNO C.; MANDELLI, DALMO; MACIEL FILHO, RUBENS. Green production of limonene diepoxide for potential biomedical applications. CATALYSIS TODAY, v. 388-389, p. 13-pg., . (09/16480-6, 18/01258-5)
ROMERO T. BUENO; OSMANDO F. LOPES; KELE T. G. CARVALHO; CAUE RIBEIRO; HENRIQUE A. J. L. MOURÃO. Semicondutores heteroestruturados: uma abordagem sobre os principais desafios para a obtenção e aplicação em processos fotoquímicos ambientais e energéticos. Química Nova, v. 42, n. 6, p. 661-675, . (15/14330-8, 18/01258-5, 16/09746-3, 15/12304-0, 18/04558-0, 13/13888-0)
SOARES, FERNANDO C.; ALMEIDA, JESSICA C. DE; KOGA, RAFAELLA H.; DUQUE, DOUGLAS M. DA SILVA DEL; SILVA, GELSON T. S. T. DA; RIBEIRO, CAUE; MENDONCA, VAGNER R. DE. TiO2/BiVO4 composite from preformed nanoparticles for heterogeneous photocatalysis. Materials Chemistry and Physics, v. 290, p. 10-pg., . (18/01258-5)
BIANCA R. FLORINDO; GABRIEL L. CATUZO; LEANDRO MARTINS. Porosity of CHA Zeolite Driving the Formation of Polyaromatic Coke Species in the Methanol to Olefins Reaction. Journal of the Brazilian Chemical Society, v. 32, n. 5, p. 1051-1059, . (18/01258-5, 19/09078-9)
VIOTO, GABRIEL C. N.; PERFECTO, TARCISIO M.; ZITO, CECILIA A.; VOLANTI, DIOGO P.. Flower-like NiO for the detection of 3-methyl-1-butanol, a microbial volatile organic compound. Materials Letters, v. 333, p. 4-pg., . (20/06421-1, 18/00033-0, 18/01258-5)
PERRONE, OLAVO M.; ROVEDA JR, ANTONIO C.; DE MORAES, DANIEL A.; VOLANTI, DIOGO P.. The enhanced n-butanol sensing performance of In2O3 loaded NiO cuboid heterostructure. Journal of Alloys and Compounds, v. 930, p. 8-pg., . (19/11058-6, 20/06421-1, 18/01258-5)
LEITE, DAVI S.; STRAPASSON, GUILHERME B.; ZANCHET, DANIELA. Unveiling the effect of metallic and oxidized phases of cobalt on acetone hydrodeoxygenation. MOLECULAR CATALYSIS, v. 530, p. 9-pg., . (20/12986-1, 18/01258-5)
ANDRADE, LUANA S.; LIMA, HERICH H. L. B.; SILVA, CLEISER T. P.; AMORIM, WANDSON L. N.; POCO, JOAO G. R.; LOPEZ-CASTILLO, ALEJANDRO; KIRILLOVA, MARINA, V; CARVALHO, WAGNER A.; KIRILLOV, ALEXANDER M.; MANDELLI, DALMO. Metal-organic frameworks as catalysts and biocatalysts for methane oxidation: The current state of the art. Coordination Chemistry Reviews, v. 481, p. 23-pg., . (18/01258-5, 21/12342-0, 21/09775-1, 19/12501-0)
DAWSON, MARGARET; RIBEIRO, CAUE; MORELLI, MARCIO RAYMUNDO. Synthesis and characterization of tin halide perovskites based on different tin(II) precursors. Materials Letters, v. 308, n. B, . (18/01258-5)
ZITO, CECILIA A.; PERFECTO, TARCIISIO M.; VOLANTI, DIOGO P.. Room-Temperature Triethylamine Sensor Based on Reduced Graphene Oxide/CeO2 Nanocomposites. ACS APPLIED NANO MATERIALS, v. 6, n. 10, p. 9-pg., . (18/00033-0, 16/25267-8, 17/01267-1, 18/01258-5, 18/08271-7)
SILVA, LAURA L.; FLORINDO, BIANCA R.; CATUZO, GABRIEL L.; ZAPELINI, IAGO W.; CRADSO, JOAS VICTOR. S.; LUNA, F. MURILO T. .; CAVALCANTE JR., CELIO L.; MARTINS, LEANDRO. Investigation of the secondary porosity in ill-crystallized or desilicated ZSM-5 zeolites and its performance on MTH reaction. MOLECULAR CATALYSIS, v. 529, p. 10-pg., . (18/20670-4, 17/21965-5, 19/12486-1, 19/09078-9, 18/01258-5, 18/21136-1)
POSSATO, LUIZ G.; PULCINELLI, SANDRA H.; MARTINS, LEANDRO; BRIOIS, VALERIE; SANTILLI, CELSO, V. Appraisal of Ni Species Supported on Porous MgO during Ethanol Steam Reforming by XAS. CHEMCATCHEM, v. 14, n. 21, p. 15-pg., . (19/12486-1, 14/11952-5, 18/01258-5, 16/12752-5)
GENTIL, TUANI C.; PINHEIRO, VICTOR S.; SOUZA, FELIPE M.; DE ARAUJO, MARCOS L.; MANDELLI, DALMO; BATISTA, BRUNO L.; DOS SANTOS, MAURO C.. Acetol as a high-performance molecule for oxidation in alkaline direct liquid fuel cell. RENEWABLE ENERGY, v. 165, p. 6-pg., . (17/21846-6, 17/22976-0, 15/10314-8, 17/10118-0, 18/18675-8, 17/26288-1, 18/01258-5)
SA, BRUNA S.; ZITO, CECILIA A.; PERFECTO, TARCISIO M.; VOLANTI, DIOGO P.. Porous ZnSnO3 nanocubes as a triethylamine sensor. SENSORS AND ACTUATORS B-CHEMICAL, v. 338, p. 10-pg., . (18/00033-0, 16/25267-8, 17/01267-1, 18/01258-5, 20/05233-7, 20/06421-1)
VIEIRA, JOSE LUCAS; PAUL, GEO; IGA, GUSTAVO D.; CABRAL, NATALIA M.; BUENO, JOSE MARIA C.; BISIO, CHIARA; GALLO, JEAN MARCEL R.. Niobium phosphates as bifunctional catalysts for the conversion of biomass-derived monosaccharides. APPLIED CATALYSIS A-GENERAL, v. 617, p. 11-pg., . (20/15949-0, 19/02132-8, 16/02128-2, 18/01258-5, 20/04109-0)
BORGES, ROGER; KLAIC, RODRIGO; FARINAS, CRISTIANE SANCHEZ; RIBEIRO, CAUE. Biological treatment of asbestos cement wastes by Aspergillus niger and Acidithiobacillus thiooxidans. APPLIED CLAY SCIENCE, v. 216, p. 10-pg., . (18/01258-5)
LIMA, DIEGO S. D.; SILVA, LAURA L. L.; ZAPELINI, IAGO W. W.; MINTOVA, SVETLANA; MARTINS, LEANDRO. Tailoring the accessibility and amphiphilicity of MWW zeolites for two-phase glycerol ketalization. INORGANIC CHEMISTRY FRONTIERS, v. 10, n. 19, p. 13-pg., . (17/21965-5, 22/01789-6, 21/08326-9, 18/01258-5, 19/12486-1)
MARINS, NATALIA HADLER; PEREIRA, ELEN MARIA FELICIANO; ALAHAKOON, SANDAMINI H.; HUANG, YINING; MARTINS, LEANDRO. Hierarchical chabazites synthesized by combining primary and secondary structure-directing agents. Microporous and Mesoporous Materials, v. 346, p. 10-pg., . (19/12201-7, 18/01258-5, 20/07265-3, 19/12486-1)
WANG, YANJIE; TORRES, JULIANA A.; SHVIRO, MEITAL; CARMO, MARCELO; HE, TAO; RIBEIRO, CAUE. Photocatalytic materials applications for sustainable agriculture. PROGRESS IN MATERIALS SCIENCE, v. 130, p. 115-pg., . (17/11937-4, 18/01258-5, 16/21515-7)
FIUZA, TANNA E. R.; SOUSA, LEONARDO S.; ZANCHET, DANIELA. Bare and Pt-loaded LaCo1-xFexO3 perovskites as catalysts for CO-PROX reaction. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 48, n. 64, p. 15-pg., . (18/01258-5, 20/08575-6)
A. RODRIGUES, THAIS; FALSETTI, PAULO H. E.; DEL DUQUE, DOUGLAS M. S.; DA SILVA, GELSON T. S. T.; F. LOPES, OSMANDO; AVANSI, WALDIR; RIBEIRO, CAUE; R. DE MENDONCA, VAGNER. A Versatile Nb2O5/SnO2 Heterostructure for Different Environmental Purposes: Water Treatment and Artificial Photosynthesis. CHEMCATCHEM, v. 13, n. 2, . (17/17553-3, 18/01258-5)
DAWSON, MARGARET; RIBEIRO, CAUE; MORELLI, MARCIO RAYMUNDO. MnCl2 doping increases phase stability of tin halide perovskites. MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, v. 132, . (18/01258-5)
DE SOUZA FILHO, JOSE CANDIDO; LOPEZ-CASTILLO, ALEJANDRO. The role of the diffusion process in bimolecular reactions with neighborhood. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, v. 53, n. 4, . (19/12501-0, 18/01258-5)
FERNANDES, LUCIANA SARMENTO; MANDELLI, DALMO; CARVALHO, WAGNER A.; FISCHMEISTER, CEDRIC; BRUNEAU, CHRISTIAN. Functionalization of (-)-beta-pinene and (-)-limonene via cross metathesis with symmetrical internal olefins. Catalysis Communications, v. 135, . (15/26787-2, 18/01258-5)
PRADO, A. C. F.; MALAFATTI, J. O. D.; OLIVEIRA, J. A.; RIBEIRO, C.; JOYA, M. R.; LUZ, A. P.; PARIS, E. C.. Preparation and Application of Nb2O5 Nanofibers in CO2 Photoconversion. NANOMATERIALS, v. 11, n. 12, . (18/01258-5, 19/21496-0)
RIBEIRO, LUCAS S.; PINATTI, IVO M.; TORRES, JULIANA A.; GIROTO, AMANDA S.; LESSE, FABIANA; LONGO, ELSON; RIBEIRO, CAUE; NOGUEIRA, ANDRE E.. Rapid microwave-assisted hydrothermal synthesis of CuBi2O4 and its application for the artificial photosynthesis. Materials Letters, v. 275, . (16/21515-7, 18/10104-1, 18/01258-5, 19/03722-3, 13/07296-2, 18/12871-0)
OLIVEIRA, JESSICA A. A.; SILVA, ROBERTA R. M. A.; DA SILVA, GELSON T. S. T.; TORRES, JULIANA A.; VALI, ABBAS; RIBEIRO, CAUE; RAJESHWAR, KRISHNAN; RUOTOLO, LUIS A. M.. Copper vanadates: Targeted synthesis of two pure phases and use in a photoanode/cathode setup for selective photoelectrochemical conversion of carbon dioxide to liquid fuel. Materials Research Bulletin, v. 149, p. 10-pg., . (16/21515-7, 20/12706-9, 19/21496-0, 18/01258-5)
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TORRES, JULIANA. A. A.; NOGUEIRA, ANDRE E.; DA SILVA, GELSON T. S. T.; RIBEIRO, CAUE. The Effect of SnO2 Surface Properties on CO2 Photoreduction to Higher Hydrocarbons. CHEMCATCHEM, v. 15, n. 6, p. 9-pg., . (18/01258-5, 16/21515-7, 20/15230-5)
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RODRIGUES FIUZA, TANNA ELYN; GONCALVES, DANIELLE SANTOS; ZANCHET, DANIELA. The Impact of Ceria Loading on the CuOx-CeO2 Interaction and Performance of AuCu/CeO2-SiO2 Catalysts in CO-PROX Reaction. European Journal of Inorganic Chemistry, v. 2021, n. 40, . (18/01258-5, 11/50727-9)
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TORRES, JULIANA ARRIEL; DA SILVA, GELSON T. S. T.; BARBOSA DE FREITAS SILVA, FERNANDO; RIBEIRO, CAUE. Experimental Evidence of CO(2)Photoreduction Activity of SnO(2)Nanoparticles. ChemPhysChem, v. 21, n. 21, p. 5-pg., . (18/01258-5, 16/21515-7)
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DE MENDONCA, VAGNER R.; LOPES, OSMANDO F.; AVANSI JR, WALDIR; ARENAL, RAUL; RIBEIRO, CAUE. Insights into formation of anatase TiO2 nanoparticles from peroxo titanium complex degradation under microwave-assisted hydrothermal treatment. CERAMICS INTERNATIONAL, v. 45, n. 17, p. 9-pg., . (18/01258-5, 15/14330-8)
OLIVEIRA, TAIS N. T.; ZITO, CECILIA A.; PERFECTO, TARCISIO M.; AZEVEDO, GUSTAVO M.; VOLANTI, DIOGO P.. ZnO twin-rods decorated with Pt nanoparticles for butanone detection. NEW JOURNAL OF CHEMISTRY, v. 44, n. 36, p. 10-pg., . (19/12345-9, 18/00033-0, 16/25267-8, 16/22219-2, 17/01267-1, 18/01258-5, 13/23886-4)
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DELGADO-ARCANO, YAIME; MANDELLI, DALMO; CARVALHO, WAGNER ALVES; MAGALHAES PONTES, LUIZ ANTONIO. Valorization of Corncob by Hydrolysis-Hydrogenation to Obtain Xylitol Under Mild Conditions. WASTE AND BIOMASS VALORIZATION, v. 12, n. 9, SI, p. 5109-5120, . (18/01258-5, 17/24931-4)
OLIVEIRA, TAIS N. T.; PERFECTO, TARCISIO M.; ZITO, CECILIA A.; VOLANTI, DIOGO P.. Improved triethylamine sensing properties by designing an In2O3/ ZnO heterojunction. SENSORS AND ACTUATORS REPORTS, v. 3, . (16/25267-8, 18/00033-0, 18/01258-5, 19/12345-9, 20/06421-1, 17/01267-1)
SANTOS, RODRIGO M. M.; BRIOIS, VALERIE; MARTINS, LEANDRO; SANTILLI, V, CELSO. Insights into the Preparation of Copper Catalysts Supported on Layered Double Hydroxide Derived Mixed Oxides for Ethanol Dehydrogenation. ACS APPLIED MATERIALS & INTERFACES, v. 13, n. 22, p. 26001-26012, . (18/01258-5, 17/13821-3, 15/23410-5)
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GALHARDO, THALITA S.; UENO, ANDERSON K.; COSTA-SILVA, THAIS A.; TEMPONE, ANDRE G.; CARVALHO, WAGNER A.; FISCHMEISTER, CEDRIC; BRUNEAU, CHRISTIAN; MANDELLI, DALMO; LAGO, JOAO HENRIQUE G.. New derivatives from dehydrodieugenol B and its methyl ether displayed high anti-Trypanosoma cruzi activity and cause depolarization of the plasma membrane and collapse the mitochondrial membrane potential. Chemico-Biological Interactions, v. 366, p. 6-pg., . (18/01258-5, 18/10279-6, 21/02789-7, 21/04464-8, 17/17044-1, 16/05006-5, 18/07885-1)
GALVANI, GIOVANA M.; ZITO, CECILIA A.; PERFECTO, TARCISIO M.; MALAFATTI, JOAO OTAVIO D.; PARIS, ELAINE C.; VOLANTI, DIOGO P.. Two-dimensional NiO nanosheets for efficient Congo red adsorption removal. Materials Chemistry and Physics, v. 290, p. 11-pg., . (18/01258-5, 20/06421-1, 18/00033-0, 17/01267-1, 16/25267-8)
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LUIZON FILHO, ROBERTO A.; POSSATO, LUIZ G.; SANTISTEBAN, OSCAR A. N.; DE VASCONCELLOS, ADRIANO; DA SILVA, DANILO A.; LIMA, MARCELO F.; MARTINS, LEANDRO; NERY, JOSE G.. Synthesis and characterization of chromium silicate catalyst and its application in the gas phase glycerol transformation into acetaldehyde. Inorganic Chemistry Communications, v. 112, . (18/01258-5, 11/51851-5, 18/17588-4)
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DE LIMA, HUGO H. C.; DA SILVA, CLEISER T. P.; KUPFER, VICENTE L.; RINALDI, JAQUELINE DE C.; KIOSHIMA, ERIKA S.; MANDELLI, DALMO; GUILHERME, MARCOS R.; RINALDI, ANDRELSON W.. Synthesis of resilient hybrid hydrogels using UiO-66 MOFs and alginate (hydroMOFs) and their effect on mechanical and matter transport properties. Carbohydrate Polymers, v. 251, . (18/01258-5, 19/13170-8)
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DA SILVA, JULIANA FLORIANO; DA SILVA FERRACINE, EDILENE DEISE; CARDOSO, DILSON. mproved accessibility of Na-LTA zeolite catalytic sites for the Knoevenagel condensation reactio. Microporous and Mesoporous Materials, v. 331, . (18/01258-5)
VIEIRA, JOSE LUCAS; DESTRO, PRISCILA; LAIER, LETICIA O.; MARQUES, CLELIA M. P.; GALLO, JEAN MARCEL R.; BUENO, JOSE MARIA C.. MgO/SiO2 prepared by wet-kneading as a catalyst for ethanol conversion to 1,3-butadiene: Prins condensation as the predominant mechanism. MOLECULAR CATALYSIS, v. 532, p. 9-pg., . (16/02128-2, 17/04058-4, 20/04109-0, 18/01258-5)

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PROCESSO PARA CONVERSÃO DIRETA DE METANO A METANOL LIVRE DE OXIGÊNIO MOLECULAR EM BAIXAS TEMPERATURAS BR1020210223162 - Fundação Universidade Federal de São Carlos (UFSCar) ; Universidade Estadual Paulista Júlio de Mesquita Filho (Unesp) . JOSE MARIA CORREA BUENO (UFSCar) ; TÁSSIA CAROLINE PASSOS PEREIRA (UFSCar) ; JUSSARA VITÓRIA REIS (UFSCar) ; STEFANIE CAROLINE MAYUMI MIZUNO (UFSCar) ; JOÃO BATISTA OLIVEIRA DOS SANTOS (UFSCar) ; JEAN MARCEL RIBEIRO GALLO (UFSCar) ; ALEJANDRO LOPEZ CASTILLO (UFSCar) ; LEANDRO MARTINS (UNESP) ; ERNESTO ANTONIO URQUIETA GONZÁLEZ (UFSCar) ; SIRIWAN DULNEE (UFSCar) ; RICARDO JOSÉ PASSINI (UFSCar) ; ELEN MARIA FELICIANO PEREIRA (UNESP) ; MONIZE PICININI (UFSCar) e PATRÍCIA MOREIRA LIMA (UFSCar). - August 2021, 11