DEVELOPMENT OF MULTIFUNCTIONAL NANOESTRUCTURED GREEN COMPOSITES BASED ON POLY(FURFURYL ALCOHOL)/GRAFITE NANOSHEETS FOR AEROSPACE APPLICATIONS

• Grant number: 18/09531-2
• Support Opportunities: Regular Research Grants
• Start date: November 01, 2018
• End date: October 31, 2020
• Field of knowledge: Engineering - Aerospace Engineering
• Principal Investigator: Mirabel Cerqueira Rezende
• Grantee: Mirabel Cerqueira Rezende
• Host Institution: Instituto de Ciência e Tecnologia (ICT). Universidade Federal de São Paulo (UNIFESP). Campus São José dos Campos. São José dos Campos , SP, Brazil
• Associated researchers: Ana Paula Lemes ; Fabio Roberto Passador ; Larissa Stieven Montagna

Abstract

The multifunctional green nanostructured composites aim the development of new technologies, from the use of products of less environmental impact, from renewable sources and environmentally correct. In this way, the development of so-called "green materials" implies preparation methodologies, containing renewable raw materials and/or chemical processes with reduced environmental impact, which result in products using clean and sustainable technology. Nowadays, it is verified that agroindustry generates innumerable biomass sources, which are often rejected by the industrial sector. However, these could be harnessed and transformed into the raw material of other products. Sugarcane bagasse, which is a by-product of agroindustry, has already been used in the production of furfuryl bioresine, also known as poly(furfuryl alcohol) (PFA). In this context, this study aims to obtain green nanocomposites, derived from renewable sources, with excellent thermal, mechanical, electrical and morphological properties. The achievement of the green nanocomposites proposed in this project aims to add benefits in the manufacture and application of artifacts that make up the interior of aircraft, with the advantage of being from a renewable source, with lower cost of production, besides being environmentally correct. The nanocomposites will be obtained by mixing in aqueous solution of p-toluenesulfonic acid (APTS) followed by ultrasonic tip ultrasound. The investigations will be carried out with the following methodologies: thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), tensile, flexural and impact tests, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and four-point electrical conductivity meter. (AU)

Scientific publications

(28)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DE SOUZA VIEIRA, LEONARDO; MONTAGNA, LARISSA STIEVEN; MARINI, JULIANO; PASSADOR, FABIO ROBERTO. Influence of particle size and glassy carbon content on the thermal, mechanical, and electrical properties ofPHBV/glassy carbon composites. Journal of Applied Polymer Science, AUG 2020. (18/09531-2)

ROJAS, JEFERSSON ALEXANDER; DE PAULA SANTOS, LUIS FELIPE; BOTELHO, EDSON COCCHIERI; RIBEIRO, BRUNO; REZENDE, MIRABEL CERQUEIRA. Morphological, mechanical, and electromagnetic interference shielding effectiveness characteristics of glass fiber/epoxy resin/MWCNT buckypaper composites. Journal of Applied Polymer Science, v. 138, n. 25, FEB 2021. (17/16970-0, 18/07867-3, 18/09531-2, 17/04740-0)

SILVEIRA, DANIEL C.; GOMES, NEWTON A. S.; REZENDE, MIRABEL C.; BOTELHO, EDSON C.. Microwave absorbing properties of glass fiber/epoxy resin composites tailored with frequency selective surface based on nonwoven of carbon fibers metalized with nickel. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 31, n. 16, JUL 2020. (18/09531-2)

ZANETINE MARQUES, THAIS PERES; MAYER, SERGIO; CANDIDO, GERALDO MAURICIO; REZENDE, MIRABEL CERQUEIRA. Fractographic analysis of scarf repaired carbon/epoxy laminates submitted to tensile strength. ENGINEERING FAILURE ANALYSIS, v. 124, JUN 2021. (18/09531-2)

RIBEIRO, BRUNO; SANTOS GOMES, NEWTON ADRIANO; REZENDE, MIRABEL CERQUEIRA. Lightweight multi-walled carbon nanotube buckypaper/glass fiber-epoxy composites for strong electromagnetic interference shielding and efficient microwave absorption. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 32, n. 11, p. 14494-14508, JUN 2021. (18/09531-2, 17/04740-0)

OLIVEIRA, TAILA S.; BRAZIL, TAYRA R.; GUERRINI, LILIA M.; REZENDE, MIRABEL C.; OLIVEIRA, MAURICIO P.. Synthesis and characterization of poly (acrylonitrile-g-lignin) by semi-batch solution polymerization and evaluation of their potential application as carbon materials. JOURNAL OF POLYMER RESEARCH, v. 27, n. 11, OCT 23 2020. (18/09531-2, 14/23766-1, 13/25619-3)

ROJAS, J. A.; RIBEIRO, B.; REZENDE, M. C.. Influence of serrated edge and rectangular strips of MWCNT buckypaper on the electromagnetic properties of glass fiber/epoxy resin composites. Carbon, v. 160, p. 317-327, APR 30 2020. (17/04740-0, 18/09531-2)

FRANZOL, A.; BANIN, T. M.; BRAZIL, T. R.; REZENDE, M. C.. Assessment of kinetic stability of cosmetic emulsions formulated with different emulsifiers using rheological and sensory analyses. Journal of Sol-Gel Science and Technology, v. 99, n. 3, AUG 2021. (18/09531-2)

RIBEIRO, BRUNO; ROJAS CORREDOR, JEFERSSON ALEXANDER; COSTA, MICHELLE LEALI; BOTELHO, EDSON COCCHIERI; REZENDE, MIRABEL CERQUEIRA. Multifunctional Characteristics of Glass Fiber-Reinforced Epoxy Polymer Composites with Multiwalled Carbon Nanotube Buckypaper Interlayer. POLYMER ENGINEERING AND SCIENCE, v. 60, n. 4, p. 740-751, APR 2020. (17/16970-0, 17/04740-0, 18/09531-2)

BARROS, ANDRE SANTIAGO; VIEIRA, LEONARDO DE SOUZA; DE MELO MORGADO, GUILHERME FERREIRA; RIBEIRO DOS ANJOS, ERICK GABRIEL; MONTEIRO DE SOUZA, GABRIEL PORTILHO; ROMEU LINO DE SOUZA, MARIA FERNANDA; WEARN, YVES NICOLAU; BRAGA DE NARDI, ANTONIO LUIS; RIBEIRO COIMBRA, MARIA CLAUDIA; DE MOURA, NAYARA KOBA; et al. Influence of out-of-plane fiber waviness and different environmental conditionings on mechanical and morphological characteristics of fiber glass/epoxy laminates. JOURNAL OF COMPOSITE MATERIALS, v. 56, n. 3, NOV 2021. (18/09531-2)

DE SOUZA VIEIRA, LEONARDO; MONTAGNA, LARISSA STIEVEN; MARINI, JULIANO; PASSADOR, FABIO ROBERTO. Influence of particle size and glassy carbon content on the thermal, mechanical, and electrical properties ofPHBV/glassy carbon composites. Journal of Applied Polymer Science, v. 138, n. 4, p. 15-pg., 2020-08-05. (18/09531-2)

VIEIRA, LEONARDO DE SOUZA; MONTAGNA, LARISSA STIEVEN; SILVA, ANA PAULA BERNARDO DA; VERGINIO, GLEICE ELLEN ALMEIDA; PASSADOR, FABIO ROBERTO. ffect of glassy carbon addition and photodegradation on the biodegradation in aqueous medium of poly (3-hydroxybutyrate-co-3-hydroxyvalerate)/glassy carbon green composite. Journal of Applied Polymer Science, v. 138, n. 33, APR 2021. (18/09531-2)

RIBEIRO, BRUNO; CORREDOR, JEFERSSON ALEXANDER ROJAS; DE PAULA SANTOS, LUIS FELIPE; GOMES, NEWTON ADRIANO SANTOS; REZENDE, MIRABEL CERQUEIRA. Electrical conductivity and electromagnetic shielding performance of glass fiber-reinforced epoxy composites with multiwalled carbon nanotube buckypaper interlayer. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 32, n. 2, p. 1962-1976, JAN 2021. (18/09531-2, 18/07867-3, 17/04740-0)

CUNHA, J. A. P.; SILVA, T. C.; COSTA, M. L.; REZENDE, M. C.. Ozone and water immersion effects on compression strength and fracture behavior of carbon/epoxy laminates. ENGINEERING FAILURE ANALYSIS, v. 120, FEB 2021. (18/09531-2)

OYAMA, ISABELA C.; DE SOUZA, GABRIEL P. M.; REZENDE, MIRABEL C.; MONTAGNA, LARISSA S.; PASSADOR, FABIO R.. A new eco-friendly green composite for antistatic packaging: Green low-density polyethylene/glassy carbon. Polymer Composites, v. 41, n. 7, MAR 2020. (18/09531-2)

MONTAGNA, LARISSA STIEVEN; DA SILVA, ANA PAULA BERNARDO; DE MELO MORGADO, GUILHERME FERREIRA; RIBEIRO, BRUNO; PASSADOR, FABIO ROBERTO; REZENDE, MIRABEL CERQUEIRA. PFA nanocomposites: the influence of three carbon nanofillers on the mechanical and electromagnetic properties. JOURNAL OF POLYMER RESEARCH, v. 28, n. 7, JUL 2021. (18/09531-2, 17/04740-0)

DE SOUZA VIEIRA, LEONARDO; DOS ANJOS, ERICK GABRIEL RIBEIRO; VERGINIO, GLEICE ELLEN ALMEIDA; OYAMA, ISABELA CESAR; BRAGA, NATALIA FERREIRA; DA SILVA, THAIS FERREIRA; MONTAGNA, LARISSA STIEVEN; REZENDE, MIRABEL CERQUEIRA; PASSADOR, FABIO ROBERTO. Carbon-based materials as antistatic agents for the production of antistatic packaging: a review. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 32, n. 4, p. 3929-3947, FEB 2021. (18/09531-2)

BRAZIL, TAYRA R.; GONCALVES, MARAISA; JUNIOR, MAURO S. O.; REZENDE, MIRABEL C.. A statistical approach to optimize the activated carbon production from Kraft lignin based on conventional and microwave processes. Microporous and Mesoporous Materials, v. 308, p. 11-pg., 2020-12-01. (18/09531-2)

RIBEIRO, BRUNO; SANTOS GOMES, NEWTON ADRIANO; BALDAN, MAURICIO; REZENDE, MIRABEL CERQUEIRA. Designing Sandwich Architecture Towards Glass Fiber/Epoxy Reinforced Multi-walled Carbon Nanotube Buckypaper Composites for Electromagnetic Interference Shielding. ELECTRONIC MATERIALS LETTERS, v. N/A, p. 8-pg., 2022-11-12. (18/09531-2, 17/04740-0)

DA SILVA, VALDIRENE APARECIDA; REZENDE, MIRABEL CERQUEIRA. S-parameters, electrical permittivity, and absorbing energy measurements of carbon nanotubes-based composites in X-band. Journal of Applied Polymer Science, v. 138, n. 7, SEP 2020. (18/09531-2)

ROJAS, J. A.; RIBEIRO, B.; REZENDE, M. C.. Curing of Glass Fiber/Epoxy Resin Composites Using Multiwalled Carbon Nanotubes Buckypaper as a Resistive Element. JOURNAL OF MANUFACTURING SCIENCE AND ENGINEERING-TRANSACTIONS OF THE ASME, v. 143, n. 4, APR 1 2021. (18/09531-2, 17/04740-0)

PRADO MENDONCA, THAIS ALINE; BRAZIL, TAYRA RODRIGUES; REZENDE, MIRABEL CERQUEIRA; GONCALVES, MARAISA. Synthesis of activated carbon from biodiesel waste as a sustainable environmental method using microwave heating. JOURNAL OF POROUS MATERIALS, v. N/A, p. 12-pg., 2022-11-08. (18/09531-2)

RIBEIRO DOS ANJOS, ERICK GABRIEL; DE MELO MORGADO, GUILHERME FERREIRA; VIEIRA, LEONARDO DE SOUZA; MONTEIRO DE SOUZA, GABRIEL PORTILHO; ROMEU LINO DE SOUZA, MARIA FERNANDA; NOGUEIRA, IURY ARAUJO; ALCANTARA RODRIGUES, LINA DAYSE; WEARN, YVES NICOLAU; PASSADOR, FABIO ROBERTO. Processing and characterization of polypropylene (PP)/ethylene-vinyl acetate (EVA) blend-based glassy carbon (GC) composites. SN APPLIED SCIENCES, v. 2, n. 8, JUL 16 2020. (18/09531-2)

CUNHA, J. A. P.; SILVA, T. C.; COSTA, M. L.; REZENDE, M. C.. Ageing effects after ozone and water immersion on tensile strength at room and high temperatures of carbon/epoxy F8552 laminates. JOURNAL OF COMPOSITE MATERIALS, v. 55, n. 1, JUL 2020. (18/09531-2)

BRAZIL, TAYRA R.; GONCALVES, MARAISA; JUNIOR, MAURO S. O.; REZENDE, MIRABEL C.. Sustainable process to produce activated carbon from Kraft lignin impregnated with H3PO4 using microwave pyrolysis. BIOMASS & BIOENERGY, v. 156, p. 9-pg., 2022-01-01. (18/09531-2)

FABIANO DA SILVA DIAS; TAYRA RODRIGUES BRAZIL; LARISSA STIEVEN MONTAGNA; MIRABEL CERQUEIRA REZENDE. Estudo da influência dos parâmetros de tratamento térmico da resina furfurílica nas características morfológicas, estruturais e condutividade elétrica do carbono vítreo reticulado. MATERIA-RIO DE JANEIRO, v. 26, n. 2, 2021-05-24. (18/09531-2)

CARLOS ALBERTO FERNANDES MARLET; MIRABEL CERQUEIRA REZENDE. Obtenção e caracterização de tecido multicamadas tridirecional de fibra de aramida visando aplicação em blindagem balística. MATERIA-RIO DE JANEIRO, v. 26, n. 1, 2021-03-12. (15/50065-7, 18/09531-2)

VIEIRA, LEONARDO DE SOUZA; MONTAGNA, LARISSA STIEVEN; SILVA, ANA PAULA BERNARDO DA; VERGINIO, GLEICE ELLEN ALMEIDA; PASSADOR, FABIO ROBERTO. Effect of glassy carbon addition and photodegradation on the biodegradation in aqueous medium of poly (3-hydroxybutyrate-co-3-hydroxyvalerate)/glassy carbon green composites. Journal of Applied Polymer Science, v. 138, n. 33, p. 13-pg., 2021-04-07. (18/09531-2)