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Sustainable synthetic methods employing catalysis, benign solvents, safer reagents, and bio-renewable feedstock

Grant number: 21/12394-0
Support Opportunities:Research Projects - Thematic Grants
Duration: June 01, 2023 - May 31, 2028
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal Investigator:Arlene Gonçalves Corrêa
Grantee:Arlene Gonçalves Corrêa
Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
Pesquisadores principais:
Ernesto Antonio Urquieta Gonzalez ; Lucia Helena Mascaro Sales ; Márcio Weber Paixão ; Marco Antonio Barbosa Ferreira
Associated researchers:Ernesto Chaves Pereira de Souza ; Ivo Freitas Teixeira ; Marco Antonio Barbosa Ferreira ; Ricardo Samuel Schwab ; Sérgio Henrique Vannucchi Leme de Mattos
Associated scholarship(s):24/01563-3 - PluriVerCidade: Environmental Education Program on links between water, energy and food aimed at public elementary schools in São Carlos, BP.TT
23/15888-9 - Support for the planning, application and evaluation of activities of PluriVerCidade: Environmental Education Program on links between water, energy and food aimed at public primary schools in São Carlos, BP.TT
23/13505-5 - Synthesis of N-heterocycles via asymmetric Ugi-type multicomponent reactions, BP.PD
+ associated scholarships 23/12011-9 - PluriVerCidade: Environmental Education Program on links between water, energy and food aimed at public elementary schools in São Carlos., BP.TT
23/11454-4 - Photocatalytic synthesis of 1-pyrrolines under continuous flow conditions and synthesis of pyrrolo[2,1-a]isoquinolines for antiplasmodial evaluation, BP.PD
23/11554-9 - Synthesis and modification of carbon materials with transition metal oxides for application in CO2 reduction assays, BP.PD - associated scholarships

Abstract

The Centre of Excellence for Research in Sustainable Chemistry (CERSusChem) was established in 2016 by the FAPESP Engineering Research Centers Program (CPE) and was co-financed by the pharmaceutical industry GlaxoSmithKline (GSK). The CERSusChem activities are based on the 3 pillars: research, innovation, and knowledge dissemination. Continuing our efforts in the development of new sustainable synthetic methods, in this present proposal, studies focused on homogeneous and heterogeneous catalysis will be addressed. To this end, we will take advantage of our expertise on asymmetric organocatalysis, photocatalysis, electrocatalysis and nanocatalysis using benign solvents, safer reagents, and bio-renewable feedstock. The new catalysts may be immobilized in different materials, such as nanoparticles, and adapted to continuous flow process. This proposal also comprises two major approaches to the education and dissemination of the produced knowledge, namely: i) the development of undergraduate, graduate, and technical training actions within the formal education principles; and ii) the elaboration of non-formal education activities involving science communication for high and elementary school teachers and students, and lay citizens. (AU)

Articles published in Agência FAPESP Newsletter about the research grant:
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Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
JANUARIO, MARCELO AUGUSTO PEREIRA; DE SOUZA, DEMETRIUS P.; ZUKERMAN-SCHPECTOR, JULIO; CORREA, ARLENE G.. Rh(III)-Catalyzed C-2 Alkylation of Indoles followed by a Post-Synthetic Modification via the Ugi Reaction. CHEMISTRYOPEN, v. 12, n. 6, p. 8-pg., . (13/07600-3, 21/12394-0, 14/50918-7)
TEIXEIRA, WYSTAN K. O.; DE ALBUQUERQUE, DANILO YANO; ZUKERMAN-SCHPECTOR, JULIO; SECKLER, DIEGO; RAMPON, DANIEL S.; SCHWAB, RICARDO S.. Copper-Mediated Intramolecular Interrupted CuAAC Selanylation. Journal of Organic Chemistry, v. 88, n. 15, p. 14-pg., . (14/50249-8, 21/12394-0, 13/06558-3)

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