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Effects of Laser and Electron Beam Incidence on Semiconductor Materials: an ab initio Investigation

Abstract

The focus of this research project is the study and control of structural and electronic properties of semiconductor materials due to the incidence of laser and electron beam. External disturbances can change the growth pattern andcontrol the defect density in semiconductor nanostructures, opening a wide field of investigations into the electronic structure of the irradiated materials, such as the emergence of magnetism in non-magnetic structures. The controlof electronic excitation and lattice heating through laser and electron beam allows modulating the band gap of the semiconductor, changing the luminescence center of the material according to the interest of studies and industrial applications, in which the relaxation channels tend to carry the nanostructure to the ground state. After a certain period of irradiation time, the formation and diffusion of nanoclusters through the material is observed, which move towards the surface of the irradiated material for their subsequent adsorption. The order-disorder relationship is observed for low radiation limits, while the greatest disorder is determined for high radiation values. Computational modeling at theatomistic scale based on density functional theory allows us to elucidate, predict and design new effects in the study of the incidence of external fields in semiconductor materials. Due to the lower mass of electrons in relation to nuclei, therapid response of electrons and holes in relation to nuclei can be simulated through finite temperature density functional theory, while the lattice heating is investigated through ab inito molecular dynamics. The high computational cost for simulating and understanding the effects of laser and electron beam incidence on semiconductors becomes a barrier to be overcome. The success previously obtained with these simulations allows us to continue investing in this model, in which silver-based semiconductor compounds will be studied firstly due to their applications in nanoscience and nanomedicine. (AU)

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VEICULO: TITULO (DATA)
VEICULO: TITULO (DATA)

Scientific publications (11)
(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)
LARANJEIRA, JOSE A. S.; GONZALO, FREDY M.; RIVERA, VICTOR J. R.; CABRAL, LUIS A.; DENIS, PABLO A.; SAMBRANO, JULIO R.. Strain engineering in molybditene: A theoretical insight into the 2D phase of α-MoO3. NEXT MATERIALS, v. 9, p. 11-pg., . (20/01144-0, 22/03959-6, 22/16509-9, 24/19996-3)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; GONZALO, FREDY M.; RIVERA, VICTOR J. R.; FLORES, EFRACIO M.; DENIS, PABLO A.; SAMBRANO, JULIO R.. First-principles investigation of bimetallic Janus ScTaCO2 MXene: Structure, stability, and gas-sensing performance. FLATCHEM, v. 54, p. 10-pg., . (24/22897-7, 20/01144-0, 24/19996-3, 22/03959-6, 24/05087-1, 22/16509-9, 24/22899-0)
ALVES, RODRIGO A. F.; RODRIGUES, HUGO X.; LARANJEIRA, JOSE A. S.; MENDONCA, FABIO L. L.; SILVA, ALYSSON M. A.; SAMBRANO, JULIO R.; RIBEIRO JR, LUIZ A.. PolyRingene: A novel 2D carbon allotrope explored via first-principles and machine learning interatomic potentials. FLATCHEM, v. 54, p. 10-pg., . (24/19996-3, 25/04757-6, 20/01144-0, 22/03959-6, 22/16509-9, 24/05087-1, 22/14576-0)
LARANJEIRA, JOSE A. S.; LIMA, K. A. L.; MARTINS, NICOLAS F.; CABRAL, LUIS A.; RIBEIRO JUNIOR, L. A.; SAMBRANO, JULIO R.. Propylenidene: A novel metallic carbon monolayer with unconventional ring topology. Solid State Communications, v. 405, p. 7-pg., . (24/19996-3, 20/01144-0, 22/03959-6, 22/16509-9, 24/05087-1, 22/14576-0)
PEREIRA, ZENNER S.; CABRAL, L.; DA SILVA, E. Z.. Superconductivity in pure hafnium kagome electride under high pressure. PHYSICAL REVIEW B, v. 112, n. 22, p. 9-pg., . (13/07296-2, 24/19996-3, 24/00998-6)
PONCE, M. A.; DESIMONE, P. M.; MAZZEI, M. E.; SIMOES, A. Z.; ROCHA, L. S. R.; DA COSTA, M. E. H. MAIA; ASSIS, M.; GIULIETTI, G.; CABRAL, L.; LONGO, E.; et al. Structural modification and electrical property modulation of SnO driven by e-beam irradiation and thermal treatment. Materials Letters, v. 406, p. 5-pg., . (25/04757-6, 24/19996-3, 23/08525-7, 24/20227-4, 13/07296-2)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; APARICIO-HUACARPUMA, BILL D.; LIMA, KLEUTON A. L.; RIBEIRO JUNIOR, LUIZ A.; SAMBRANO, JULIO R.. Two-dimensional T-C3N functionalized with sodium: A promising platform for solid-state hydrogen storage. PHYSICA B-CONDENSED MATTER, v. 719, p. 8-pg., . (25/04757-6, 22/14576-0, 24/19996-3, 13/08293-7, 24/05087-1, 22/16509-9, 20/01144-0, 22/03959-6)
GAO, MINGYANG; GUO, JUN; YANG, XIAODONG; ZHOU, YANJIANG; LARANJEIRA, JOSE ARTIGAS DOS SANTOS; SAMBRANO, JULIO R.; ZHANG, WEN. From sensors to system-level integration: Flexible WO3/MoS2 heterojunction NO2 gas sensor. SENSORS AND ACTUATORS B-CHEMICAL, v. 451, p. 7-pg., . (22/16509-9, 24/19996-3)
LARANJEIRA, JOSE A. S.; LIMA, KLEUTON A. L.; MARTINS, NICOLAS F.; JUNIOR, LUIZ A. RIBEIRO; GALVAO, DOUGLAS S.; CABRAL, LUIS A.; SAMBRANO, JULIO R.. β-Irida-graphene: A new 2D carbon allotrope for sodium-ion battery anodes. PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, v. 177, p. 10-pg., . (25/04757-6, 22/14576-0, 24/19996-3, 13/08293-7, 24/05087-1, 22/16509-9, 20/01144-0, 22/03959-6)
LARANJEIRA, JOSE A. S.; MARTINS, NICOLAS F.; LOPES LIMA, KLEUTON ANTUNES; CABRAL, LUIS A.; RIBEIRO JUNIOR, LUIZ A.; GALVAO, DOUGLAS S.; SAMBRANO, JULIO R.. TPHE-Graphene: A First-Principles Study of a New 2D Carbon Allotrope for Hydrogen Storage. ACS OMEGA, v. 10, n. 32, p. 12-pg., . (20/01144-0, 24/19996-3, 24/05087-1, 22/03959-6, 22/16509-9, 13/08293-7)
MARTINS, NICOLAS F.; LARANJEIRA, JOSE A. S.; LIMAB, KLEUTON A. L.; CABRAL, LUIS A.; RIBEIRO JR, LUIZ A.; SAMBRANO, JULIO R.. HOP-graphene: A high-capacity anode for Li/Na-ion batteries unveiled by first-principles calculations. Applied Surface Science, v. 710, p. 10-pg., . (20/01144-0, 24/19996-3, 24/05087-1, 22/14576-0, 22/03959-6, 22/16509-9, 13/08293-7)