Study of reactions of clean synthesis and chemical modification of the biodiesel and fusel oil for preparation of organic carbonate and carbamates using carbon dioxide in the presence of organocatalysts and heterogeneous catalysts

• Grant number: 13/24487-6
• Support Opportunities: Regular Research Grants
• Start date: May 01, 2014
• End date: June 30, 2016
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Organic Chemistry
• Principal Investigator: Eduardo Rene Perez Gonzalez
• Grantee: Eduardo Rene Perez Gonzalez
• Host Institution: Faculdade de Ciências e Tecnologia (FCT). Universidade Estadual Paulista (UNESP). Campus de Presidente Prudente. Presidente Prudente , SP, Brazil

Abstract

The project aims the study of reactions of synthesis and modification of biodiesel from soy, canola and cartamo oils with diverse heterogeneous catalysts and also in homogeneous phase. For synthesis of biodiesel, heteropoliacids will be studied among other catalysts such as basic supported organocatalisadores, complexes of Metal-chitosan, montmorillonites. In addition of methyl and ethyl esters, it is considered the use of main fusel oil alcohols (isobutyl and isopentyl alcohols) obtained by recycling of this by-product of Brazilian sugar and ethanol industry. The chemical modification of biodiesel will be performed by epoxidation and subsequent cycloaddition of carbon dioxide for production of carbonates and carbamates, with potential application in the area of new organic materials. These materials will be proceeding from clean sources, using as raw material vegetal oils, fusel oil and carbon dioxide. Physical chemical characterization and will be carried out using GC-MS, ESI-MS, RMN, FT-IR. These methodologies will be also used for low quality fatty ester recovery. (AU)

Scientific publications

(8)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MARTINS, CARINA C.; ZANUTTO BASSETTO, JR., CARLOS A.; SANTOS, JANDYSON M.; EBERLIN, MARCOS N.; MAGALHAES, ALVICLER; VARANDA, WAMBERTO; PEREZ GONZALEZ, EDUARDO R.. Mass spectrometry study of N-alkylbenzenesulfonamides with potential antagonist activity to potassium channels. Amino Acids, v. 48, n. 2, p. 445-459, FEB 2016. (13/24487-6)

ZANUTTO BASSETTO JUNIOR, CARLOS ALBERTO; VARANDA, WAMBERTO ANTONIO; PEREZ GONZALEZ, EDUARDO RENE. 4-Chloro-3-nitro-N-butylbenzenesulfonamide acts on K(V)3.1 channels by an open-channel blocker mechanism. Amino Acids, v. 49, n. 11, p. 1895-1906, NOV 2017. (13/24487-6, 12/19750-7)

PEREIRA, FERNANDA STUANI; LANFREDI, SILVANIA; PEREZ GONZALEZ, EDUARDO RENE; DA SILVA AGOSTINI, DEUBER LINCON; GOMES, HOMERO MARQUES; MEDEIROS, RICARDO DOS SANTOS. Thermal and morphological study of chitosan metal complexes. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 129, n. 1, p. 291-301, JUL 2017. (13/24487-6, 12/13901-3, 13/26576-6)

DO ESPIRITO SANTO, RAFAEL DIAS; ARENAS VELASQUEZ, ANGELA MARIA; GUSHIKEN PASSIANOTO, LUANA VITORINO; LOPERA SEPULVEDA, ALEX ARBEY; CLEMENTINO, LEANDRO DA COSTA; ASSIS, RENATA PIRES; BAVIERA, AMANDA MARTINS; KALABA, PREDRAG; DOS SANTOS, FABIO NEVES; EBERLIN, MARCOS NOGUEIRA; et al. N, N ', N ''-trisubstituted guanidines: Synthesis, characterization and evaluation of their leishmanicidal activity. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, v. 171, p. 13-pg., 2019-06-01. (13/24487-6, 17/03552-5, 13/08248-1, 16/19289-9)

DO ESPIRITO SANTO, RAFAEL DIAS; ARENAS VELASQUEZ, ANGELA MARIA; GUSHIKEN PASSIANOTO, LUANA VITORINO; LOPERA SEPULVEDA, ALEX ARBEY; CLEMENTINO, LEANDRO DA COSTA; ASSIS, RENATA PIRES; BAVIERA, AMANDA MARTINS; KALABA, PREDRAG; DOS SANTOS, FABIO NEVES; EBERLIN, MARCOS NOGUEIRA; et al. N, N `, N `'-trisubstituted guanidines: Synthesis, characterization and evaluation of their leishmanicidal activity. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, v. 171, p. 116-128, JUN 1 2019. (13/24487-6, 17/03552-5, 16/19289-9, 13/08248-1)

PEREIRA, F. S.; PEREIRA, L. J.; CREDITO, D. F. A.; GIRAO, L. H. V.; IDEHARA, A. H. S.; GONZALEZ, E. R. P.. Cycling of waste fusel alcohols from sugar cane industries using supercritical carbon dioxide. RSC ADVANCES, v. 5, n. 99, p. 81515-81522, 2015. (13/24487-6, 12/24330-7, 11/23438-6, 12/24661-3, 14/00289-3, 12/13901-3)

CAPITAO, R. M.; SANTO, R. D. E.; MAGALHAES, A.; ASSIS, D.; DA SILVA, G. V. J.; SCARIM, C. B.; CHELUCCI, R. C.; ANDRADE, C. R.; CHUNG, M. C.; GONZALEZ, E. R. P.. Synthesis of azo carbonate monomers and biocompatibility study of poly(azo-carbonate-urethane)s. RSC ADVANCES, v. 6, n. 83, p. 79987-79997, 2016. (13/24487-6)

ZANUTTO BASSETTO JUNIOR, CARLOS ALBERTO; GUSHIKEN PASSIANOTO, LUANA VITORINO; PEREZ GONZALEZ, EDUARDO RENE; VARANDA, WAMBERTO ANTONIO. Benzenesulfonamides act as open-channel blockers on K(V)3.1 potassium channel. Amino Acids, v. 51, n. 2, p. 355-364, FEB 2019. (12/19750-7, 13/24487-6)

Filed patent(s) as a result of this research project