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Study of reactions of clean synthesis and chemical modification of the biodiesel and fusel oil for preparation of organic carbonate and carbamates using carbon dioxide in the presence of organocatalysts and heterogeneous catalysts

Abstract

The project aims the study of reactions of synthesis and modification of biodiesel from soy, canola and cartamo oils with diverse heterogeneous catalysts and also in homogeneous phase. For synthesis of biodiesel, heteropoliacids will be studied among other catalysts such as basic supported organocatalisadores, complexes of Metal-chitosan, montmorillonites. In addition of methyl and ethyl esters, it is considered the use of main fusel oil alcohols (isobutyl and isopentyl alcohols) obtained by recycling of this by-product of Brazilian sugar and ethanol industry. The chemical modification of biodiesel will be performed by epoxidation and subsequent cycloaddition of carbon dioxide for production of carbonates and carbamates, with potential application in the area of new organic materials. These materials will be proceeding from clean sources, using as raw material vegetal oils, fusel oil and carbon dioxide. Physical chemical characterization and will be carried out using GC-MS, ESI-MS, RMN, FT-IR. These methodologies will be also used for low quality fatty ester recovery. (AU)

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Scientific publications (7)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DO ESPIRITO SANTO, RAFAEL DIAS; ARENAS VELASQUEZ, ANGELA MARIA; GUSHIKEN PASSIANOTO, LUANA VITORINO; LOPERA SEPULVEDA, ALEX ARBEY; CLEMENTINO, LEANDRO DA COSTA; ASSIS, RENATA PIRES; BAVIERA, AMANDA MARTINS; KALABA, PREDRAG; DOS SANTOS, FABIO NEVES; EBERLIN, MARCOS NOGUEIRA; JOSE DA SILVA, GIL VALDO; ZEHL, MARTIN; LUBEC, GERT; SILVA GRAMINHA, MARCIA APARECIDA; PEREZ GONZALEZ, EDUARDO RENE. N, N `, N `'-trisubstituted guanidines: Synthesis, characterization and evaluation of their leishmanicidal activity. EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, v. 171, p. 116-128, JUN 1 2019. Web of Science Citations: 0.
ZANUTTO BASSETTO JUNIOR, CARLOS ALBERTO; GUSHIKEN PASSIANOTO, LUANA VITORINO; PEREZ GONZALEZ, EDUARDO RENE; VARANDA, WAMBERTO ANTONIO. Benzenesulfonamides act as open-channel blockers on K(V)3.1 potassium channel. Amino Acids, v. 51, n. 2, p. 355-364, FEB 2019. Web of Science Citations: 0.
ZANUTTO BASSETTO JUNIOR, CARLOS ALBERTO; VARANDA, WAMBERTO ANTONIO; PEREZ GONZALEZ, EDUARDO RENE. 4-Chloro-3-nitro-N-butylbenzenesulfonamide acts on K(V)3.1 channels by an open-channel blocker mechanism. Amino Acids, v. 49, n. 11, p. 1895-1906, NOV 2017. Web of Science Citations: 1.
PEREIRA, FERNANDA STUANI; LANFREDI, SILVANIA; PEREZ GONZALEZ, EDUARDO RENE; DA SILVA AGOSTINI, DEUBER LINCON; GOMES, HOMERO MARQUES; MEDEIROS, RICARDO DOS SANTOS. Thermal and morphological study of chitosan metal complexes. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 129, n. 1, p. 291-301, JUL 2017. Web of Science Citations: 5.
MARTINS, CARINA C.; ZANUTTO BASSETTO, JR., CARLOS A.; SANTOS, JANDYSON M.; EBERLIN, MARCOS N.; MAGALHAES, ALVICLER; VARANDA, WAMBERTO; PEREZ GONZALEZ, EDUARDO R. Mass spectrometry study of N-alkylbenzenesulfonamides with potential antagonist activity to potassium channels. Amino Acids, v. 48, n. 2, p. 445-459, FEB 2016. Web of Science Citations: 2.
CAPITAO, R. M.; SANTO, R. D. E.; MAGALHAES, A.; ASSIS, D.; DA SILVA, G. V. J.; SCARIM, C. B.; CHELUCCI, R. C.; ANDRADE, C. R.; CHUNG, M. C.; GONZALEZ, E. R. P. Synthesis of azo carbonate monomers and biocompatibility study of poly(azo-carbonate-urethane)s. RSC ADVANCES, v. 6, n. 83, p. 79987-79997, 2016. Web of Science Citations: 0.
PEREIRA, F. S.; PEREIRA, L. J.; CREDITO, D. F. A.; GIRAO, L. H. V.; IDEHARA, A. H. S.; GONZALEZ, E. R. P. Cycling of waste fusel alcohols from sugar cane industries using supercritical carbon dioxide. RSC ADVANCES, v. 5, n. 99, p. 81515-81522, 2015. Web of Science Citations: 3.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.
Filed patent(s) as a result of this research project

MÉTODO DE OBTENÇÃO DE BENZENOSSULFONAMIDAS, BENZENOSSULFONAMIDAS E SEU USO BR1020160217539 - Universidade Estadual Paulista (UNESP) . Eduardo René Pérez González; Carlos Alberto Zanutto Bassetto Junior; Carina Couto Martins; Wamberto Antonio Varanda - September 2016, 22