Advanced spectroscopy of novel nanomaterials

• Grant number: 13/16911-2
• Support Opportunities: Research Grants - Young Investigators Grants
• Start date: August 01, 2014
• End date: July 31, 2019
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Lázaro Aurélio Padilha Junior
• Grantee: Lázaro Aurélio Padilha Junior
• Host Institution: Instituto de Física Gleb Wataghin (IFGW). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated researchers: Diogo Burigo Almeida
• Associated research grant(s): 18/15574-6 - Advanced spectroscopy of nanomaterials: from ensemble to single-particle, AP.JP2; 17/21549-1 - Random lasers in semiconductor nanocrystals, AV.BR; 16/50011-7 - Two-dimensional spectroscopy of novel nanomaterials, AP.R SPRINT
• Associated scholarship(s): 15/06616-9 - Time-resolved spectroscopy in nanomaterials, BP.IC

Abstract

Recent advances on the development of new methods for synthesis of semiconductor nanostructures has allowed for better control of their optical and electronic properties. In those structures, quantum confinement changes the electronic structure changing existing and generating novel physical phenomena which are of interest not only for fundamental science but also for technological applications. This is the case of the enhanced multi-exciton generation rate in semiconductor quantum dots, which can be useful for application in generation-III solar panels. In this project, we propose to use ultrafast and nonlinear spectroscopy to study the dynamics of photoexcited carriers and the nonlinear optical response in nanostructured semiconductors. In particular, we will investigate multi-excitons interaction and multi-photon absorption in visible and near-infrared emitting nanoparticles which are candidates for applications on solar cells, 3D microscopy and telecommunications. Finally, this project will contribute to the expansion of ultrafast and nonlinear spectroscopy studies not only at UNICAMP but also, in the entire São Paulo State. (AU)

Scientific publications

(21)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX3 Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, MAY 2020. (14/50906-9, 18/15574-6, 17/11986-5, 16/02268-9, 13/16911-2)

NAGAMINE, GABRIEL; JEONG, BYEONG GUK; FERREIRA, TOMAS A. C.; CHANG, JUN HYUK; PARK, KYOUNGWON; LEE, DOH C.; BAE, WAN KI; PADILHA, LAZARO A.. Efficient Optical Gain in Spherical Quantum Wells Enabled by Engineering Biexciton Interactions. ACS PHOTONICS, v. 7, n. 8, p. 2252-2264, AUG 19 2020. (18/15574-6, 18/25339-4, 19/22565-6, 13/16911-2)

CHANG, JUN HYUK; PARK, PHILIP; JUNG, HEEYOUNG; JEONG, BYEONG GUK; HAHM, DONGHYO; NAGAMINE, GABRIEL; KO, JONGKUK; CHO, JINHAN; PADILHA, LAZARO A.; LEE, DOH C.; et al. Unraveling the Origin of Operational Instability of Quantum Dot Based Light-Emitting Diodes. ACS NANO, v. 12, n. 10, p. 10231-10239, OCT 2018. (13/16911-2)

BARROS, LEONARDO W. T.; CARDOSO, THIAGO A. S.; BIHLMEIER, ANGELA; WAGNER, DANNY; KOELMEL, DOMINIK K.; HOERNER, ANNA; BRAESE, STEFAN; CRUZ, CARLOS H. BRITO; PADILHA, LAZARO A.. Two-photon absorption in a series of 2,6-disubstituted BODIPY dyes. Physical Chemistry Chemical Physics, v. 19, n. 32, p. 21683-21690, AUG 28 2017. (13/16911-2, 14/06451-7)

PELEGATI, VITOR B.; KYOTOKU, BERNARDO B. C.; PADILHA, LAZARO A.; CESAR, CARLOS L.. Six-wave mixing coherent anti-Stokes Raman scattering microscopy. BIOMEDICAL OPTICS EXPRESS, v. 9, n. 5, p. 2407-2417, MAY 1 2018. (05/51689-2, 13/16911-2, 11/51959-0, 14/50938-8)

CASTANEDA, JUAN A.; NAGAMINE, GABRIEL; YASSITEPE, EMRE; BONATO, LUIZ G.; VOZNYY, OLEKSANDR; HOOGLAND, SJOERD; NOGUEIRA, ANA F.; SARGENT, EDWARD H.; BRITO CRUZ, CARLOS H.; PADILHA, LAZARO A.. Efficient Biexciton Interaction in Perovskite Quantum Dots Under Weak and Strong Confinement. ACS NANO, v. 10, n. 9, p. 8603-8609, SEP 2016. (14/18327-9, 13/16911-2, 13/05798-0, 14/21928-4)

ROSA, HENRIQUE G.; CASTANEDA, JUAN A.; BRITO CRUZ, CARLOS H.; PADILHA, LAZARO A.; GOMES, JOSE C. V.; THOROH DE SOUZA, EUNEZIO A.; FRAGNITO, HUGO L.. Controlled stacking of graphene monolayer saturable absorbers for ultrashort pulse generation in erbium-doped fiber lasers. OPTICAL MATERIALS EXPRESS, v. 7, n. 7, p. 2528-2537, JUL 1 2017. (10/19085-8, 13/16911-2, 12/07678-0, 12/50259-8)

LIU, ALBERT; ALMEIDA, DIOGO B.; BONATO, LUIZ G.; NAGAMINE, GABRIEL; ZAGONEL, LUIZ F.; NOGUEIRA, ANA F.; PADILHA, LAZARO A.; CUNDIFF, S. T.. Multidimensional coherent spectroscopy reveals triplet state coherences in cesium lead-halide perovskite nanocrystals. SCIENCE ADVANCES, v. 7, n. 1, JAN 2021. (13/16911-2, 16/50011-7)

LIU, ALBERT; ALMEIDA, DIOGO B.; BAE, WAN-KI; PADILHA, LAZARO A.; CUNDIFF, STEVEN T.. Simultaneous Existence of Confined and Delocalized Vibrational Modes in Colloidal Quantum Dots. Journal of Physical Chemistry Letters, v. 10, n. 20, p. 6144-6150, OCT 17 2019. (13/16911-2, 16/50011-7)

NAGAMINE, GABRIEL; BONATO, LUIZ GUSTAVO; CASTANEDA, JUAN A.; YASSITEPE, EMRE; NOGUEIRA, ANA F.; BRITO CRUZ, CARLOS H.; PADILHA, LAZARO A.; RAFAILOV, MK. Nonlinear Spectroscopy in Perovskite Quantum Dots. ULTRAFAST BANDGAP PHOTONICS III, v. 10638, p. 7-pg., 2018-01-01. (13/05798-0, 13/16911-2)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX3 Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v. 59, n. 28, p. 9-pg., 2020-05-07. (17/11986-5, 14/50906-9, 13/16911-2, 18/15574-6, 16/02268-9)

LIU, A.; ALMEIDA, D. B.; BAE, W. K.; PADILHA, L. A.; CUNDIFF, S. T.. Non-Markovian Exciton-Phonon Interactions in Core-Shell Colloidal Quantum Dots at Femtosecond Timescales. Physical Review Letters, v. 123, n. 5, AUG 2 2019. (13/16911-2, 16/50011-7)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX(3)Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v. 59, n. 28, p. 11501-11509, JUL 6 2020. (14/50906-9, 18/15574-6, 17/11986-5, 13/16911-2)

NAGAMINE, GABRIEL; NUNCIARONI, HENRIQUE B.; MCDANIEL, HUNTER; EFROS, ALEXANDER L.; DE BRITO CRUZ, CARLOS H.; PADILHA, LAZARO A.. Evidence of Band-Edge Hole Levels Inversion in Spherical CuInS2 Quantum Dots. Nano Letters, v. 18, n. 10, p. 6353-6359, OCT 2018. (13/16911-2)

LIU, ALBERT; BONATO, LUIZ G.; SESSA, FRANCESCO; ALMEIDA, DIOGO B.; ISELE, ERIK; NAGAMINE, GABRIEL; ZAGONEL, LUIZ F.; NOGUEIRA, ANA F.; PADILHA, LAZARO A.; CUNDIFF, STEVEN T.. Effect of dimensionality on the optical absorption properties of CsPbI3 perovskite nanocrystals. Journal of Chemical Physics, v. 151, n. 19, NOV 21 2019. (13/16911-2)

TAZAWA, YUJIRO; HABISREUTINGER, SEVERIN N.; ZHANG, NANLIN; GREGORY, DANIEL A. F.; NAGAMINE, GABRIEL; KESAVA, SAMEER V.; MAZZOTTA, GIULIO; ASSENDER, HAZEL E.; RIEDE, MORITZ; PADILHA, LAZARO A.; et al. Carbon Nanotubes for Quantum Dot Photovoltaics with Enhanced Light Management and Charge Transport. ACS PHOTONICS, v. 5, n. 12, p. 4854-4863, DEC 2018. (13/16911-2)

YASSITEPE, EMRE; YANG, ZHENYU; VOZNYY, OLEKSANDR; KIM, YOUNGHOON; WALTERS, GRANT; CASTANEDA, JUAN ANDRES; KANJANABOOS, PONGSAKORN; YUAN, MINGJIAN; GONG, XIWEN; FAN, FENGJIA; et al. Amine-Free Synthesis of Cesium Lead Halide Perovskite Quantum Dots for Efficient Light-Emitting Diodes. ADVANCED FUNCTIONAL MATERIALS, v. 26, n. 47, p. 8757-8763, DEC 20 2016. (14/18327-9, 13/16911-2, 13/05798-0)

NAGAMINE, GABRIEL; ROCHA, JAQUELINE O.; BONATO, LUIZ G.; NOGUEIRA, ANA F.; ZAHARIEVA, ZHANET; WATT, ANDREW A. R.; DE BRITO CRUZ, CARLOS H.; PADILHA, LAZARO A.. Two-Photon Absorption and Two-Photon-Induced Gain in Perovskite Quantum Dots. Journal of Physical Chemistry Letters, v. 9, n. 12, p. 3478-3484, JUN 21 2018. (13/16911-2)

KOELMEL, DOMINIK K.; HOERNER, ANNA; CASTANEDA, JUAN A.; FERENCZ, JULIO A. P.; BIHLMEIER, ANGELA; NIEGER, MARTIN; BRAESE, STEFAN; PADILHA, LAZARO A.. Linear and Nonlinear Optical Spectroscopy of Fluoroalkylated BODIPY Dyes. Journal of Physical Chemistry C, v. 120, n. 8, p. 4538-4545, MAR 3 2016. (13/16911-2)

ALO, ARTHUR; BARROS, LEONARDO W. T.; NAGAMINE, GABRIEL; VIEIRA, LUCAS B.; CHANG, JUN HYUK; JEONG, BYEONG GUK; BAE, WAN KI; PADILHA, LAZARO A.. Simple Yet Effective Method to Determine Multiphoton Absorption Cross Section of Colloidal Semiconductor Nanocrystals. ACS PHOTONICS, v. 7, n. 7, p. 1806-1812, JUL 15 2020. (18/15574-6, 19/22823-5, 13/16911-2)

NAGAMINE, G.; ROCHA, J. O.; BONATO, L. G.; NOGUEIRA, ANA F.; BRITO CRUZ, C. H.; PADILHA, L. A.; IEEE. Size Dependent Ultra-low Upconverted Lasing Threshold in CsPbBr3 Perovskites Quantum Dots. 2018 CONFERENCE ON LASERS AND ELECTRO-OPTICS (CLEO), v. N/A, p. 2-pg., 2018-01-01. (13/16911-2)