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Contribution of Nanostructured Materials in Electroanalysis of pharmaceuticals and dyes, in the oxidation and reduction photoeletrocatalytic process of Inorganic and Organic Pollutants and Water Disinfection.

Grant number: 15/18109-4
Support Opportunities:Regular Research Grants
Duration: February 01, 2016 - February 28, 2018
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
Principal Investigator:Maria Valnice Boldrin
Grantee:Maria Valnice Boldrin
Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil


The use of electrodes constructed from nanostructured materials or in nanoscale in the electrochemistry, has revolutionized some aspects of thermodynamics and kinetics of the electrodic reactions, energy conversion processes, modification and synthesis of chemical compounds, development of new analytical methods and etc. In this proposal our goal is to explore the electrochemical as a tool in the preparation and/or utilization of nanostructured materials to improve electroanalytical methods response as well as in photoelectrocatalysis measures. Among the extraordinary diversity of nanomaterials is intended to investigate the construction, characterization and application of graphene electrodes modified with cysteine and keratin, magnetic nanoparticles (Fe2O3) and tosyl modified with carboxyl groups and semiconductor nanostructured based on TiO2, and WO3 with and without decoration with Pt and Ag and composites of TiO2/WO3 and Si/TiO2 decorated with Pt. The interest in these materials is justified for the search response for new challenges: determining textile dyes and hair dyes in environmental samples in a quick and inexpensive way, to determine steroids and diuretics in biological fluids and environmental matrices, to investigate new CO2 reduction methods to generate products with higher added value, to improve water disinfection processes and improve the cost/benefit involved in water treatment. In addition we aimed to improve the performance of photoelectrocatalytic processes with enlargeent of semiconductor absorption front of the sunlight spectrum contributing to a significant impact in making these technologies commercially viable. (AU)

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Scientific publications (24)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
DE BRITO, JULIANA FERREIRA; BESSEGATO, GUILHERME GARCIA; FRAGA DE TOLEDO E SOUZA, PEDRO RAFAEL; VIANA, TAIS SUELEN; DE OLIVEIRA, DANIELLE PALMA; MARTINEZ-HUITLE, CARLOS ALBERTO; BOLDRIN ZANONI, MARIA VALNICE. Combination of Photoelectrocatalysis and Ozonation as a Good Strategy for Organics Oxidation and Decreased Toxicity in Oil-Produced Water. Journal of the Electrochemical Society, v. 166, n. 5, p. H3231-H3238, . (14/03679-7, 15/18109-4, 14/50945-4, 13/25343-8)
DE MORAES, PALOMA B.; HUDARI, FELIPE F.; SILVA, JOAO P.; ZANONI, MARIA V. B.. Enhanced Detection of Ponceau 4R Food Dye by Glassy Carbon Electrode Modified with Reduced Graphene Oxide. Journal of the Brazilian Chemical Society, v. 29, n. 6, p. 1237-1244, . (15/18109-4)
CARDOSO, J. C.; STULP, S.; DE BRITO, J. F.; FLOR, J. B. S.; FREM, R. C. G.; ZANONI, M. V. B.. MOFs based on ZIF-8 deposited on TiO2 nanotubes increase the surface adsorption of CO2 and its photoelectrocatalytic reduction to alcohols in aqueous media. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 225, p. 563-573, . (15/18109-4)
FRANCO, JEFFERSON HONORIO; DA SILVA, BIANCA F.; OLIVEIRA, REGINA V.; MEIRELES, GABRIELA; DE OLIVEIRA, DANIELLE PALMA; DE CASTRO, ALEXANDRE A.; RAMALHO, TEODORICO C.; ZANONI, MARIA V. B.. Identification of biotransformation products of disperse dyes with rat liver microsomes by LC-MS/MS and theoretical studies with DNA: Structure-mutagenicity relationship using Salmonella/microsome assay. Science of The Total Environment, v. 613, p. 1093-1103, . (14/50945-4, 15/18109-4, 08/10449-7)
BESSEGATO, GUILHERME GARCIA; HUDARI, FELIPE FANTINATO; BOLDRIN ZANONI, MARIA VALNICE. Self-doped TiO2 nanotube electrodes: A powerful tool as a sensor platform for electroanalytical applications. Electrochimica Acta, v. 235, p. 527-533, . (15/18109-4, 14/03679-7)
BESSEGATO, GUILHERME GARCIA; DE SOUZA, JOAO CARLOS; CARDOSO, JULIANO CARVALHO; BOLDRIN ZANONI, MARIA VALNICE. Assessment of several advanced oxidation processes applied in the treatment of environmental concern constituents from a real hair dye wastewater. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 6, n. 2, p. 2794-2802, . (14/03679-7, 15/18109-4, 15/12998-1)
DE BRITO, JULIANA FERREIRA; LIMA PERINI, JOAO ANGELO; PERATHONER, SIGLINDA; BOLDRIN ZANONI, MARIA VALNICE. Turning carbon dioxide into fuel concomitantly to the photoanode-driven process of organic pollutant degradation by photoelectrocatalysis. Electrochimica Acta, v. 306, p. 277-284, . (14/50945-4, 15/18109-4, 13/25343-8, 16/18057-7, 16/07895-1)
USUKURA KIM, JOAQUIM YUJI; BESSEGATO, GUILHERME G.; DE SOUZA, BARBARA C.; DA SILVA, JOSIEL J.; BOLDRIN ZANONI, MARIA VALNICE. Efficient treatment of swimming pool water by photoelectrocatalytic ozonation: Inactivation of Candida parapsilosis and mineralization of Benzophenone-3 and urea. CHEMICAL ENGINEERING JOURNAL, v. 378, . (15/18109-4, 14/03679-7)
DE SOUZA, JOAO CARLOS; DA SILVA, BIANCA FERREIRA; MORALES, DANIEL ALEXANDRE; UMBUZEIRO, GISELA DE ARAGAO; BOLDRIN ZANONI, MARIA VALNICE. Assessment of p-aminophenol oxidation by simulating the process of hair dyeing and occurrence in hair salon wastewater and drinking water from treatment plant. JOURNAL OF HAZARDOUS MATERIALS, v. 387, . (14/50945-4, 15/18109-4, 15/12998-1, 08/10449-7)
BESSEGATO, GUILHERME G.; DE ALMEIDA, LUCIO C.; FERREIRA, SERGIO L. C.; BOLDRIN ZANONI, MARIA VALNICE. Experimental design as a tool for parameter optimization of photoelectrocatalytic degradation of a textile dye. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 7, n. 4, . (08/10449-7, 11/21606-9, 14/50945-4, 15/18109-4, 12/18357-0, 14/03679-7)
FABRAO, RODRIGO MONTEIRO; DE BRITO, JULIANA FERREIRA; DA SILVA, JOSE LUIZ; STRADIOTTO, NELSON RAMOS; BOLDRIN ZANONI, MARIA VALNICE. Appraisal of photoelectrocatalytic oxidation of glucose and production of high value chemicals on nanotube Ti/TiO2 electrode. Electrochimica Acta, v. 222, p. 123-132, . (08/10449-7, 15/18109-4)
LIMA PERINI, JOAO A.; CARDOSO, JULIANO C.; DE BRITO, JULIANA F.; BOLDRIN ZANONI, MARIA V.. Contribution of thin films of ZrO2 on TiO2 nanotubes electrodes applied in the photoelectrocatalytic CO2 conversion. JOURNAL OF CO2 UTILIZATION, v. 25, p. 254-263, . (15/18109-4, 16/18057-7, 13/25343-8)
HUDARI, FELIPE F.; BESSEGATO, GUILHERME G.; BEDATTY FERNANDES, FLAVIO C.; ZANONI, MARIA V. B.; BUENO, PAULO R.. Reagentless Detection of Low-Molecular-Weight Triamterene Using Self-Doped TiO2 Nanotubes. Analytical Chemistry, v. 90, n. 12, p. 7651-7658, . (15/13359-2, 15/18109-4, 14/03679-7, 12/22820-7)
FRANCO, JEFFERSON HONORIO; DA SILVA, BIANCA F.; DIAS, ELISANGELA FRANCISCON G.; DE CASTRO, ALEXANDRE A.; RAMALHO, TEODORICO C.; ZANONI, MARIA VALNICE BOLDRIN. Influence of auxochrome group in disperse dyes bearing azo groups as chromophore center in the biotransformation and molecular docking prediction by reductase enzyme: Implications and assessment for environmental toxicity of xenobiotics. ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, v. 160, p. 114-126, . (15/18109-4, 08/10449-7)
SAYAO, FABIANA A.; DA SILVA FLOR, JADER BARBOSA; GALVAO FREM, REGINA CELIA; STULP, SIMONE; CARDOSO, JULIANO C.; ZANONI, MARIA V. B.. Nitrite Reduction Enhancement on Semiconducting Electrode Decorated with Copper(II) Aspirinate Complex. ELECTROCATALYSIS, v. 7, n. 6, p. 486-494, . (15/18109-4)
STULP, SIMONE; CARDOSO, JULIANO C.; DE BRITO, JULIANA FERREIRA; FLOR, JADER BARBOSA S.; GALVAO FREM, REGINA CELIA; SAYAO, FABIANA AVOILO; BOLDRIN ZANONI, MARIA VALNICE. An Artificial Photosynthesis System Based on Ti/TiO2 Coated with Cu(II) Aspirinate Complex for CO2 Reduction to Methanol. ELECTROCATALYSIS, v. 8, n. 3, p. 279-287, . (15/18109-4, 13/25343-8)
CARDOSO, JULIANO CARVALHO; BESSEGATO, GUILHERME GARCIA; BOIDRIN ZANONI, MARIA VALNICE. Efficiency comparison of ozonation, photolysis, photocatalysis and photoelectrocatalysis methods in real textile wastewater decolorization. WATER RESEARCH, v. 98, p. 39-46, . (14/03679-7, 15/18109-4)
DE BRITO, JULIANA FERREIRA; BESSEGATO, GUILHERME GARCIA; LIMA PERINI, JOAO ANGELO; DE MOURA TORQUATO, LILIAN DANIELLE; BOLDRIN ZANONI, MARIA VALNICE. Advances in photoelectroreduction of CO2 to hydrocarbons fuels: Contributions of functional materials. JOURNAL OF CO2 UTILIZATION, v. 55, . (14/03679-7, 13/25343-8, 16/18057-7, 14/50945-4, 18/02950-0, 19/00463-7, 15/18109-4)
FRANCO, JEFFERSON HONORIO; DA SILVA, BIANCA F.; ZANONI, MARIA V. B.. Assessment of semi-permanent hair dyes in wash water from beauty salons by liquid chromatography-tandem mass spectrometry-selected reaction monitoring (LC-MS/MS-SRM). ANALYTICAL METHODS, v. 12, n. 44, p. 5415-5423, . (08/10449-7, 15/18109-4)
RODRIGUES DE SOUZA, MARCIELLI KAROLINE; FREITAS CARDOSO, EDUARDO DOS SANTOS; FORTUNATO, V, GUILHERME; LANZA, V, MARCOS R.; NAZARIO, CARLOS EDUARDO; BOLDRIN ZANONI, MARIA VALNICE; MAIA, GILBERTO; CARDOSO, JULIANO CARVALHO. Combination of Cu-Pt-Pd nanoparticles supported on graphene nanoribbons decorating the surface of TiO2 nanotube applied for CO2 photoelectrochemical reduction. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 4, . (19/04421-7, 17/10118-0, 15/18109-4)
CARDOSO, J. C.; STULP, S.; DE SOUZA, M. K. R.; HUDARI, F. F.; GUBIANI, J. R.; FREM, R. C. G.; ZANONI, M. V. B.. The effective role of ascorbic acid in the photoelectrocatalytic reduction of CO2 preconcentrated on TiO2 nanotubes modified by ZIF-8. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 856, . (15/18109-4)
FRANCO, JEFFERSON HONORIO; DA SILVA, BIANCA F.; DE CASTRO, ALEXANDRE A.; RAMALHO, TEODORICO C.; ISABEL PIVIDORI, MARIA; BOLDRIN ZANONI, MARIA VALNICE. Biotransformation of disperse dyes using nitroreductase immobilized on magnetic particles modified with tosyl group: Identification of products by LC-MS-MS and theoretical studies conducted with DNA. Environmental Pollution, v. 242, n. A, p. 863-871, . (08/10449-7, 15/18109-4)
SANCHEZ DE LA CRUZ, PAMELA TERESA; IRIKURA, KALLYNI; LACHGAR, ABDESSADEK; CARDOSO, JULIANO CARVALHO; ALARCON CAVERO, HUGO; BOLDRIN ZANONI, MARIA VALNICE. Preparation of FTO/CU2O Electrode Protected by PEDOT:PSS and Its Better Performance in the Photoelectrocatalytic Reduction of CO2 to Methanol. ELECTROCATALYSIS, v. 11, n. 5, . (17/12790-7, 15/18109-4)

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