Metal transportation and natural organic matter characterization from rivers of Itacoatiara, Amazônia

• Grant number: 15/22954-1
• Support Opportunities: Regular Research Grants
• Start date: February 01, 2016
• End date: September 30, 2018
• Field of knowledge: Physical Sciences and Mathematics - Chemistry
• Principal Investigator: Márcia Cristina Bisinoti
• Grantee: Márcia Cristina Bisinoti
• Host Institution: Instituto de Biociências, Letras e Ciências Exatas (IBILCE). Universidade Estadual Paulista (UNESP). Campus de São José do Rio Preto. São José do Rio Preto , SP, Brazil
• Associated researchers: Altair Benedito Moreira

Abstract

The natural organic matter (NOM) is critical in cycling elements in water bodies, presenting a more labile fraction and a more recalcitrant, and last is composed of humic substances. Several studies on the characterization of organic matter and quantification of macro and microelements have been conducted in the Amazon, but is largely absent in this approach Itacoatiara region. The main objective of this study is to determine the stock of metals and calculate how much is exported to the Amazon River, in addition to studying the organic matter of black water rivers through a characterization of humic substances, followed by quantification of labile organic matter and recalcitrant . To this end, sediment sampling will be carried (surface) and soil and two water samples at eight locations, five in water bodies of Itacoatiara region, two along the Amazon River and one on the Madeira River (representative of black waters and white). Will be held extraction and fractionation of aquatic humic substances (AHS) of Caru river (blackwater), followed by characterization by UV-Vis, IR spectroscopy, molecular fluorescence, 13 C nuclear magnetic resonance, Offline Tetramethylammonium Hydroxide (TMAH) - GC-MS thermochemolysis. The characterization will include study lability and recalcitrance of aquatic MON method using the kinetics consumption of hydrogen peroxide. In all the samples of sediment, soil and surface water will be quantified concentration of total dissolved metal (Cd, Cr, Ni, Zn, Fe, Mn, Pb, Cu and Ba) using Atomic Absorption Spectrophotometer with atomization Electrothermal (GFAAS) or with atomization by flame (FAAS). The analytical reliability of the results will be verified with the use of certified reference materials and continued participation of the Environmental Sciences Studies Laboratory Proficiency study for metals. With the results it can determine the inventory and how much is exported metal some tributaries to the Amazon River. As for the results of organic matter is expected this work to obtain a broad characterization of MON present in the region inferring their role in carbon cycling. (AU)

Scientific publications

(19)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DOS SANTOS, JOAO VITOR; FREGOLENTE, LAIS GOMES; LARANJA, MARCIO JUSTI; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; BISINOTI, MARCIA CRISTINA. Hydrothermal carbonization of sugarcane industry by-products and process water reuse: structural, morphological, and fuel properties of hydrochars. BIOMASS CONVERSION AND BIOREFINERY, APR 2021. (17/13230-5, 18/09914-9, 17/26718-6, 15/22954-1, 17/05408-9, 18/15733-7)

LARANJA, MARCIO J.; JUNIOR, FRANCISCO H. S.; NOGUEIRA, GABRIELA A.; VIEIRA, LAIS H. S.; OLIVEIRA, NAIARA C.; SOARES, JOAO M.; CORDEIRO, CARLOS H. N.; OTUBO, LARISSA; MOREIRA, ALTAIR B.; FERREIRA, ODAIR P.; et al. Valorisation of sugar cane bagasse using hydrothermal carbonisation in the preparation of magnetic carbon nanocomposite in a single-step synthesis applied to chromium adsorption. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, v. N/A, p. 15-pg., 2022-03-30. (18/15733-7, 15/22954-1, 17/26718-6, 17/13230-5, 21/09126-3, 13/21776-7, 14/22400-3, 12/23066-4, 11/00574-1, 14/10368-8)

BENTO, LUCAS RAIMUNDO; MELO, CAMILA ALMEIDA; FERREIRA, ODAIR PASTOR; MOREIRA, ALTAIR BENEDITO; MOUNIER, STEPHANE; PICCOLO, ALESSANDRO; SPACCINI, RICCARDO; BISINOTI, MARCIA CRISTINA. Humic extracts of hydrochar and Amazonian Dark Earth: Molecular characteristics and effects on maize seed germination. Science of The Total Environment, v. 708, MAR 15 2020. (15/22954-1, 18/15733-7, 17/05575-2, 17/17991-0)

DA SILVA, LEILA SOARES; CONSTANTINO, ISABELA CARREIRA; BENTO, LUCAS RAIMUNDO; TADINI, AMANDA MARIA; BISINOTI, MARCIA CRISTINA; BOSCOLO, MAURICIO; FERREIRA, ODAIR PASTOR; MOUNIER, STEPHANE; PICCOLO, ALESSANDRO; SPACCINI, RICCARDO; et al. Humic extracts from hydrochar and Amazonian Anthrosol: Molecular features and metal binding properties using EEM-PARAFAC and 2D FTIR correlation analyses. Chemosphere, v. 256, OCT 2020. (15/22954-1, 17/26718-6, 17/05575-2)

BENTO, LUCAS R.; CONSTANTINO, ISABELA C.; TADINI, AMANDA M.; MELO, CAMILA A.; FERREIRA, ODAIR P.; MOREIRA, ALTAIR B.; BISINOTI, MARCIA C.. Chemical and Spectroscopic Characteristics of Anthrosol (Amazonian Dark Earth) and Surrounding Soil from the Brazilian Amazon Forest: Evaluation of Mineral and Organic Matter Content by Depth. Journal of the Brazilian Chemical Society, v. 31, n. 8, p. 1623-1634, AUG 2020. (15/22954-1, 18/15733-7, 17/05575-2)

DOS SANTOS, JOAO VITOR; FREGOLENTE, LAIS GOMES; LARANJA, MARCIO JUSTI; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; BISINOTI, MARCIA CRISTINA. Hydrothermal carbonization of sugarcane industry by-products and process water reuse: structural, morphological, and fuel properties of hydrochars. BIOMASS CONVERSION AND BIOREFINERY, v. 12, n. 1, SI, p. 153-161, JAN 2022. (15/22954-1, 17/26718-6, 18/09914-9, 17/13230-5, 18/15733-7, 17/05408-9)

CONSTANTINO, ISABELA C.; TEODORO, GRAZIELLY C.; MOREIRA, ALTAIR B.; PASCHOAL, FABIANA M. M.; TRINDADE, WANDERSON G.; BISINOTI, MARCIA C.. Distribution of Metals in the Waters and Sediments of Rivers in Central Amazon Region, Brazil. Journal of the Brazilian Chemical Society, v. 30, n. 9, p. 1906-1915, SEP 2019. (15/22954-1, 18/15733-7)

ARIANE MAZIERO SANTANA; MÁRCIA CRISTINA BISINOTI; CAMILA ALMEIDA MELO; ODAIR PASTOR FERREIRA; ALTAIR BENEDITO MOREIRA. DISPONIBILIDADE DE NUTRIENTES E CARBONO ORGÂNICO EM SOLOS CONTENDO CARVÃO HIDROTÉRMICO LAVADO E NÃO LAVADO E COMPARAÇÃO COM SOLOS ANTROPOGÊNICOS. Química Nova, v. 42, n. 3, p. 262-272, 2019-05-02. (17/26718-6, 13/21776-7, 15/22954-1, 14/22400-3)

DOS SANTOS, JOAO VITOR; FREGOLENTE, LAIS GOMES; MOUNIER, STEPHANE; HAJJOUL, HOUSSAM; FERREIRA, ODAIR PASTOR; MOREIRA, ALTAIR BENEDITO; BISINOTI, MARCIA CRISTINA. Fulvic acids from Amazonian anthropogenic soils: Insight into the molecular composition and copper binding properties using fluorescence techniques. ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, v. 205, DEC 1 2020. (18/15733-7, 17/13230-5, 18/09914-9, 17/26718-6, 17/05408-9, 15/22954-1)

COELHO, ADONIS; PERRONE, OLAVO MICALI; GOMES, ELENI; DA-SILVA, ROBERTO; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Mixed metal oxides from sucrose and cornstarch templated hydrotalcite-like LDHs as catalysts for ethyl biodiesel synthesis. APPLIED CATALYSIS A-GENERAL, v. 532, p. 32-39, FEB 25 2017. (15/22954-1, 13/23886-4, 15/11588-4)

ISABELA C. CONSTANTINO; JULIANA G. VIANA; PRISCILA A. TEIXEIRA; ALTAIR B. MOREIRA; GIOVANNA P. GAMA; FABIANA M. M. PASCHOAL; ÉZIO SARGENTINI JR.; MÁRCIA C. BISINOTI. Interaction of Pb, Ni and Cd with Aquatic Humic Substances of Amazonian Blackwater Rivers. Journal of the Brazilian Chemical Society, v. 32, n. 2, p. 260-268, 2021-02-01. (15/22954-1)

FREGOLENTE, LAIS GOMES; AZEVEDO RANGEL MIGUEL, THAIZ BATISTA; MIGUEL, EMILIO DE CASTRO; MELO, CAMILA DE ALMEIDA; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; BISINOTI, MARCIA CRISTINA. Toxicity evaluation of process water from hydrothermal carbonization of sugarcane industry by-products. Environmental Science and Pollution Research, v. 26, n. 27, SI, p. 27579-27589, SEP 2019. (15/22954-1)

OLIVEIRA, NAIARA C.; PASCHOAL, ALEXANDRE R.; PAULA, RICARDO J.; CONSTANTINO, ISABELA C.; BISINOTI, MARCIA C.; MOREIRA, ALTAIR B.; FREGOLENTE, LAIS G.; SANTANA, ARIANE M.; SOUSA, FRANCISCO A.; FERREIRA, ODAIR P.; et al. Morphological analysis of soil particles at multiple length-scale reveals nutrient stocks of Amazonian Anthrosols. Geoderma, v. 311, p. 58-66, FEB 1 2018. (15/22954-1)

LARANJA, MARCIO JUSTI; JULIO DA SILVA, RENATA CRISTINA; BISINOTI, MARCIA CRISTINA; MOREIRA, ALTAIR BENEDITO; BOSCOLO, MAURICIO; FERREIRA, ODAIR PASTOR; MELO, CAMILA DE ALMEIDA. Factorial design of experiments for extraction and screening analysis of organic compounds in hydrochar and its process water of sugar cane bagasse and vinasse. BIOMASS CONVERSION AND BIOREFINERY, v. 12, n. 1, SI, p. 81-90, JAN 2022. (17/13230-5, 17/26718-6, 11/00574-1, 15/22954-1, 18/15733-7, 14/22400-3, 12/23066-4, 13/21776-7)

BENTO, LUCAS RAIMUNDO; RAMIRO CASTRO, ANTONIO JOEL; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; BISINOTI, MARCIA CRISTINA; MELO, CAMILA ALMEIDA. Release of nutrients and organic carbon in different soil types from hydrochar obtained using sugarcane bagasse and vinasse. Geoderma, v. 334, p. 24-32, JAN 15 2019. (15/22954-1, 13/21776-7, 15/00206-3)

FREGOLENTE, LAIS GOMES; AZEVEDO RANGEL MIGUEL, THAIZ BATISTA; MIGUEL, EMILIO DE CASTRO; MELO, CAMILA DE ALMEIDA; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; BISINOTI, MARCIA CRISTINA. Toxicity evaluation of process water from hydrothermal carbonization of sugarcane industry by-products. Environmental Science and Pollution Research, v. 26, n. 27, p. 11-pg., 2019-09-01. (15/22954-1)

DOS SANTOS, JOAO VITOR; FREGOLENTE, LAIS GOMES; MOREIRA, ALTAIR BENEDITO; FERREIRA, ODAIR PASTOR; MOUNIER, STEPHANE; VIGUIER, BRUNO; HAJJOUL, HOUSSAM; BISINOTI, MARCIA CRISTINA. Humic-like acids from hydrochars: Study of the metal complexation properties compared with humic acids from anthropogenic soils using PARAFAC and time-resolved fluorescence. Science of The Total Environment, v. 722, JUN 20 2020. (17/13230-5, 18/09914-9, 17/26718-6, 15/22954-1, 17/05408-9, 18/15733-7)

FREGOLENTE, LAIS G.; DOS SANTOS, JOAO VITOR; MAZZATI, FELIPE S.; MIGUEL, THAIZ B. A. R.; MIGUEL, EMILIO DE C.; MOREIRA, ALTAIR B.; FERREIRA, ODAIR P.; BISINOTI, MARCIA C.. Hydrochar from sugarcane industry by-products: assessment of its potential use as a soil conditioner by germination and growth of maize. CHEMICAL AND BIOLOGICAL TECHNOLOGIES IN AGRICULTURE, v. 8, n. 1, MAR 10 2021. (15/22954-1, 18/15733-7, 17/26718-6)

FREGOLENTE, LAIS G.; DOS SANTOS, JOAO VITOR; VINCI, GIOVANNI; PICCOLO, ALESSANDRO; MOREIRA, ALTAIR B.; FERREIRA, ODAIR P.; BISINOTI, MARCIA C.; SPACCINI, RICCARDO. Insights on Molecular Characteristics of Hydrochars by C-13-NMR and Off-Line TMAH-GC/MS and Assessment of Their Potential Use as Plant Growth Promoters. Molecules, v. 26, n. 4, FEB 2021. (15/22954-1, 18/15733-7, 17/26718-6)