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Biorefinery development integrated to a bioethanol sugar cane plant with zero CO2 emission: routes to convert renewable resources to bio-products and bio-electricity

Grant number: 15/20630-4
Support type:Research Projects - Thematic Grants
Duration: April 01, 2017 - March 31, 2022
Field of knowledge:Engineering - Chemical Engineering
Principal Investigator:Rubens Maciel Filho
Grantee:Rubens Maciel Filho
Home Institution: Faculdade de Engenharia Química (FEQ). Universidade Estadual de Campinas (UNICAMP). Campinas, SP, Brazil
Co-Principal Investigators:Francisco Maugeri Filho ; Maria Regina Wolf Maciel ; Reginaldo Guirardello
Assoc. researchers:Adriano Pinto Mariano ; Aline Carvalho da Costa ; André Luiz Jardini Munhoz ; Antonio Maria Francisco Luiz Jose Bonomi ; Aulus Roberto Romão Bineli ; Bruno Colling Klein ; Carlos Eduardo Vaz Rossell ; Daniele Farias ; Edvaldo Rodrigo de Morais ; Elmer Alberto Ccopa Rivera ; Francisco Maugeri Filho ; Laura Plazas Tovar ; Leonardo Vasconcelos Fregolente ; Luisa Fernanda Rios Pinto ; Maria Ingrid Rocha Barbosa Schiavon ; Marija Tasic ; Marina Oliveira de Souza Dias ; Otavio Cavalett ; Raphael Soeiro Suppino ; Rosana Goldbeck ; Sarita Candida Rabelo ; Tassia Lopes Junqueira ; Viktor Oswaldo Cardenas Concha
Associated grant(s):18/17966-9 - XVI Latin-American polymer symposium and XIV Iberoamerican polymer Congress, AR.EXT
18/02742-8 - International Conference on biomass - iconBM 2018, AR.EXT
17/14056-9 - Chlamydomonas reinhardtii cultivation in vinasse for bioethanol production, AV.EXT
17/08671-2 - 11th European Congress of Chemical Engineering, AR.EXT
Associated scholarship(s):19/01723-2 - Evaluation of heat and water integration alternatives of sugarcane biorefineries, BP.DD
18/20787-9 - Strategies for microalgae biomass saccharification targeting bioethanol 3G production, BP.DR
18/14223-5 - Obtaining symbiotic microcapsules of xylo-oligosaccharides from sugarcane straw, BP.MS
+ associated scholarships 18/25925-0 - N-butanol production from FERMENTATATION of sugar cane bagasse hemicellulosic hydrolysate with cell immobilization, BP.IC
17/27092-3 - Technoeconomic analysis of a sugarcane biorefinery with bio-based chemicals and optimized ethanol production, BP.PD
17/18401-2 - Adaptation of a catalytic reform reactor to block the cracking of organic gases in biomass thermo-conversion process, BP.IC
17/07633-0 - Mathematical modeling and evaluation of strategies of enzymatic hydrolysis of sugarcane bagasse at high solid loads, BP.MS
17/07390-0 - IBE production (isopropanol, butanol, and ethanol) from the fermentation of sugarcane bagasse lignocellulosic sugars mixed with molasses, BP.IC
17/03091-8 - Techno-economic and environmental assessment of biorefinery technologies, BP.PD
14/10064-9 - Biodiesel production from microalgae through in situ supercritical transesterification, BP.PD - associated scholarships

Abstract

An integrated process is proposed in this project, so as to maximize the productivity of biofuels and high added value chemicals from sugarcane molasses and bagasse and straw. The conceptual idea is to use the first generation bioethanol plant as the basis, for new processes development, since in such plants many facilities are already available as it is with electricity, steam, water and bagasse surplus, if the plant is optimized. The greenhouse gas carbon dioxide (CO2), generated in the production of biofuels, is proposed to be used in the production of ethanol, from algal biomass and catalytic transformation or biological fermentation of synthesis gas (syngas) as well as use this renewable carbon as molecule to obtain chemicals via chemical synthesis and fermentation; the use of supercritical CO2 (scCO2) has attracted much interest in order to facilitate various chemical processes and it will be considered as part of the some chemical route. This challenging integrated process has the major appeal of not emitting carbon dioxide and makes the best of the renewable carbon for producing biofuels and chemicals, turning it, when technically and economically feasible, a milestone to progress of Brazilian biorefinery. Worldwide, analyses reveal that a biorefinery integrating biofuels and chemicals offers potentially a much higher return on investment and meets its energy and economic goals simultaneously. (AU)

Scientific publications (6)
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
ROQUE, LAERTI REIS; MORGADO, GRAZIELLE PATRICIA; NASCIMENTO, VIVIANE MARCOS; IENCZAK, JACIANE LUTZ; RABELO, SARITA CANDIDA. Liquid-liquid extraction: A promising alternative for inhibitors removing of pentoses fermentation. FUEL, v. 242, p. 775-787, APR 15 2019. Web of Science Citations: 0.
MOTTA, INGRID LOPES; MIRANDA, NAHIEH TOSCANO; MACIEL FILHO, RUBENS; WOLF MACIEL, MARIA REGINA. Sugarcane bagasse gasification: Simulation and analysis of different operating parameters, fluidizing media, and gasifier types. BIOMASS & BIOENERGY, v. 122, p. 433-445, MAR 2019. Web of Science Citations: 0.
PIN, THAYNARA C.; NAKASU, PEDRO Y. S.; MATTEDI, SILVANA; RABELO, SARITA C.; COSTA, ALINE C. Screening of protic ionic liquids for sugarcane bagasse pretreatment. FUEL, v. 235, p. 1506-1514, JAN 1 2019. Web of Science Citations: 0.
LEAL SILVA, JEAN FELIPE; MARIANO, ADRIANO PINTO; MACIEL FILHO, RUBENS. Economic potential of 2-methyltetrahydrofuran (MTHF) and ethyl levulinate (EL) produced from hemicelluloses-derived furfural. BIOMASS & BIOENERGY, v. 119, p. 492-502, DEC 2018. Web of Science Citations: 0.
MOTTA, INGRID LOPES; MIRANDA, NAHIEH TOSCANO; MACIEL FILHO, RUBENS; WOLF MACIEL, MARIA REGINA. Biomass gasification in fluidized beds: A review of biomass moisture content and operating pressure effects. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, v. 94, p. 998-1023, OCT 2018. Web of Science Citations: 4.
FLEIG, OLIVIA PANIZ; LOPES, EMILIA SAVIOLI; RIVERA, ELMER CCOPA; MACIEL FILHO, RUBENS; TOVAR, LAURA PLAZAS. Concept of rice husk biorefining for levulinic acid production integrating three steps: Multi-response optimization, new perceptions and limitations. Process Biochemistry, v. 65, p. 146-156, FEB 2018. Web of Science Citations: 4.

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