Advanced search
Start date
Betweenand

pH Influence on catalytic glycerol electrooxidation on silver electrodes

Grant number: 14/07075-9
Support type:Scholarships in Brazil - Scientific Initiation
Effective date (Start): July 01, 2014
Effective date (End): July 10, 2016
Field of knowledge:Engineering - Chemical Engineering - Chemical Technology
Principal researcher:Janaina de Souza Garcia
Grantee:Nina Yumi Suzuki Dantas
Home Institution: Centro de Ciências Naturais e Humanas (CCNH). Universidade Federal do ABC (UFABC). Ministério da Educação (Brasil). Santo André , SP, Brazil

Abstract

This project aims to study and understand the mechanism of the electrocatalytic conversion of glycerol into more valuable commercial compounds. The issue is focused indirectly on the production of biodiesel in the Brazilian energy matrix. The glycerol, as byproduct in the biodiesel production, has led to a significant increase in the supply of this compound in domestic industrial market and hence a drop in the price traded. Thus, we seek in this project, with the aid of electrocatalysis, an alternative way of transforming glycerol into more valuable compounds, such as: glycolic, tartronic acid, glyceraldehyde, oxalic acid, dihydroxyacetone. However, very little is known about the conditions in which they can act with selectivity for the production of one or more products mentioned above. Thus, in this project we propose to work with silver electrocatalysts and identify, by means of High Performance Liquid Chromatography (HPLC), the products yielded during the electrooxidation reaction. The set of the results achieved will provide us knowledge to propose suitable routes and understand the minimum conditions for the selective production of compounds from glycerol.

News published in Agência FAPESP Newsletter about the scholarship:
Articles published in other media outlets (0 total):
More itemsLess items
VEICULO: TITULO (DATA)
VEICULO: TITULO (DATA)

Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
SUZUKI, NINA Y.; SANTIAGO, PATRICIA V. B.; GALHARDO, THALITA S.; CARVALHO, WAGNER A.; SOUZA-GARCIA, JANAINA; ANGELUCCI, CAMILO A. Insights of glycerol electrooxidation on polycrystalline silver electrode. Journal of Electroanalytical Chemistry, v. 780, p. 391-395, NOV 1 2016. Web of Science Citations: 10.

Please report errors in scientific publications list by writing to: cdi@fapesp.br.