Preparation of heavy metal oxide glasses fibers with optical and magneto-optical properties

• Grant number: 16/16900-9
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• Start date: April 01, 2017
• End date: March 31, 2021
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Inorganic Chemistry
• Agreement: Coordination of Improvement of Higher Education Personnel (CAPES)
• Principal Investigator: Marcelo Nalin
• Grantee: Douglas Faza Franco
• Host Institution: Instituto de Química (IQ). Universidade Estadual Paulista (UNESP). Campus de Araraquara. Araraquara , SP, Brazil
• Associated research grant: 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass, AP.CEPID
• Associated scholarship(s): 18/19272-4 - Production of heavy metal optical fibers to be used in Faraday rotators, BE.EP.PD

Abstract

This project aims the preparation and characterization of fibers presenting optical and magneto-optical properties based on heavy metal oxide glasses doped with different concentrations of paramagnetic species, such as transitions metals ions (Fe2+/ Fe3+ e Mn2+) and rare earth ions. Glasses will be obtained by melt quenching technique, and subsequently, core-shell preform will be prepared using the sucking method. The core-shell optical fibers will be prepared using a drawing tower. The thermal, structural and optical properties of precursors glasses and fibers will be studied by Thermal Analysis (DSC and DMTA), X-ray diffraction, UV-Vis-NIR, Raman and M-Lines spectroscopies, Optical microscopy and Luminescence. Investigations of the magneto-optical properties will be driven using a vibrating sample magnetometer and by Faraday rotation and, besides, the nonlinear optical properties of the magneto-optical fibers will be investigated. Raman and Brillouin scatter measurement will be studied using optical time domain reflectometry (OTDR) likewise, the possibility of characterization of others photonics properties will be evaluated. (AU)

Scientific publications

(11)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

FRANCO, DOUGLAS F.; MANZANI, DANILO; CARVAJAL, EDUAR E.; PRANDO, GABRIELA AUGUSTA; DONOSO, JOSE PEDRO; MAGON, CLAUDIO J.; ANTONIO, SELMA G.; GOBATO, YARA GALVAO; NALIN, MARCELO. Optical and EPR studies of zinc phosphate glasses containing Mn2+ ions. Journal of Materials Science, v. 55, n. 23, SI, MAY 2020. (18/16126-7, 16/10668-7, 13/07793-6, 16/16900-9)

FRANCO, DOUGLAS F.; CARVAJAL, EDUAR E.; DONOSO, JOSE PEDRO; SILVA, MAURICIO A. P.; SANT'ANA, ANTONIO C.; FARES, HSSEN; MAGON, CLAUDIO J.; NALIN, MARCELO. Structural and EPR studies of Cu(2+)ons in NaPO3 - Sb2O3 - CuO glasses. Journal of Non-Crystalline Solids, v. 503, p. 169-175, JAN 15 2019. (13/07793-6, 16/16900-9)

FRANCO, DOUGLAS F.; FERNANDES, ROGER G.; FELIX, JORLANDIO F.; MASTELARO, VALMOR R.; ECKERT, HELLMUT; AFONSO, CONRADO R. M.; MESSADDEQ, YOUNES; MESSADDEQ, SANDRA H.; MORENCY, STEEVE; NALIN, MARCELO. Fundamental studies of magneto-optical borogermanate glasses and derived optical fibers containing Tb3+. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 11, p. 312-327, MAR-APR 2021. (18/19272-4, 13/07793-6, 16/16900-9)

FRANCO, DOUGLAS F.; LEDEMI, YANNICK; CORRER, WAGNER; MORENCY, STEEVE; AFONSO, CONRADO R. M.; MESSADDEQ, SANDRA H.; MESSADDEQ, YOUNES; NALIN, MARCELO. Magneto-optical borogermanate glasses and fibers containing Tb3+. SCIENTIFIC REPORTS, v. 11, n. 1, MAY 10 2021. (16/16900-9, 13/07793-6, 18/19272-4)

CABRAL, THIAGO D.; FRANCO, DOUGLAS F.; FUJIWARA, ERIC; NALIN, MARCELO; CORDEIRO, CRISTIANO M. B.. Magnetic Field Fiber Specklegram Sensors Based on Tb³⁺-Doped Magneto-Optical Glasses With High Verdet Constants. IEEE SENSORS JOURNAL, v. 23, n. 7, p. 8-pg., 2023-04-01. (14/50632-6, 13/07793-6, 17/25666-2, 16/16900-9, 18/19272-4)

LAMARCA, RAFAELA SILVA; FRANCO, DOUGLAS FAZA; NALIN, MARCELO; FEITOSA DE LIMA GOMES, PAULO CLAIRMONT; MESSADDEQ, YOUNES. Label-Free Ultrasensitive and Environment-Friendly Immunosensor Based on a Silica Optical Fiber for the Determination of Ciprofloxacin in Wastewater Samples. Analytical Chemistry, v. 92, n. 21, p. 14415-14422, NOV 3 2020. (13/07793-6, 16/16900-9, 18/19272-4, 18/22393-8)

FARES, HSSEN; CASTRO, TARCIO; FRANCO, DOUGLAS FAZA; FUCIKOVA, ANNA; DA SILVA, ROBSON R.; VALENTA, JAN; RIBEIRO, SIDNEY J. L.; NALIN, MARCELO. Tuning multicolor emission in AgNCs/Tm3+/Mn2+-doped fluorophosphate glasses. Journal of Non-Crystalline Solids, v. 535, MAY 1 2020. (16/16343-2, 13/07793-6, 16/16900-9)

FRANCO, DOUGLAS F.; DE OLIVEIRA BARUD, HELIDA G.; BARUD, HERNANE S.; OLIVEIRA JUNIOR, OSMIR B.; MENEGUIN, ANDREIA B.; DE OLIVEIRA, LUIZ FERNANDO C.; SILVA, MAURICIO A. P.; RIBEIRO, SIDNEY J. L.; NALIN, MARCELO. A review on polyphosphate coacervates-structural properties and bioapplications. Journal of Sol-Gel Science and Technology, v. 94, n. 3, JAN 2020. (13/07793-6, 16/16900-9)

MANZANI, DANILO; FRANCO, DOUGLAS F.; AFONSO, CONRADO R. M.; SANT'ANA, ANTONIO C.; NALIN, MARCELO; RIBEIRO, SIDNEY J. L.. A new SERS substrate based on niobium lead-pyrophosphate glasses obtained by Ag+/Na+ ion exchange. SENSORS AND ACTUATORS B-CHEMICAL, v. 277, p. 347-352, DEC 20 2018. (13/07793-6, 16/16900-9)

DE BRITO, CAIQUE SERATI; RABAHI, CESAR RICARDO; TEODORO, MARCIO DALDIN; FRANCO, DOUGLAS F.; NALIN, MARCELO; BARCELOS, INGRID D.; GOBATO, YARA GALVAO. Strain engineering of quantum confinement in WSe2 on nano-roughness glass substrates. Applied Physics Letters, v. 121, n. 7, p. 7-pg., 2022-08-15. (19/23488-5, 16/16900-9, 19/14017-9, 18/19272-4, 13/07793-6)

FRANCO, DOUGLAS F.; MANZANI, DANILO; CARVAJAL, EDUAR E.; PRANDO, GABRIELA AUGUSTA; DONOSO, JOSE PEDRO; MAGON, CLAUDIO J.; ANTONIO, SELMA G.; GOBATO, YARA GALVAO; NALIN, MARCELO. Optical and EPR studies of zinc phosphate glasses containing Mn2+ ions. Journal of Materials Science, v. 55, n. 23, p. 14-pg., 2020-05-05. (16/16900-9, 18/16126-7, 13/07793-6, 16/10668-7)