Structural modification of triglycerides aiming new monomers and polymers, using different synthetic routes: microwave irradiation and photopolymerization

• Grant number: 18/03460-6
• Support Opportunities: Scholarships in Brazil - Doctorate
• Start date: June 01, 2018
• End date: May 02, 2022
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Gilbert Bannach
• Grantee: Rafael Turra Alarcon
• Host Institution: Faculdade de Ciências (FC). Universidade Estadual Paulista (UNESP). Campus de Bauru. Bauru , SP, Brazil
• Associated scholarship(s): 19/11493-4 - Chemical modification of Brazilian vegetable oils from macaw and baru nuts to find new monomers and polymers using maleinization, epoxidation, and carbonation syntheses, BE.EP.DR

Abstract

This project aims the synthesis and characterization of new monomers and polymers using as reactants vegetable oil (biomass), cyclic anhydrides, and polyol by two different synthetic routes (microwave and photopolymerization) following the Green Chemistry principles. The important point in this project is provide values to Brazilian bio-commodities, whereas the vegetable oil must be modified its chemical structure to increase the reactivity, yielding polymers. It is still intended in this project synthesize new polymer by photopolymerization using as reactants acrylic monomers with macromers obtained from reactions of different anhydrides, polyol, and vegetable oils. These new polymers will be characterized, and the results can provide the best applications. All the monomers and polymers are going to characterized by: Simultaneous Thermogravimetric/Derivative Thermogravimetry-Differential Thermal Analysis (TG/DTG-DTA), Differential Scanning Calorimetry (DSC), Scanning Electronic Microscopy (SEM), Fourier Transform Infrared Spectroscopy (MIR), Nuclear Magnetic Resonance (NMR 1H and 13C), High Resolution Mass Spectrometry (HRMS), as well as solvent resistance. (AU)

Scientific publications

(21)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ALARCON, RAFAEL T.; LAMB, KATIE J.; BANNACH, GILBERT; NORTH, MICHAEL. Opportunities for the Use of Brazilian Biomass to Produce Renewable Chemicals and Materials. CHEMSUSCHEM, v. 14, n. 1, p. 169-188, JAN 7 2021. (18/03460-6, 17/08820-8, 19/11493-4)

MAGRI, RAQUEL; GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; BANNACH, GILBERT. Epoxidation reaction in promising Brazilian biomass: decreased time and catalyst loading to produce renewable monomers. JOURNAL OF POLYMER RESEARCH, v. 28, n. 9, SEP 2021. (18/03460-6, 20/00906-3, 17/08820-8)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY C.; MORALLES, ANA C.; MORGON, NELSON H.; DE SOUZA, AGUINALDO R.; BANNACH, GILBERT. AIE Effect by Oxygen Clustering in Vegetable Oil-Based Polymers. CHEMISTRYSELECT, v. 6, n. 31, p. 7838-7844, AUG 20 2021. (13/08293-7, 18/03460-6, 17/08820-8, 15/22338-9)

FERREIRA, LAURA TEOFILO; ALARCON, RAFAEL TURRA; PERPETUO, GLAUCO LINI; BANNACH, GILBERT. Investigation and characterization by TG/DTG-DTA and DSC of the fusion of Riboflavin, and its interaction with the antibiotic norfloxacin in the screening of cocrystal. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 136, n. 2, p. 581-588, APR 2019. (13/09022-7, 18/03460-6, 17/08820-8)

GAGLIERI, CAROLINE; ALARCON, RAFAEL T.; DE MOURA, ANIELE; MAGRI, RAQUEL; DA SILVA-FILHO, LUIZ C.; BANNACH, GILBERT. Green and Efficient Modification of Grape Seed Oil to Synthesize Renewable Monomers. Journal of the Brazilian Chemical Society, v. 32, n. 11, p. 2120-2131, NOV 2021. (20/00906-3, 17/08820-8, 18/03460-6)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; CAVALHEIRO, EDER T. G.; NORTH, MICHAEL; BANNACH, GILBERT. A new acrylated monomer from macaw vegetable oil that polymerizes without external photoinitiators. JOURNAL OF POLYMER RESEARCH, v. 28, n. 11, NOV 2021. (18/03460-6, 17/08820-8)

DA SILVA TANAKA, ALINE CRISTINA; DOS SANTOS, GIOVANNY CARVALHO; ALARCON, RAFAEL TURRA; DA SILVA FILHO, LUIZ CARLOS; ROSIFINI ALVES REZENDE, MARIA CRISTINA. Effect of the Incorporation of EDB Co-initiator in the Resin in Halogen and LED Light. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 24, n. 1, 2021. (18/03460-6)

MAGRI, RAQUEL; GAGLIERI, CAROLINE; ALARCON, RAFAEL TURRA; DE SOUZA, AGUINALDO ROBINSON; BANNACH, GILBERT. MICROLEARNING AS A TOOL FOR SCIENTIFIC DISSEMINATION: THERMAL ANALYSIS OF THE PORTUGUESE GOOD LUCK ROOSTER. Química Nova, NOV 2021. (18/03460-6)

ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DE SOUZA, OTAVIO A.; RINALDO, DANIEL; BANNACH, GILBERT. Microwave-Assisted Syntheses of Vegetable Oil-Based Monomer: A Cleaner, Faster, and More Energy Efficient Route. JOURNAL OF POLYMERS AND THE ENVIRONMENT, v. 28, n. 4, FEB 2020. (18/03460-6, 17/08820-8)

RODRIGUES, EDGAR JUNIO DAMASCENO; DE CARVALHO, PEDRO LUIZ PUCCI FIGUEIREDO; XAVIER, WILLIAM DOS SANTOS; GUIMARAES, MATHEUS GARDIM; VICENTE, IGOR SIMOES TIAGUA; BARROS, MARGARIDA MARIA; SARTORI, MARIA MARCIA PEREIRA; PADILHA, PEDRO DE MAGALHAES; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; et al. Plant-based polymer as a thermoresistant carrier of phytase in Nile tilapia (Oreochromis niloticus) diets. ANIMAL FEED SCIENCE AND TECHNOLOGY, v. 296, p. 6-pg., 2023-01-02. (18/03460-6, 18/19293-1, 17/08820-8)

BENITES, ANA BEATRIZ; ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; LAMB, KATIE J.; BANNACH, GILBERT. Effect of metal oxide fillers in urethane dimethacrylate polymer with glycerol obtained by photopolymerization synthesis. JOURNAL OF POLYMER RESEARCH, v. 27, n. 10, p. 11-pg., 2020-09-28. (17/08820-8, 18/03460-6, 19/11493-4)

ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY CARVALHO; ROLDAO, JUAN CARLOS; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. A deep investigation into the thermal degradation of urethane dimethacrylate polymer. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, APR 2021. (18/03460-6, 15/00615-0, 16/01599-1, 17/08820-8, 18/14506-7)

MACHADO, RAFAEL DE GODOI; GAGLIERI, CAROLINE; ALARCON, RAFAEL TURRA; DE MOURA, ANIELE; DE ALMEIDA, AMANDA COSMO; CAIRES, FLAVIO JUNIOR; IONASHIRO, MASSAO. Cobalt selenate pentahydrate: Thermal decomposition intermediates and their properties dependence on temperature changes. Thermochimica Acta, v. 689, JUL 2020. (18/24378-6, 17/14936-9, 18/03460-6)

GAGLIERI, CAROLINE; DE MOURA, ANIELE; ALARCON, RAFAEL T.; MAGRI, RAQUEL; BANNACH, GILBERT. Thermal behavior of some cyclic anhydrides: an important characterization for synthesis in the polymer field. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. N/A, p. 12-pg., 2022-01-23. (20/00906-3, 18/03460-6, 17/08820-8)

HOLANDA, BRUNO B. C.; ALARCON, RAFAEL T.; GUERRA, RENAN B.; RINALDO, DANIEL; SPAZZINI, FABIOLA C. R.; CASTRO, RICARDO A. E.; BANNACH, GILBERT. Investigation of thermal degradation products of mebendazole by thermal and spectroscopic analysis. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, v. 135, p. 76-84, OCT 2018. (18/03460-6, 17/08820-8)

BALDO PIRES, OSMAR ANTONIO; ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. Synthesis and characterization of a biopolymer of glycerol and macadamia oil. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 137, n. 1, p. 161-170, JUL 2019. (17/08820-8, 15/00615-0, 16/01599-1, 18/03460-6, 13/09022-7)

ALARCON, RAFAEL TURRA; DOS SANTOS, GIOVANNY CARVALHO; DE OLIVEIRA, ARTHUR ROSSI; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. Synthesis of luminescent polymers in the UV light region from dimethacrylate monomer using novel quinoline dyes. Journal of Applied Polymer Science, v. 136, n. 19, MAY 15 2019. (13/09022-7, 18/03460-6, 16/01599-1, 18/14506-7, 15/00615-0, 17/08820-8)

HOLANDA, BRUNO B. C.; ALARCON, RAFAEL T.; GAGLIERI, CAROLINE; DE SOUZA, AGUINALDO R.; CASTRO, RICARDO A. E.; ROSA, PAULO C. P.; TANGERINO, DEBORA J. A.; BANNACH, GILBERT. Thermal studies, degradation kinetic, equilibrium solubility, DFT, MIR, and XRPD analyses of a new cocrystal of gemfibrozil and isonicotinamide. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 136, n. 5, p. 2049-2062, JUN 2019. (13/09022-7, 18/03460-6, 13/07296-2, 15/22338-9)

ALARCON, RAFAEL TURRA; GAGLIERI, CAROLINE; DOS SANTOS, GIOVANNY CARVALHO; ROLDAO, JUAN CARLOS; MAGDALENA, AROLDO GERALDO; DA SILVA-FILHO, LUIZ CARLOS; BANNACH, GILBERT. A deep investigation into the thermal degradation of urethane dimethacrylate polymer. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, v. 147, n. 4, p. 3083-3097, FEB 2022. (16/01599-1, 17/08820-8, 18/03460-6, 18/14506-7, 15/00615-0)

DE MOURA, ANIELE; GAGLIERI, CAROLINE; ALARCON, RAFAEL TURRA; FERREIRA, LAURA TEOFILO; VECCHI, RAFAEL; ROVIS SANCHES, MARIANA LIESSA; DE OLIVEIRA, RODRIGO CARDOSO; VENTURINI, JAMES; DA SILVA-FILHO, LUIZ CARLOS; CAIRES, FLAVIO JUNIOR. A New Curcuminoids-Coumarin Derivative: Mechanochemical Synthesis, Characterization and Evaluation of Its In Vitro Cytotoxicity and Antimicrobial Properties. CHEMISTRYSELECT, v. 6, n. 41, p. 11352-11361, NOV 8 2021. (13/07296-2, 18/03460-6, 18/14506-7, 18/24378-6)

GAGLIERI, CAROLINE; ALARCON, RAFAEL TURRA; MAGRI, RAQUEL; NORTH, MICHAEL; BANNACH, GILBERT. Development of renewable thermosetting polymers based on grape seed oil derivatives. Journal of Applied Polymer Science, v. 139, n. 41, p. 13-pg., 2022-08-12. (18/03460-6, 13/07793-6, 21/02152-9)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

ALARCON, Rafael Turra. Structural Modification of triacylglycerols to obtain monomers and polymers following Principles of Green Chemistry: Efficient synthetic pathways with less energy spending.. 2022. Doctoral Thesis - Universidade Estadual Paulista (Unesp). Faculdade de Ciências. Bauru Bauru.