Use of Localized Electrochemical Techniques for the Study of Corrosion of of High Strength Aluminum Alloys Joined by Friction (FSW).

• Grant number: 18/06880-6
• Support Opportunities: Scholarships in Brazil - Post-Doctoral
• Effective date (Start): July 01, 2018
• Effective date (End): June 30, 2022
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Physical Metallurgy
• Principal Investigator: Isolda Costa
• Grantee: Rejane Maria Pereira da Silva
• Host Institution: Instituto de Pesquisas Energéticas e Nucleares (IPEN). Secretaria de Desenvolvimento Econômico (São Paulo - Estado). São Paulo , SP, Brazil
• Associated research grant: 13/13235-6 - Investigation on the localized corrosion and the fatigue corrosion resistance of high strength aluminum alloys joined by friction stir welding (FSW), AP.TEM
• Associated scholarship(s): 19/11427-1 - Micro-electrochemical techniques to study the localized corrosion in Al-Cu-Li alloys joined by friction stir welding (FSW), BE.EP.PD

Abstract

This project aims to study the corrosion of aluminum alloys with high mechanical resistance (Al-Cu-Li), aeronautical grade, joined by FSW by means of localized electrochemical techniques with high spatial resolution, such as the Localized Electrochemical Impedance Spectroscopy (LEIS), Scanning Vibrating Electrode Technique (SVET) and Scanning Electrochemical Microscopy (SECM) techniques. These techniques will allow to identify the formation of galvanic pairs, to determine anodic and cathodic regions, and to study the local electrochemical reactivity, aiming to identify localized attacks caused by microstructural characteristics, and how the changes resulting from the welding process modify the susceptibility to corrosion of the different regions.

Scientific publications

(18)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

CARVALHO MACHADO, CARULINE DE SOUZA; PEREIRA DA SILVA, REJANE MARIA; DE SOUSA ARAUJO, JOAO VICTOR; MILAGRE, MARIANA XAVIER; DONATUS, UYIME; GONCALVES DE VIVEIROS, BARBARA VICTORIA; KLUMPP, RAFAEL EMIL; COSTA, ISOLDA. Influence of chloride ions concentration on the development of severe localised corrosion and its effects on the electrochemical response of the 2198-T8 alloy. CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, DEC 2020. (13/13235-6, 18/06880-6, 17/03095-3)

CARVALHO MACHADO, CARULINE DE SOUZA; PEREIRA DA SILVA, REJANE MARIA; DE SOUSA ARAUJO, JOAO VICTOR; MILAGRE, MARIANA XAVIER; DONATUS, UYIME; GONCALVES DE VIVEIROS, BARBARA VICTORIA; KLUMPP, RAFAEL EMIL; COSTA, ISOLDA. Influence of chloride ions concentration on the development of severe localised corrosion and its effects on the electrochemical response of the 2198-T8 alloy. CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, v. 56, n. 4, p. 341-350, MAY 19 2021. (18/06880-6, 13/13235-6, 17/03095-3)

DA SILVA, REJANE MARIA P.; IZQUIERDO, JAVIER; MILAGRE, MARIANA X.; BETANCOR-ABREU, ABENCHARA MARIA; DE OLIVEIRA, LEANDRO A.; ANTUNES, RENATO A.; SOUTO, RICARDO M.; COSTA, ISOLDA. On the local corrosion behavior of coupled welded zones of the 2098-T351 Al-Cu-Li alloy produced by Friction Stir Welding (FSW): An amperometric and potentiometric microelectrochemical investigation. Electrochimica Acta, v. 373, MAR 20 2021. (19/11427-1, 13/13235-6, 18/06880-6)

DA SILVA, REJANE M. P.; IZQUIERDO, JAVIER; MILAGRE, MARIANA X.; BETANCOR-ABREU, ABENCHARA M.; COSTA, ISOLDA; SOUTO, RICARDO M.. Use of Amperometric and Potentiometric Probes in Scanning Electrochemical Microscopy for the Spatially-Resolved Monitoring of Severe Localized Corrosion Sites on Aluminum Alloy 2098-T351. SENSORS, v. 21, n. 4, FEB 2021. (13/13235-6, 18/06880-6, 19/11427-1)

DONATUS, UYIME; PEREIRA DA SILVA, REJANE MARIA; DE SOUSA ARAUJO, JOAO VICTOR; MILAGRE, MARIANA XAVIER; DE ABREU, CAIO PALUMBO; CARVALHO MACHADO, CARULINE DE SOUZA; COSTA, ISOLDA. Macro and microgalvanic interactions in friction stir weldment of AA2198-T851 alloy. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 8, n. 6, p. 6209-6222, NOV-DEC 2019. (13/13235-6, 18/06880-6, 17/03095-3)

DE VIVEIROS, BARBARA VICTORIA G.; DA SILVA, REJANE MARIA P.; DONATUS, UYIME; COSTA, ISOLDA. Welding and galvanic coupling effects on the electrochemical activity of dissimilar AA2050 and AA7050 aluminum alloys welded by Friction Stir Welding (FSW). Electrochimica Acta, v. 449, p. 15-pg., 2023-03-20. (18/06880-6, 17/03095-3, 13/13235-6)

MILAGRE, MARIANA X.; DONATUS, UYIME; SILVA, REJANE MARIA P.; BETANCOR-ABREU, ABENCHARA M.; PRADA RAMIREZ, OSCAR M.; MACHADO, CARULINE S. C.; ARAUJO, JOAO VICTOR S.; SOUTO, RICARDO M.; COSTA, ISOLDA. Galvanic coupling effects on the corrosion behavior of the 6061 aluminum alloy used in research nuclear reactors. JOURNAL OF NUCLEAR MATERIALS, v. 541, p. 11-pg., 2020-12-01. (18/06880-6)

MILAGRE, MARIANA X.; DONATUS, UYIME; MOGILI, V, NAGA; SILVA, REJANE MARIA P.; DE VIVEIROS, BARBARA VICTORIA G.; PEREIRA, VICTOR F.; ANTUNES, RENATO A.; MACHADO, CARULINE S. C.; ARAUJO, JOAO VICTOR S.; COSTA, ISOLDA. Galvanic and asymmetry effects on the local electrochemical behavior of the 2098-T351 alloy welded by friction stir welding. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, v. 45, p. 162-175, MAY 15 2020. (13/13235-6, 18/06880-6, 17/03095-3)

JOÃO VICTOR DE SOUSA ARAUJO; REJANE MARIA PEREIRA DA SILVA; UYIME DONATUS; CARULINE DE SOUZA CARVALHO MACHADO; ISOLDA COSTA. Microstructural, Electrochemical and Localized Corrosion Characterization of the AA2198-T851 Alloy. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 23, n. 4, 2020-09-14. (19/18388-1, 16/20572-7, 18/06880-6)

BARBOZA, WANESSA DAS GRACAS; MILAGRE, MARIANA XAVIER; DONATUS, UYIME; CARVALHO MACHADO, CARULINE DE SOUZA; PRADA RAMIREZ, OSCAR MAURICIO; DE SOUSA ARAUJO, JOAO VICTOR; PEREIRA DA SILVA, REJANE MARIA; COSTA, ISOLDA. Corrosion behaviour of the 2098-T351 Al-Cu-Li alloy after different surface treatments. CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, v. 57, n. 3, p. 11-pg., 2022-03-29. (18/06880-6)

REJANE MARIA P. DA SILVA; MARIANA X. MILAGRE; JOÃO VICTOR DE S. ARAUJO; OSCAR MAURICIO P. RAMIREZ; CARULINE DE SOUZA C. MACHADO; RENATO A. ANTUNES; ISOLDA COSTA. Investigação da atividade eletroquímica de liga Al-Cu-Li após processo de soldagem por fricção e mistura. Química Nova, v. 46, n. 4, p. 307-318, 2023-05-29. (19/18388-1, 13/13235-6, 18/06880-6)

JOÃO VICTOR DE SOUSA ARAUJO; REJANE MARIA PEREIRA DA SILVA; MARIANA XAVIER MILAGRE; CARULINE DE SOUZA CARVALHO MACHADO; ISOLDA COSTA. MECANISMO DE EVOLUÇÃO DE HIDROGÊNIO DURANTE A CORROSÃO DA LIGA 2198-T8 EM MEIO CONTENDO CLORETO: UMA ABORDAGEM ELETROQUÍMICA. Química Nova, v. 43, n. 8, p. 1058-1065, 2020-10-16. (19/18388-1, 18/06880-6)

DA SILVA, REJANE MARIA P.; MILAGRE, MARIANA X.; DE OLIVEIRA, LEANDRO A.; DONATUS, UYIME; ANTUNES, RENATO A.; COSTA, ISOLDA. The local electrochemical behavior of the AA2098-T351 and surface preparation effects investigated by scanning electrochemical microscopy. SURFACE AND INTERFACE ANALYSIS, v. 51, n. 10, JULY 2019. (18/06880-6, 13/13235-6)

MILAGRE, MARIANA X.; DONATUS, UYIME; MACHADO, CARULINE S. C.; ARAUJO, JOAO VICTOR S.; DA SILVA, REJANE MARIA P.; DE VIVEIROS, BARBARA VICTORIA G.; ASTARITA, ANTONELLO; COSTA, ISOLDA. Comparison of the corrosion resistance of an Al-Cu alloy and an Al-Cu-Li alloy. CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, v. 54, n. 5, p. 1-11, APR 2019. (13/13235-6, 18/06880-6, 17/03095-3)

MILAGRE, MARIANA X.; DONATUA, UYIME; MACHADO, CARULINE S. C.; ARAUJO, JOAO VICTOR S.; FERREIRA, RAPHAEL O.; SILVA, REJANE MARIA P.; ANTUNES, RENATO A.; COSTA, ISOLDA. Exfoliation corrosion susceptibility in the zones of friction stir welded AA2098-T351. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 8, n. 6, p. 5916-5929, NOV-DEC 2019. (13/13235-6, 18/06880-6, 17/03095-3)

DA SILVA, REJANE MARIA P.; IZQUIERDO, JAVIER; MILAGRE, MARIANA X.; ARAUJO, JOAO VICTOR DE S.; ANTUNES, RENATO A.; SOUTO, RICARDO M.; COSTA, ISOLDA. Electrochemical characterization of alloy segregation in the near-surface deformed layer of welded zones of an Al-Cu-Li alloy using scanning electrochemical microscopy. Electrochimica Acta, v. 427, p. 7-pg., 2022-07-20. (13/13235-6, 18/06880-6, 19/11427-1)

JOÃO VICTOR DE SOUSA ARAUJO; REJANE MARIA PEREIRA DA SILVA; BÁRBARA VICTORIA VIVEIROS; MARIANA XAVIER MILAGRE; CARULINE DE SOUZA CARVALHO MACHADO; ISOLDA COSTA. COMPREENDENDO OS MECANISMOS DE CORROSÃO DE LIGAS DE AL-CU-LI: UMA INVESTIGAÇÃO ATRAVÉS DE TÉCNICAS ELETROQUÍMICAS GLOBAIS E LOCAIS. Química Nova, v. 45, n. 6, p. 680-689, 2022-08-29. (18/06880-6)

DA SILVA, REJANE MARIA P.; MILAGRE, MARIANA X.; IZQUIERDO, JAVIER; BETANCOR-ABREU, ABENCHARA MARIA; DE OLIVEIRA, LEANDRO A.; ARAUJO, JOAO VICTOR DE S.; ANTUNES, RENATO A.; SOUTO, RICARDO M.; COSTA, ISOLDA. Surface finishing effects on the corrosion behavior and electrochemical activity of 2098-T351 aluminum alloy investigated using scanning microelectrochemical techniques. MATERIALS CHARACTERIZATION, v. 191, p. 12-pg., 2022-07-18. (13/13235-6, 19/11427-1, 18/06880-6)