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Exploration of Enantioselective Transformations of Diazoketones and Sulfoxonium Ylides

Grant number: 19/05002-8
Support type:Scholarships in Brazil - Post-Doctorate
Effective date (Start): August 01, 2019
Effective date (End): July 31, 2021
Field of knowledge:Physical Sciences and Mathematics - Chemistry - Organic Chemistry
Principal Investigator:Antonio Carlos Bender Burtoloso
Grantee:David Philip Day
Home Institution: Instituto de Química de São Carlos (IQSC). Universidade de São Paulo (USP). São Carlos , SP, Brazil


The research proposed provides a unified catalytic strategy using chiral Brønsted acids to access carbon-oxygen, carbon-nitrogen, carbon-sulfur and carbon-halogen bonds from either diazoketones or sulfoxonium ylides as starting materials.

Scientific publications
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
MORA VARGAS, JORGE ANDRES; DAY, DAVID P.; BURTOLOSO, ANTONIO C. B. Substituted Naphthols: Preparations, Applications, and Reactions. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, NOV 2020. Web of Science Citations: 0.
GALLO, RAFAEL D. C.; MOMO, PATRICIA B.; DAY, DAVID P.; BURTOLOSO, ANTONIO C. B. Catalytic Friedel-Crafts Alkylation of Electron Rich Aromatic Derivatives with alpha-Aryl Diazoacetates Mediated by Bronsted Acids. ORGANIC LETTERS, v. 22, n. 6, p. 2339-2343, MAR 20 2020. Web of Science Citations: 0.

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