Single-photon emission from point defects and substrate-induced hot spots in two-dimensional semiconductors: a scanning tunnelling microscopy-induced luminescence study

• Grant number: 20/12480-0
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate
• Effective date (Start): March 29, 2021
• Effective date (End): August 30, 2021
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Luiz Fernando Zagonel
• Grantee: Ricardo Javier Peña Román
• Supervisor: Eric Le Moal
• Host Institution: Instituto de Física Gleb Wataghin (IFGW). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Research place: Institut des Sciences Moléculaires d’Orsay (ISMO), France
• Associated to the scholarship: 18/08543-7 - Light emission by individual defects in 2D materials, BP.DR

Abstract

In this project, we will experimentally investigate the role of defects in the luminescence properties of two-dimensional (2D) semiconductors that are of paramount importance for future optoelectronics, i.e., monolayer transition metal dichalcogenides (TMDs). We will carry out such investigations on the nanometer scale using a combination of scanning tunnelling microscopy (STM) and optical spectroscopy and microscopy. We will consider both point defects in the 2D semiconductor, i.e., atomic vacancies or substitutional atoms, and more "mesoscopic" highly luminescent areas, or hot spots, engineered through local interactions with underlying plasmonic nanostructures (i.e., mechanical strain, Purcell effect, electronic doping, etc.). The goals of the project are to gain fundamental understanding on how to tailor the TMDs in order to obtain single-photon nanosources that have enhanced quantum yield (i.e., low losses) and improved electro-luminescence efficiency (i.e., high electron-to-photon conversion rate). (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

PENA ROMAN, RICARDO JAVIER; POMMIER, DELPHINE; BRETEL, REMI; LOPEZ, LUIS E. PARRA; LORCHAT, ETIENNE; CHASTE, JULIEN; OUERGHI, ABDELKARIM; LE MOAL, SEVERINE; BOER-DUCHEMIN, ELIZABETH; DUJARDIN, GERALD; et al. Electroluminescence of monolayer WS2 in a scanning tunneling microscope: Effect of bias polarity on spectral and angular distribution of emitted light. PHYSICAL REVIEW B, v. 106, n. 8, p. 7-pg., 2022-08-24. (18/08543-7, 20/12480-0, 14/23399-9)

PENA ROMAN, RICARDO JAVIER; BRETEL, REMI; POMMIER, DELPHINE; LOPEZ, LUIS ENRIQUE PARRA; LORCHAT, ETIENNE; BOER-DUCHEMIN, ELIZABETH; DUJARDIN, GERALD; BORISOV, ANDREI G.; ZAGONEL, LUIZ FERNANDO; SCHULL, GUILLAUME; et al. Tip-Induced and Electrical Control of the Photoluminescence Yield of Monolayer WS2. Nano Letters, v. 22, n. 23, p. 8-pg., 2022-12-14. (20/12480-0, 14/23399-9, 18/08543-7)