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Study of the replacement of tartrazine yellow dye by Pequi carotenoids extracted using high performance ionic liquids

Grant number: 21/00596-7
Support Opportunities:Scholarships in Brazil - Doctorate (Direct)
Start date: June 01, 2021
End date: May 31, 2026
Field of knowledge:Agronomical Sciences - Food Science and Technology - Food Science
Principal Investigator:Veridiana Vera de Rosso
Grantee:Caroline Ramos da Silva Souza
Host Institution: Instituto de Saúde e Sociedade (ISS). Universidade Federal de São Paulo (UNIFESP). Campus Baixada Santista. Santos , SP, Brazil
Associated scholarship(s):24/10635-8 - Bigels for 3D food printing with pequi carotenoids incorporated: Insights about in vitro dynamic gastrointestinal digestion, cytotoxicity and antioxidant bioactivity assessment, BE.EP.DD

Abstract

Consumer requirements for purchasing processed food have increased considerably, especially speaking about food additives, searching for "clean label" and/or 100% natural food has been a trend. In this context, finding alternatives to synthetic dyes has become urgent. In order to achieve this objective, different strategies are set as goals aiming the application of natural dyes in industrialized foods, in order to maintain stability and color under adverse conditions of industrial processing. The development of new extraction methods to replace the use of volatile organic solvents is one of the trends for obtaining extracts of natural pigments. This way, the purpose of this project is to obtain a carotenoid extract from the Brazilian tropical fruit known as Pequi (Caryocar brasiliense) to replace the synthetic yellow dye tartrazine, by a high-performance extraction method using ionic liquids such as "green" extractors. Therefore, four ionic liquids will be tested, 1-n-butyl-3-methylimidazolium tetrafluoroborate and 1-n-hexyl-3-methylimidazolium chloride of commercial origin; and 1-n-butyl-3-methylimidazolium chloride and 1-n-butyl-3-methylimidazolium hexafluorophosphate synthesized in laboratory, so that the best two owns will be selected for the optimization of extraction using the technique of experimental planning and response surface. The qualitative and quantitative evaluation of the carotenoid extracts obtained will be performed by HPLC-PAD-MS/MS. Subsequently, the carotenoid extract obtained under optimized conditions will be applied for the development of nanocapsules and bio-ink for 3D printing. These two systems will be evaluated for antioxidant activity, bioaccessibility and uptake in a cellular model (CACO2). The set of these results will allow defining if Pequi carotenoid extract can be presented as an alternative to the artificial yellow dye tartrazine. (AU)

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Scientific publications (5)
(The scientific publications listed on this page originate from the Web of Science or SciELO databases. Their authors have cited FAPESP grant or fellowship project numbers awarded to Principal Investigators or Fellowship Recipients, whether or not they are among the authors. This information is collected automatically and retrieved directly from those bibliometric databases.)
RAMOS-SOUZA, CAROLINE; BANDONI, DANIEL HENRIQUE; ARISSETO BRAGOTTO, ADRIANA PAVESI; DE ROSSO, VERIDIANA VERA. Risk assessment of azo dyes as food additives: Revision and discussion of data gaps toward their improvement. COMPREHENSIVE REVIEWS IN FOOD SCIENCE AND FOOD SAFETY, v. N/A, p. 28-pg., . (21/02692-3, 21/00596-7)
RAMOS-SOUZA, CAROLINE; NASS, PRICILA; JACOB-LOPES, EDUARDO; ZEPKA, LEILA QUEIROZ; BRAGA, ANNA RAFAELA CAVALCANTE; DE ROSSO, VERIDIANA VERA. Changing Despicable Me: Potential replacement of azo dye yellow tartrazine for pequi carotenoids employing ionic liquids as high-performance extractors. Food Research International, v. 174, p. 12-pg., . (21/00596-7, 21/02692-3)
RAMOS-SOUZA, CAROLINE; BANDONI, DANIEL HENRIQUE; DE ROSSO, VERIDIANA VERA. Color Development in Carotenoid-Enriched Bigels: Effects of Extraction Method, Saponification, and Oleogel-to-Hydrogel Ratios on CIELAB Parameters. GELS, v. 11, n. 10, p. 16-pg., . (24/10635-8, 21/02692-3, 21/00596-7)
RAMOS-SOUZA, CAROLINE; DA TRINDADE, LETICIA GUERREIRO; BRAGA, ANNA RAFAELA CAVALCANTE; PERRECHIL, FABIANA; DE ROSSO, VERIDIANA VERA. Electrospun microfibers of zein and polyethylene oxide: A study on pequi carotenoid encapsulation. FOOD HYDROCOLLOIDS, v. 166, p. 4-pg., . (21/00596-7, 21/02692-3)
RAMOS-SOUZA, CAROLINE; FERNANDES, ANDRESSA SILVA; MAZZO, TATIANA MARTELLI; PERRECHIL, FABIANA; DE ROSSO, VERIDIANA VERA. Fine-tuning carotenoid-enriched bigel formulations: Exploring the influence of Oleogel: Hydrogel ratio on physicochemical properties and 3D food printing. FOOD HYDROCOLLOIDS, v. 164, p. 15-pg., . (21/00596-7, 21/02692-3)