Novel boron-doped ultra nanocrystalline diamond/dioxide titanium nanotube/titanium (B-UNCDws/DTNT/Ti) as a porous composite to remove emergent pollutants from gases and urine

• Grant number: 21/07615-7
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate (Direct)
• Start date: February 01, 2022
• End date: January 31, 2023
• Field of knowledge: Engineering - Materials and Metallurgical Engineering
• Principal Investigator: Neidenei Gomes Ferreira
• Grantee: Laís Gimenes Vernasqui
• Supervisor: Manuel Andrés Rodrigo Rodrigo
• Host Institution: Instituto Nacional de Pesquisas Espaciais (INPE). São José dos Campos , SP, Brazil
• Institution abroad: Universidad de Castilla-La Mancha, Ciudad Real (UCLM), Spain
• Associated to the scholarship: 19/00592-1 - Degradation of carbamate agrochemicals from Advanced Oxidation Electrochemical Processes (AOEP) using boron doped diamond electrodes, BP.DD

Abstract

Emerging pollutants are not included in monitoring programs by environmental and health agencies, and therefore, do not have environmental control regulations. These pollutants originated by anthropogenic actions are volatile organic and pharmaceutical compounds, which are found in air and urine/water, respectively. In addition, if they are not treated before reaching the environment they can be responsible for well-being population loss. Thus, an important field of study is the search for alternatives to recover contaminated air and urine with emerging pollutants. Electrochemical Oxidation Processes (EOP) are methods with high efficiency in organic degradation due to their high oxidative species productions and can be applied both for air and urine decontamination. Consequently, we propose a novel boron-doped ultra nanocrystalline diamond/dioxide titanium nanotube/titanium growth without seeding (B-UNCDWS/DTNT/Ti) as a porous composite to be used as electrode material to treat air and urine contaminated with emergent pollutants using EOP. This composite is very attractive for electrochemical applications by its large surface area provided by the homogeneity and porosity by combining the B-UNCDWS as well as DTNT singular properties. (AU)

Scientific publications

(7)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

VERNASQUI, L. G.; FERREIRA, N. G.; SAEZ, C.; RODRIGO, M. A.. Enhancing electrochemical production of peroxophosphates using new boron doped diamond coatings. Electrochimica Acta, v. 467, p. 7-pg., 2023-09-06. (17/10118-0, 21/07615-7, 19/00592-1)

VERNASQUI, LAIS; MONTIEL, MIGUEL A.; FERREIRA, NEIDENEI GOMES; CANIZARES, PABLO; RODRIGO, MANUEL A.. Design, Validation, and Fabrication of a Tailored Electrochemical Reactor Using 3D Printing for Studies of Commercial Boron-Doped Diamond Electrodes. Industrial & Engineering Chemistry Research, v. 63, n. 13, p. 11-pg., 2024-03-25. (17/10118-0, 19/00592-1, 21/07615-7)

VERNASQUI, LAIS G.; SEGUNDO, INALMAR D. BARBOSA; MARTINEZ-HUITLE, CARLOS A.; FERREIRA, NEIDENEI G.; RODRIGO, MANUEL A.. Unraveling the Environmental Applications of Nanoporous Ultrananocrystalline Diamond Films. CATALYSTS, v. 14, n. 12, p. 14-pg., 2024-12-01. (17/10118-0, 23/06233-9, 19/00592-1, 21/07615-7)

VERNASQUI, LAIS G.; DOS SANTOS, ALEXSANDRO J.; FORTUNATO, GUILHERME V.; KRONKA, MATHEUS S.; BARAZORDA-CCAHUANA, HARUNA L.; FAJARDO, ANA S.; FERREIRA, NEIDENEI G.; LANZA, MARCOS R. V.. Highly porous seeding-free boron-doped ultrananocrystalline diamond used as high-performance anode for electrochemical removal of carbaryl from water. Chemosphere, v. 305, p. 9-pg., 2022-06-30. (19/20634-0, 14/50945-4, 19/00592-1, 21/07615-7, 17/23464-3, 17/10118-0, 19/04421-7)

VERNASQUI, LAIS G. A.; KAWATA, BIANCA A.; SARDINHA, A. F. A.; RODRIGO, MANUEL A. G.; FERREIRA, NEIDENEI G.. Achievement and electrochemical responsiveness of advanced boron-doped ultrananocrystalline diamond on highly ordered titanium dioxide nanotubes. DIAMOND AND RELATED MATERIALS, v. 121, p. 11-pg., 2022-01-05. (17/05343-4, 19/00592-1, 17/10118-0, 21/07615-7)

VERNASQUI, LAIS G.; SANTOS, GESSICA O. S.; RODRIGUEZ-GOMEZ, ALBERTO; LANZA, MARCOS R. V.; FERREIRA, NEIDENEI G.; RODRIGO, MANUEL A.. New diamond coatings for peroxosulphate production. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 954, p. 8-pg., 2024-01-10. (20/02743-4, 21/07615-7, 17/10118-0, 19/00592-1, 22/03386-6)

VERNASQUI, LAIS GIMENES; SANTOS, GESSICA DE OLIVEIRA SANTIAGO; ISIDRO, JULIA; SILVA, TAYNARA OLIVEIRA; LANZA, MARCOS ROBERTO DE VASCONCELOS; SAEZ, CRISTINA; FERREIRA, NEIDENEI GOMES; RODRIGO, MANUEL ANDRES RODRIGO. New diamond coatings for a safer electrolytic disinfection. Environmental Science and Pollution Research, v. N/A, p. 10-pg., 2023-10-24. (19/08701-4, 20/02743-4, 21/07615-7, 17/10118-0, 22/07227-0, 19/00592-1, 22/03386-6)