Fabio Henrique Barros de Lima
CV Lattes
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Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC) (Institutional affiliation for the last research proposal) Birthplace: Brazil
Fabio H. B. Lima (1978) graduated in Chemistry at University of Sao Paulo, São Carlos, in 2001. He obtained his Ph.D. in Physical Chemistry at the Institute of Chemistry of São Carlos of the University of São Paulo (IQSC/USP), São Carlos, in 2006, with a stage at the Brookhaven National Laboratory (USA, NY), in 2005. He spent 12 months as a postdoctoral IQSC fellow between 2006 and 2008. In 2008 he was appointed Associate Professor at the Physical Chemistry Department in the same Institution. He published 51 papers, receiving 2966 citations - October/2019 - Scopus (h-index 28). Prof. Lima is currently interested in the following topics: (i) synthesis and characterization of nanostructured electrocatalysts; (ii) electro-oxidation of organic and inorganic molecules; (iii) electro-reduction of oxygen; (iv) electrocatalysis and foto-electrocatalysis of water splitting; (v) electro-reduction of CO2 and (vi) electrocatalysis of reactions involved in hydrogen storage: H2/H2O and CO2/formic acid or CO2/formate ions cycles (regenerative electrochemical cycles). These reactions are involved in electrochemical energy conversion and storage devices, such as fuel cells, electrolyzers, electrochemical reformers, and regenerative electrochemical devices. (Source: Lattes Curriculum)
- Carbon dioxide and water electrochemistry: application in energy conversion and storage, AP.R
Abstract
The reactions involved in the carbon dioxide and water electrochemistry can be utilized in electrochemical energy conversion and storage devices. The coupling of carbon dioxide electro-reduction and water electro-oxidation can be used in electrochemical devices of fuel production. On the contrary, the coupling of the electro-oxidation of molecules with high hydrogen content and the oxyg...
- Electrocatalysis IV: fundamental and applied aspects of electrocatalytic processes, bio-electrocatalysis and kinetic instabilities, AP.BIOEN.TEM
Abstract
The goal of the present project consists of the study of electrocatalytic processes taking place in energy conversion and storage systems, particularly the ones involving reactions in fuel cells, including bio-active electrodes. Attention will be paid to the study of the oxygen reduction reaction and of the oxidation of alcohol molecules and hydrogen deliberately contaminated with trace...
- Electrocatalysis of the ethanol electrooxidation on platinum monolayers deposited on core-shell nanoparticles, AP.R
Abstract
This work aims at studying the ethanol oxidation electrocatalysis. This reaction, that takes place at the anode of direct ethanol fuel cells, will be investigated on electrocatalysts formed by Pt monolayers. The electrocatalysis of the total oxidation of the ethanol to CO2 involves the deshydrogenation step, the C-C bond breaking, and the oxidation of the adsorbed CO, which is a product...
- Photo-electrocatalysis of formic acid oxidation for hydrogen production, BP.IC
Abstract
Photoelectrolytic cells are important alternatives to hydrogen (H2), since they are operated with renewable fuels and with solar energy. H2 production is relevant because it can be used as fuel in fuel cells of the PEMFC type (polymer electrolyte membrane fuel cell). Photoelectrochemically shaped, the fuel is photo-electro-oxidized without anode and protons (for acid electrolytes) are e...
- Functionalization of AU eletrocatalysts by imidazole dithiocarbamate derivatives: exploring the molecular junction as strategy for electroreduction of carbon dioxide, BP.PD
Abstract
The electrocatalytic reduction of carbon dioxide (CO2) is a key theme on the global research concerning stock and energy conversion. Due the multidisciplinary of the problem, these investigations apply concepts from different sciences. For instance, the functionalization of metallic surfaces by organic molecules is considered an elegant and efficient strategy to modulate the catalytic a...
- Activity and stability investigation of the electrocatalysts constituted by abundant elements for the oxygen reduction reaction, BP.IC
Abstract
The development of fuel cells is linked to the overcoming some obstacles in order to allow the large-scale applications of these devices. Among them, high overpotentials and slow kinetics of oxygen reduction (ORR) on the cathodic electrode are highlighted, as well as the current dependence on the use of noble metals such as Pt and Pd, which do not present practical stability also increa...
- A high-throughput combinatorial approach in the study of metallic alloys and their respective chalcogenides for application in the CO2 photo-/electrochemical reduction reaction, BP.PD
Abstract
The increasing rise in the atmospheric CO2 concentration (greenhouse gas and climate change) has encouraged the search for methods to fix this pollutant. In recent years, photo-/electro-reduction of CO2 has been highlighted as promising; beyond the consumption of this gas, it still produces fuel, or reagents such as hydrocarbons, alcohols and carboxylic acids. Several materials have bee...
- Metallic Carbonitrides and nanoestructured carbon composites as non-noble electrocatalysts for the oxygen reduction reaction, BP.PD
Abstract
The development of high efficiency devices for energy conversion is a technological urge, nowadays on the world scenario, in order to develop a sustainable society based on non-pollutant and trustable energy sources. In according to this context, electrochemical devices such as hydrogen fuel cells or direct liquid fuels as alcohols or formic acid/formate ions, appears highlighted as a g...
- Development of electrocatalysts for the electroreduction of CO2 and photo-electrooxidation of water: investigation of the reaction products by on-line mass spectrometry, BP.PD
Abstract
The increase of the world demand for energy and the depletion of fossil fuels in conjunction with the global warming crisis, has forced researches aiming at obtaining a new source of energy free of environmental damage, sustainable and with low cost. The development of electrochemical devices that mimic natural photosynthesis for the synthesis of high value-added products, the so-called...
(Only some records are available in English at this moment)
- Metal sulfide and oxide nanostructures as electrocatalysts for hydrogen and oxygen electrodes, BE.EP.DR
Abstract
The development of electrochemical devices that promote the regenerative electro-conversion between chemical and electrical energy is of great importance for a sustainable energy scenario. The unitized regenerative fuel cells (URFC) are examples of such devices, which require bifunctional electrocatalysts, i.e., active materials for hydrogen evolution/oxidation and for the oxygen evolut...
- Ethanol electro-oxidation in solid acid fuel cells: effect of the electrocatalyst and operation temperature on the reaction pathways, BE.EP.DR
Abstract
Direct Ethanol Fuel Cells (DEFC) are an important type of virtual hydrogen fuel cell. This is mainly because ethanol has a high hydrogen content or high energy density, low toxicity, and possibility to be produced in large amounts through the fermentation of biomass, offering an interesting economic viability. The total electro-oxidation of ethanol to CO2 releases 12 electrons per molec...
- Study of the hydrazine and borohydride ions electro-oxidation reaction on non-noble metal electrocatalysts for alkaline fuel cells, BE.EP.DR
Abstract
Passive fuel cells fed with liquid fuels, such as hydrazine and borohydride ions in the anode, and air in the cathode (also called hydrazine or borohydride/air batteries) are promising alternatives as power sources. This is due to their high energy density, autonomy, and easy fuel supply, compared to lithium ion batteries that have high energy density, but with limited autonomy. The hyd...
(Only some records are available in English at this moment)
| 3 / 3 | Completed research grants |
| 3 / 3 | Ongoing scholarships in Brazil |
| 14 / 13 | Completed scholarships in Brazil |
| 4 / 4 | Completed scholarships abroad |
| 24 / 23 | All research grants and scholarships |
| Associated processes | |
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
| Publications | 19 |
| Citations | 313 |
| Cit./Article | 16.5 |
| Data from Web of Science | |
DE OLIVEIRA, DRIELLY C.; SILVA, WANDERSON O.; CHATENET, MARIAN; LIMA, FABIO H. B.. NiOX-Pt/C nanocomposites: Highly active electrocatalysts for the electrochemical oxidation of hydrazine. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 201, p. 22-28, FEB 2017. Web of Science Citations: 15.
QUEIROZ, A. C.; LIMA, F. H. B.. Electrocatalytic activity and stability of Co and Mn-based oxides for the oxygen reduction reaction in alkaline electrolyte. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 707, p. 142-150, OCT 15 2013. Web of Science Citations: 19.
CANTANE, D. A.; OLIVEIRA, F. E. R.; SANTOS, S. F.; LIMA, F. H. B.. Synthesis of Pt-based hollow nanoparticles using carbon-supported Co@Pt and Ni@Pt core-shell structures as templates: Electrocatalytic activity for the oxygen reduction reaction. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 136, p. 351-360, JUN 5 2013. Web of Science Citations: 57.
NAGAO, RAPHAEL; CANTANE, DANIEL A.; LIMA, FABIO H. B.; VARELA, HAMILTON. The dual pathway in action: decoupling parallel routes for CO2 production during the oscillatory electro-oxidation of methanol. Physical Chemistry Chemical Physics, v. 14, n. 23, p. 8294-8298, 2012. Web of Science Citations: 32.
LIMA, FABIO H. B.; PASQUALETI, ANIELLI M.; CONCHA, M. BELEN MOLINA; CHATENET, MARIAN; TICIANELLI, EDSON A.. Borohydride electrooxidation on Au and Pt electrodes. Electrochimica Acta, v. 84, n. SI, p. 202-212, DEC 1 2012. Web of Science Citations: 63.
NAGAO, RAPHAEL; CANTANE, DANIEL A.; LIMA, FABIO H. B.; VARELA, HAMILTON. Influence of Anion Adsorption on the Parallel Reaction Pathways in the Oscillatory Electro-oxidation of Methanol. Journal of Physical Chemistry C, v. 117, n. 29, p. 15098-15105, JUL 25 2013. Web of Science Citations: 23.
DE SOUZA, JOAO C. P.; SILVA, WANDERSON O.; LIMA, FABIO H. B.; CRESPILHO, FRANK N.. Enzyme activity evaluation by differential electrochemical mass spectrometry. CHEMICAL COMMUNICATIONS, v. 53, n. 60, p. 8400-8402, AUG 4 2017. Web of Science Citations: 4.
CAMILO, MARIANA R.; SILVA, WANDERSON O.; LIMA, FABIO H. B.. Investigation of Electrocatalysts for Selective Reduction of CO2 to CO: Monitoring the Reaction Products by on line Mass Spectrometry and Gas Chromatography. Journal of the Brazilian Chemical Society, v. 28, n. 9, p. 1803-1815, SEP 2017. Web of Science Citations: 4.
SILVA, W. O.; QUEIROZ, A. C.; PAGANIN, V. A.; LIMA, F. H. B.. Faradaic efficiency of ethanol oxidation to CO2 at metallic nanoparticle/short-side-chain PFSA solid-state electrolyte interfaces investigated by on-line DEMS. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 824, p. 99-107, SEP 1 2018. Web of Science Citations: 1.
MAILLARD, FREDERIC; SILVA, WANDERSON O.; CASTANHEIRA, LUIS; DUBAU, LAETITIA; LIMA, FABIO H. B.. Carbon Corrosion in Proton-Exchange Membrane Fuel Cells: Spectrometric Evidence for Pt-Catalysed Decarboxylation at Anode-Relevant Potentials. ChemPhysChem, JULY 2019. Web of Science Citations: 0.
GALIOTE, N. A.; OLIVEIRA, F. E. R.; LIMA, F. H. B.. FeCo-N-C oxygen reduction electrocatalysts: Activity of the different compounds produced during the synthesis via pyrolysis. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 253, p. 300-308, SEP 15 2019. Web of Science Citations: 1.
COSTA, MAGNO BARCELOS; LUCAS, FRANCISCO W. S.; MASCARO, LUCIA HELENA. Electrodeposition Conditions Effect Sb2Se3 Thin-Film Properties. CHEMELECTROCHEM, v. 6, n. 11, p. 2937-2944, JUN 3 2019. Web of Science Citations: 0.
PASQUALETI, ANIELLI M.; PADGETT, ELLIOT; KUO, DING-YUAN; MULLER, DAVID A.; LIMA, FABIO H. B.; SUNTIVICH, JIN. Influence of Aliovalent Substitutions on Oxygen Reduction on Tantalum Oxynitrides. Journal of the Electrochemical Society, v. 164, n. 6, p. F645-F650, 2017. Web of Science Citations: 1.
DELMONDE, M. V. F.; NASCIMENTO, M. A.; NAGAO, R.; CANTANE, D. A.; LIMA, F. H. B.; VARELA, H.. Production of Volatile Species during the Oscillatory Electro-oxidation of Small Organic Molecules. Journal of Physical Chemistry C, v. 118, n. 31, p. 17699-17709, AUG 7 2014. Web of Science Citations: 14.
QUEIROZ, A. C.; SILVA, W. O.; RODRIGUES, I. A.; LIMA, F. H. B.. Identification of bimetallic electrocatalysts for ethanol and acetaldehyde oxidation: Probing C-2-pathway and activity for hydrogen oxidation for indirect hydrogen fuel cells. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 160, p. 423-435, NOV 2014. Web of Science Citations: 6.
CANTANE, D. A.; AMBROSIO, W. F.; CHATENET, M.; LIMA, F. H. B.. Electro-oxidation of ethanol on Pt/C, Rh/C, and Pt/Rh/C-based electrocatalysts investigated by on-line DEMS. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 681, p. 56-65, AUG 1 2012. Web of Science Citations: 34.
OLIVEIRA, FRANCISCA E. R.; GALIOTE, NELSON A.; LIMA, FABIO H. B.. Investigation of Earth-Abundant Oxygen Reduction Electrocatalysts for the Cathode of Passive Air-Breathing Direct Formate Fuel Cells. CATALYSTS, v. 8, n. 8, AUG 2018. Web of Science Citations: 1.
DAMAS, GIANE B.; MIRANDA, CAETANO R.; SGARBI, RICARDO; PORTELA, JAMES M.; CAMILO, MARIANA R.; LIMA, FABIO H. B.; ARAUJO, C. MOYSES. On the Mechanism of Carbon Dioxide Reduction on Sn-Based Electrodes: Insights into the Role of Oxide Surfaces. CATALYSTS, v. 9, n. 8, AUG 2019. Web of Science Citations: 0.
PASQUALETI, ANIELLI M.; OLU, PIERRE-YVES; CHATENET, MARIAN; LIMA, FABIO H. B.. Borohydride Electrooxidation on Carbon-Supported Noble Metal Nanoparticles: Insights into Hydrogen and Hydroxyborane Formation. ACS CATALYSIS, v. 5, n. 5, p. 2778-2787, MAY 2015. Web of Science Citations: 38.
(References retrieved automatically from State of São Paulo Research Institutions)
LIMA, Fabio Henrique Barros de. \"Desenvolvimento de eletrocatalisadores dispersos para o cátodo de células a combustível alcalinas\". 2006. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos.
PASQUALETI, Aniélli Martini. Investigação da atividade de eletrocatalisadores nanoestruturados para a eletrooxidação de íons BH4- em eletrólito alcalino. 2013. Dissertação (Mestrado) - Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos.
PASQUALETI, Aniélli Martini. Eletrocatalisadores formados por nitretos, carbetos e óxidos metálicos para o eletrodo de oxigênio. 2017. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos.
QUEIROZ, Adriana Coêlho. Oxidação eletroquímica de etanol em temperatura ambiente e intermediária: estudo quantitativo das vias reacionais por espectrometria de massas on-line. 2016. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos.
OLIVEIRA, Drielly Cristina de. Estudo das reações de eletro-oxidação de hidrazina e íons borohidreto em eletrocatalisadores de níquel e cobalto em eletrólito alcalino. 2016. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos.
CANTANE, Daniel Augusto. Investigação da oxidação eletroquímica de etanol por espectrometria de massas on-line sobre nanoestruturas metálicas. 2013. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos.