Douglas Wagner Franco
CV Lattes
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Universidade de São Paulo (USP). Instituto de Química de São Carlos (IQSC) (Institutional affiliation for the last research proposal) Birthplace: Brazil
graduate at Química Araraquara Licenciatura e Bacharelado from Universidade Estadual Paulista Júlio de Mesquita Filho (1968) and ph.d. at Chemistry from Universidade de São Paulo (1972). Has experience in Chemistry, focusing on Inorganic Chemistry, acting on the following subjects: rutênio, aguardente, ruthenium, cachaça and nitric oxide. (Source: Lattes Curriculum)
- X Brazilian Meeting on Chemistry of Food and Beverages, AO.R
- Nitrosyl and nitroxyl as ligands on Ru(II): synthesis, kinetics, reactivity and thermodynamics, AP.R
Abstract
The present research project presents a natural extension of previous ones including HNO/NO- system. The reactivity aspects still enclosed in the present project. The knowledge regarding to the reactivity changes on the phosphorus esters coordinated to ruthenium can provide a better understanding of its reactivity and help on tailoring more robust compounds with respect to nucleophilic ...
- VIII Brazilian meeting on chemistry of food and beverages, AO.R
(Only some records are available in English at this moment)
- HNO donor compounds: a thermodynamic, kinetic, experimental and theoretical approach, BP.DR
Abstract
It is proposed to investigate the chemical complex of ruthenium-nitroxil (Ru-HNO, Ru-NO-) from the point of view of thermodynamic and kinetic in order to better understand the redox reactions [Ru(NO)]3+ / [Ru(NO)]2+ and control the reactions release binder nitroxil (HNO/NO-). The initial option is that this complex by dissociation takes place slowly, in view of its application as a temp...
- Distinguishing hydroalcoholic wood extracts and monitoring their stages of aging using gas sensors, gas chromatography (GC-MS) and multivariate analysis, BP.PD
Abstract
Currently the woods identification is accomplished visually considering the taxonomy of plant and taking wood collections as a reference. Within the scope of spirits aging, the process taking place in wood barrels is considered a lapidation of the spirits. The diversity of wood found in Brazil is a great potential to be explored, aiming to produce quality beverages, with good acceptabil...
- Anchoring of the complex trans-[RuII(NO+)(NH3)4ina]CL3 (ina = isonicotinic acid) in PAMAM dendrimers, and evaluation of their trypanocidal activities, BP.MS
(Only some records are available in English at this moment)
| 31 / 19 | Completed research grants |
| 16 / 6 | Completed scholarships in Brazil |
| 47 / 25 | All research grants and scholarships |
| Associated processes | |
(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)
| Publications | 11 |
| Citations | 54 |
| Cit./Article | 4.9 |
| Data from Web of Science | |
. Teores de carbamato de etila em aguardentes de cana e mandioca: parte II. Química Nova, v. 32, n. 1, p. -, 2009.
METZKER, GUSTAVO; TOLEDO, JR., JOSE C.; LIMA, FRANCISCO C. A.; MAGALHAES, ALVICLER; CARDOSO, DANIEL R.; FRANCO, DOUGLAS W.. Nitric Oxide as an Activation Agent for Nucleophilic Attack in trans-[Ru(NO)(NH3)(4)[P(OEt)(3)]](PF6)(3). Journal of the Brazilian Chemical Society, v. 21, n. 7, p. 1266-1273, 2010. Web of Science Citations: 8.
TFOUNI‚ E.; KRIEGER‚ M.; MCGARVEY‚ B.R.; FRANCO‚ D.W.. Structure‚ chemical and photochemical reactivity and biological activity of some ruthenium amine nitrosyl complexes. Coordination Chemistry Reviews, v. 236, n. 1, p. 57-69, 2003. (99/07109-9)
ROVEDA, JR., ANTONIO CARLOS; AGUIAR, HELENA DE FAZIO; MIRANDA, KATRINA M.; TADINI, CARMEN CECILIA; FRANCO, DOUGLAS WAGNER. Light-triggered and cysteine-mediated nitric oxide release from a biodegradable starch-based film. JOURNAL OF MATERIALS CHEMISTRY B, v. 2, n. 41, p. 7232-7242, 2014. Web of Science Citations: 8. (12/23651-4)
METZKER, GUSTAVO; DE AGUIAR, INARA; SOUZA, MAYKON LIMA; CARDOSO, DANIEL RODRIGUES; FRANCO, DOUGLAS WAGNER. Reaction of ruthenium(II) complexes with 2,2-diphenyl-1-picrylhydrazyl (DPPH center dot) and hydroxyl radicals. Canadian Journal of Chemistry, v. 92, n. 8, p. 788-793, AUG 2014. Web of Science Citations: 1.
AGUIAR, HELENA DE FAZIO; ROVEDA JUNIOR, ANTONIO CARLOS; PIVA, RENAN DE JESUS; ONODA, KEVIN AKIRA; MIYAKAWA, AYUMI AUREA; KRIEGER, JOSE EDUARDO; FRANCO, DOUGLAS WAGNER; TADINI, CARMEN CECILIA. Compatibility of Cassava Starch Films as Nitric Oxide Carrier for Potential Medical Device. Journal of Applied Polymer Science, v. 132, n. 2, JAN 10 2015. Web of Science Citations: 3. (10/16057-3, 13/17368-0, 12/23651-4)
ANDRADE SOBRINHO, LUIZ GUALBERTO DE; CAPPELINI, LUCIANA TEREZA DIAS; SILVA, ALEXANDRE ATAÍDE DA; GALINARO, CARLOS ALEXANDRE; BUCHVISER, SILMARA FRANÇA; CARDOSO, DANIEL RODRIGUES; FRANCO, DOUGLAS WAGNER. Teores de carbamato de etila em aguardentes de cana e mandioca. Parte II. Química Nova, v. 32, n. 1, p. 116-119, 2009.
SIQUEIRA, MARCOS RECHI; PERRONE, OLAVO MICALI; METZKER, GUSTAVO; DE OLIVEIRA LISBOA, DANIELA CORREA; THOMEO, JOAO CLAUDIO; BOSCOLO, MAURICIO. Highly selective 1-butanol obtained from ethanol catalyzed by mixed metal oxides: Reaction optimization and catalyst structure behavior. MOLECULAR CATALYSIS, v. 476, OCT 2019. Web of Science Citations: 0. (16/15575-7, 17/13230-5, 92/03515-3, 15/11588-4, 13/23886-4)
ZANICHELLI, PATRÍCIA GRAÇA; MIOTTO, ALEXANDRE M.; ESTRELA, HEDER F. G.; SOARES, FERNANDA ROCHA; GRASSI-KASSISSE, DORA M.; SPADARI-BRATFISCH, REGINA C.; CASTELLANO, EDUARDO E.; RONCAROLI, FEDERICO; PARISE, ALEJANDRO R.; OLABE, JOSÉ A.; et al. The [Ru(Hedta)NO](0,1-) system: structure, chemical reactivity and biological assays. Journal of Inorganic Biochemistry, v. 98, n. 11, p. 1921-1932, nov. 2004. (99/07109-9)
SCARPELLINI, MARCIELA; NEVES, ADEMIR; CASTELLANO, EDUARDO E.; FRANCO, DOUGLAS W.. Structural, electrochemical and spectroscopic characterization of a new [Cu2L2([mu-Cl)(2)](2)[CuCl4](2) dimer complex. Journal of Molecular Structure, v. 694, n. 1-3, p. 193-198, Jun. 2004. (99/07109-9)
SILVA, WELTER C.; CASTELLANO, EDUARDO E.; FRANCO, DOUGLAS W.. Structural and reactivity changes in ruthenium ammines induced by the NO ligand. Polyhedron, v. 23, n. 6, p. 1063-1067, mar. 2004. (99/07109-9)
SCARPELLINI, MARCIELA; NEVES, ADEMIR; CASTELLANO, EDUARDO E.; NEVES, EDUARDO F. DE ALMEIDA; FRANCO, DOUGLAS W.. A structural model for oxidized type II copper nitrite reductase with a polyimidazole tripodal ligand. Polyhedron, v. 23, n. 4, p. 511-518, fev. 2004. (99/07109-9)
SCARPELLINI, MARCIELA; TOLEDO JÚNIOR, JOSÉ CARLOS; NEVES, ADEMIR; ELLENA, JAVIER; CASTELLANO, EDUARDO E.; FRANCO, DOUGLAS W.. Structural, spectroscopic and redox studies of a new ruthenium(III) complex with an imidazole-rich tripodal ligand. Inorganica Chimica Acta, v. 357, n. 3, p. 707-715, fev. 2004. (99/07109-9)
TOLEDO‚ J.C.; DOS SANTOS LIMA NETO‚ B.; FRANCO‚ D.W.. Mutual effects in the chemical properties of the ruthenium metal center and ancillary ligands upon coordination. Coordination Chemistry Reviews, v. 249, n. 3, p. 419-431, 2005.
TRUZZI, DANIELA RAMOS; FERREIRA, ANTONIO GILBERTO; DA SILVA, SEBASTIAO CLAUDINO; CASTELLANO, EDUARDO ERNESTO; ALVES LIMA, FRANCISCO DAS CHAGAS; FRANCO, DOUGLAS WAGNER. Nitrosyl induces phosphorous-acid dissociation in ruthenium(II). DALTON TRANSACTIONS, v. 40, n. 48, p. 12917-12925, 2011. Web of Science Citations: 9. (08/02014-0)
SOUZA, MAYKON LIMA; ROVEDA, JR., ANTONIO CARLOS; MELO PEREIRA, JOSE CLAYSTON; FRANCO, DOUGLAS WAGNER. New perspectives on the reactions of metal nitrosyls with thiolates as nucleophiles. Coordination Chemistry Reviews, v. 306, n. 2, SI, p. 615-627, JAN 1 2016. Web of Science Citations: 7. (12/23651-4)
TRUZZI, DANIELA R.; CASTELLANO, EDUARDO E.; FRANCO, DOUGLAS W.. Synthesis, characterization, X-ray crystallography and stability in aqueous medium of trans-[Ru(CO)(NH3)(4)P(OH)(3)](2+). Polyhedron, v. 124, p. 184-190, MAR 9 2017. Web of Science Citations: 2. (12/23651-4)
LUIZ GUALBERTO DE ANDRADE SOBRINHO; LUCIANA TEREZA DIAS CAPPELINI; ALEXANDRE ATAÍDE DA SILVA; CARLOS ALEXANDRE GALINARO; SILMARA FRANÇA BUCHVISER; DANIEL RODRIGUES CARDOSO; DOUGLAS WAGNER FRANCO. Teores de carbamato de etila em aguardentes de cana e mandioca: parte II. Química Nova, v. 32, n. 1, p. -, 2009.
GUSTAVO METZKER; JOSÉ C. TOLEDO JR.; FRANCISCO C. A. LIMA; ALVICLER MAGALHÃES; DANIEL R. CARDOSO; DOUGLAS W. FRANCO. Nitric oxide as an activation agent for nucleophilic attack in trans-[Ru(NO)(NH3)4{P(OEt)3}](PF6)3. Journal of the Brazilian Chemical Society, v. 21, n. 7, p. -, 2010.
ROVEDA JR, ANTONIO C.; SANTOS, WILLY G.; SOUZA, MAYKON L.; ADELSON, CHARLES N.; GONCALVES, FELIPE S.; CASTELLANO, EDUARDO E.; GARINO, CLAUDIO; FRANCO, DOUGLAS W.; CARDOSO, DANIEL R.. Light-activated generation of nitric oxide (NO) and sulfite anion radicals (SO3 center dot-) from a ruthenium(II)nitrosylsulphito complex. DALTON TRANSACTIONS, v. 48, n. 29, p. 10812-10823, AUG 7 2019. Web of Science Citations: 0. (12/23651-4, 17/01189-0)
SOUZA, MAYKON L.; CASTELLANO, EDUARDO E.; TELSER, JOSHUA; FRANCO, DOUGLAS W.. Secondary Coordination Sphere Effects in Ruthenium(III) Tetraammine Complexes: Role of the Coordinated Water Molecule. Inorganic Chemistry, v. 54, n. 4, p. 2067-2080, FEB 16 2015. Web of Science Citations: 7. (12/23651-4)
LUIZ GUALBERTO DE ANDRADE-SOBRINHO; MAURÍCIO BOSCOLO; BENEDITO DOS SANTOS LIMA-NETO; DOUGLAS WAGNER FRANCO. Carbamato de etila em bebidas alcoólicas (cachaça, tiquira, uísque e grapa). Química Nova, v. 25, n. 6b, p. 1074-1077, Dez. 2002.
CARLOS‚ R.M.; FERRO‚ A.A.; SILVA‚ H.A.S.; GOMES‚ M.G.; BORGES‚ S.S.S.; FORD‚ P.C.; TFOUNI‚ E.; FRANCO‚ D.W.. Photochemical reactions of trans-[Ru (NH3)4 L (NO)]3+ complexes. Inorganica Chimica Acta, v. 357, n. 5, p. 1381-1388, 2004. (99/07109-9)
BAGATIN‚ I.A.; DE ALMEIDA SANTOS‚ R.H.; FRANCO‚ D.W.; MAGALHAES‚ A.; FERREIRA‚ A.G.. Spectroscopic and electrochemical properties of a new nitrosyl-complex of Ru (II): trans-(Ru (NO){(CH3CH2) 2PCH2CH2P (CH2CH3) 2} 2Cl)(PF6) 2. Inorganica Chimica Acta, v. 333, n. 1, p. 109-115, 2002. (99/07109-9)
FREITAS, CRISTINA S.; ROVEDA, ANTONIO C.; TRUZZI, JR., DANIELA R.; GARCIA, ANDRE C.; CUNHA, THIAGO M.; CUNHA, FERNANDO Q.; FRANCO, DOUGLAS W.. Anti-inflammatory and Anti-nociceptive Activity of Ruthenium Complexes with Isonicotinic and Nicotinic Acids (Niacin) as Ligands. Journal of Medicinal Chemistry, v. 58, n. 11, p. 4439-4448, JUN 11 2015. Web of Science Citations: 9. (13/08216-2, 11/19670-0, 12/23651-4)
EDUARDO S. P. NASCIMENTO; DANIEL R. CARDOSO; DOUGLAS W. FRANCO. Comparação de técnicas de determinação de ésteres em cachaça. Química Nova, v. 32, n. 9, p. 2323-2327, 2009.
LISÂNIAS R. POLASTRO; LISANGELA M. BOSO; LUIZ G. ANDRADE-SOBRINHO; BENEDITO S. LIMA-NETO; DOUGLAS W. FRANCO. Compostos nitrogenados em bebidas destiladas: cachaça e tiquira. FOOD SCIENCE AND TECHNOLOGY, v. 21, n. 1, p. 78-81, Jan. 2001. (98/09053-8)
(References retrieved automatically from State of São Paulo Research Institutions)
JUNIOR, José Carlos Toledo. Aspectos da reatividade de complexos de rutênio contendo óxido nítrico como ligante. 2004. 119f. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos. (99/11252-1)
RECHE, Roni Vicente. Aspectos da tipificação da aguardente. 2006. x, 154f. Dissertação (Mestrado) - Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos. (04/11525-8)
METZKER, Gustavo. Nitrosilo complexos de rutênio(II) como captores de radicais de interesse biológico. 2009. Dissertação (Mestrado) - Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos. (06/05877-4)
TRUZZI, Daniela Ramos. Comportamento em solução de P(OH)(OEt)2 e P(OH)3 coordenados a tetraaminas de Ru(II). 2010. Dissertação (Mestrado) - Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos. (08/02014-0)
JÚNIOR, Antonio Carlos Roveda. Ancoramento de nitrosilo complexo de rutênio em dendrímeros PAMAM e estudo de suas propriedades químicas e biológicas. 2011. Dissertação (Mestrado) - Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos. (09/04265-3)
SILVA, Augusto Cesar Huppes da. Estudo teórico-experimental de nitroxil e nitroxil complexos em tetraaminas de rutênio(II). 2016. Tese (Doutorado) – Instituto de Química de São Carlos. Universidade de São Paulo (USP). São Carlos. (12/22270-7)
MÉTODO PARA CLASSIFICAÇÃO DE BEBIDAS DESTILADAS QUANTO A SEU PROCESSO DE DESTILAÇÃO E DISPOSITIVO COMPREENDENDO TAL MÉTODO PI0704923-4 - Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP); Universidade de São Paulo (USP). Douglas Wagner Franco; Roni Vicente Reche - September 2007, 28
PROCESSO PARA DIFERENCIAÇÃO DE DERIVADOS DE CANA-DE-AÇÚCAR E DISPOSITIVO COMPREENDENDO TAL MÉTODO PI0705458-0 - Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP); Universidade de São Paulo (USP). Douglas Wagner Franco; Carlos Alexandre Galinaro; Daniel Rodrigues Cardoso - October 2007, 26