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(Reference retrieved automatically from SciELO through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Microwave-assisted Hydrothermal Synthesis of Magnetite Nanoparticles with Potential Use as Anode in Lithium Ion Batteries

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Author(s):
Xavier, Camila Soares [1] ; Paskocimas, Carlos Alberto [2] ; da Motta, Fabiana Villela [2] ; Araujo, Vinicius Dantas [2] ; Aragon, Maria Jose [3] ; Tirado, Jose Luis [3] ; Lavela, Pedro [3] ; Longo, Elson [1] ; Bomio Delmonte, Mauricio Roberto [2]
Total Authors: 9
Affiliation:
[1] Univ Estadual Paulista, UNESP, Inst Quim, BR-14800900 Araraquara, SP - Brazil
[2] Univ Fed Rio Grande do Norte, DEMat, Dept Mat Engn, Lab Sintese Quim Mat, UFRN, BR-59078970 Natal, RN - Brazil
[3] Univ Cordoba, Lab Quim Inorgan, E-14071 Cordoba - Spain
Total Affiliations: 3
Document type: Journal article
Source: MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS; v. 17, n. 4, p. 1065-1070, Ago. 2014.
Web of Science Citations: 5
Abstract

Rechargeable solid-state batteries have long been considered an attractive power source for a wide variety of applications, and in particular, lithium-ion batteries are emerging as the technology of choice for portable electronics. One of the main challenges in the design of these batteries is to ensure that the electrodes maintain their integrity over many discharge-recharge cycles. Fe3O4 deserves great attention as one of the most important electrode active materials due to its high theoretical capacity (926 mAhg- 1), low cost, being environmental-friendly and naturally abundance in worldwide. A simple strategy to synthesize magnetite nanoparticles (Fe3O4) by microwave-assisted hydrothermal method in a short processing time without further treatment is reported. The material obtained was tested as anode active material for lithium ions batteries. Impedance spectroscopy revealed that small differences in cell performance on cycling observed between samples cannot be strictly correlated to cell resistance. A high reversible capacity of 768.5 mAhg- 1 at 1C over 50 cycles was demonstrated, suggesting its prospective use as anode material for high power lithium ion batteries. (AU)

FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
Grantee:Elson Longo da Silva
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC
FAPESP's process: 08/57872-1 - National Institute for Materials Science in Nanotechnology
Grantee:Elson Longo da Silva
Support type: Research Projects - Thematic Grants