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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Combined photoelectrocatalytic/electro-Fenton process using a Pt/TiO2NTs photoanode for enhanced degradation of an azo dye: A mechanistic study

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Author(s):
Almeida, Lucio C. [1] ; Silva, Bianca F. [1] ; Zanoni, Maria V. B. [1]
Total Authors: 3
Affiliation:
[1] UNESP, Inst Chem Araraquara, Dept Analyt Chem, BR-14800900 Araraquara, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Journal of Electroanalytical Chemistry; v. 734, p. 43-52, NOV 15 2014.
Web of Science Citations: 8
Abstract

The combined photoelectrocatalytic/electro-Fenton (PEC/EF) process containing a Pt/TiO2NTs photoanode and an air-diffusion PTFE cathode is investigated in the degradation of the Acid Red 29 (AR29) dye. The photoelectrocatalytic (PEC), electro-Fenton (EF) and photoelectrocatalytic/electro-Fenton (PEC/EF) processes are compared in the performance of dye treatment. The mineralisation ability of the AR29 dye increased in the sequence PEC < EF < PEC/EF with total organic carbon (TOC) decays of 81%, 90% and 98%, respectively. The AR29 decays followed a pseudo first-order kinetic. The higher mineralisation capacity obtained for the PEC/EF process in comparison with the PEC and EF processes was ascribed to the additional production of (OH)-O-. by the photolytic reactions in bulk and on the Pt/TiO2NTs surface. The synergetic effect from the photocatalytic reduction of H2O2 onto the electrode surface (which minimises the electron/hole pair recombination) and the photolysis of Fe(III)-carboxylate complexes also enhanced the degradation efficiency of the coupled process. Finally, a plausible pathway for AR29 degradation via the PEC/EF process was proposed based on the by-products detected by HPLC and LC-MS/MS. (C) 2014 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 11/21606-9 - Synthesis and characterization of Ti/TiO2-Pt and Ti/TiO2/WO3 photoanodes for application in the degradation of VAT dyes by photoelectro-Fenton process
Grantee:Lucio César de Almeida
Support type: Scholarships in Brazil - Post-Doctorate