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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Structural investigation of nickel polyphosphate coacervate glass-ceramics

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Author(s):
Franco, Douglas F. ; Manzani, Danilo ; Barud, Hernane S. ; Antonio, Selma G. ; de Oliveira, Luiz F. C. ; Silva, Mauricio A. P. ; Ribeiro, Sidney J. L. ; Nalin, Marcelo
Total Authors: 8
Document type: Journal article
Source: RSC ADVANCES; v. 6, n. 94, p. 91150-91156, 2016.
Web of Science Citations: 2
Abstract

Nickel polyphosphate coacervates have been prepared through the coacervation process of sodium polyphosphate and Ni2+ chloride solutions by the addition of different solvents with low molecular weight. The great potential of nickel polyphosphate coacervates as a material precursor was demonstrated by preparation of nickel polyphosphate glass-ceramics. Structural and spectroscopic properties were analyzed by thermal analysis, X-ray powder diffraction, Raman spectroscopic and UV-VIS techniques. Raman spectra for the nickel polyphosphate coacervates and nickel polyphosphate coacervates glass-ceramics samples shows that the addition of solvents leads to a depolymerization of the polyphosphate chains, resulting in an increase of shorter chains species based on pyrophosphates. The identification and quantification of Ni2P4O12, beta-Ni2P2O7 and delta-Ni2P2O7 crystalline phases present in the nickel polyphosphate glass-ceramics were carried out by X-ray powder diffraction using the Rietveld method. Quantitative phase analyses of the three polymorph forms were also evaluated. Based on interpretation of reflectance spectroscopy and Rietveld refinement, Ni2+ ions may occupy distorted octahedral and tetrahedral sites. (AU)

FAPESP's process: 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass
Grantee:Edgar Dutra Zanotto
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC