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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Marrying SPR excitation and metal-support interactions: unravelling the contribution of active surface species in plasmonic catalysis

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Geonmonond, Rafael S. [1] ; Quiroz, Jhon [1] ; Rocha, Guilherme F. S. R. [1] ; Oropeza, Freddy E. [2] ; Rangel, Clara J. [1] ; Rodrigues, Thenner S. [3] ; Hofmann, Jan P. [2] ; Hensen, Emiel J. M. [2] ; Ando, Romulo A. [1] ; Camargo, Pedro H. C. [1]
Total Authors: 10
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Ave Prof Lineu Prestes 748, BR-05508000 Sao Paulo, SP - Brazil
[2] Eindhoven Univ Technol, Lab Inorgan Mat Chem, Dept Chem Engn & Chem, POB 513, NL-5600 MB Eindhoven - Netherlands
[3] IPEN CNEN, Inst Pesquisas Energet & Nucl, BR-05508000 Sao Paulo, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: NANOSCALE; v. 10, n. 18, p. 8560-8568, MAY 14 2018.
Web of Science Citations: 4

Plasmonic catalysis takes advantage of the surface plasmon resonance (SPR) excitation to drive or accelerate chemical transformations. In addition to the plasmonic component, the control over metal-support interactions in these catalysts is expected to strongly influence the performances. For example, CeO2 has been widely employed towards oxidation reactions due to its oxygen mobility and storage properties, which allow for the formation of Ce3+ sites and adsorbed oxygen species from metal-support interactions. It is anticipated that these species may be activated by the SPR excitation and contribute to the catalytic activity of the material. Thus, a clear understanding of the role played by the SPR-mediated activation of surface oxide species at the metal-support interface is needed in order to take advantage of this phenomenon. Herein, we describe and quantify the contribution from active surface oxide species at the metal-support interface (relative to O-2 from air) to the activities in green SPR-mediated oxidation reactions. We employed CeO2 decorated with Au NPs (Au/CeO2) as a model plasmonic catalyst and the oxidation of p-aminothiophenol (PATP) and aniline as proof-of-concept transformations. We compared the results with SiO2 decorated with Au NPs (Au/SiO2), in which the formation of surface oxide species at the metal-support interface is not expected. We found that the SPR-mediated activation of surface oxide species at the metal-support interface in Au/CeO2 played a pivotal role in the detected activities, being even higher than the contribution coming from the activation of O-2 from air. (AU)

FAPESP's process: 15/21366-9 - Hybrid materials containing metal nanoparticles for catalytic applications
Grantee:Pedro Henrique Cury Camargo
Support type: Regular Research Grants
FAPESP's process: 15/26308-7 - Optimization of the physicochemical properties of nano -structured materials for applications in molecular recognition, catalysis and energy conversion/storage
Grantee:Roberto Manuel Torresi
Support type: Research Projects - Thematic Grants