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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Electrochemical Deposition of the Single Phase TlxCu3-xSe2 Thin Films

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Lucas, Francisco W. S. [1] ; Mascaro, Lucia H. [1]
Total Authors: 2
[1] Univ Fed Sao Carlos, Dept Quim, BR-13565905 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Journal of the Brazilian Chemical Society; v. 29, n. 12, p. 2449-2456, DEC 2018.
Web of Science Citations: 0

In spite of selenide semiconductors having a wide application area, TlCu2Se2(TCSe) is poorly studied and its synthesis by non-vacuum or thermic methodology in film form is non-existent. Generally, the main problems of applying these TCSe compounds are related to complicated single phase growth. and the great time consuming and non-scalable fabrication method. In this work, the facile, fast, scalable and new electrochemical deposition of this material was proposed as a workaround for these main problems and obtaining single phase thin film. Thus, the electrodeposited TlxCu3-xSe2 films were characterized by scanning electron microscopy. X-ray diffraction (with Rietveld refinement) and energy dispersive X-ray spectroscopy. They showed interesting variation of composition (x =1.1,1.2, and 1.25) and morphology as function of the electrodeposition potential, electrolytic bath temperature and thermal treatment. (AU)

FAPESP's process: 12/10947-2 - Preparation and characterization of MBSe thin films (M = Ag or Cu; B = In, Ga, Sb or Tl; and S = S or Se) for application in photovoltaic cells"
Grantee:Francisco Willian de Souza Lucas
Support type: Scholarships in Brazil - Doctorate
FAPESP's process: 16/10513-3 - Synthesis and Application of Functional Nanostructured Materials in Electro/photoelectrocatalysis under Continuous Flow Conditions: A New Perspective for Synthesis and Functionalization of Heterocyclic System.
Grantee:Francisco Willian de Souza Lucas
Support type: Scholarships in Brazil - Post-Doctorate
FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
Grantee:Elson Longo da Silva
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC