CO2 Reduction of Hybrid Cu2O-Cu/Gas Diffusion Layer Electrodes and their Integration in a Cu-based Photoelectrocatalytic Cell

Author(s)

de Brito, Juliana Ferreira ^{[1, 2, 3, 4]} ; Genovese, Chiara ^{[1, 2, 3]} ; Tavella, Francesco ^{[1, 2, 3]} ; Ampelli, Claudio ^{[1, 2, 3]} ; Zanoni, Maria Valnice Boldrin ^[4] ; Centi, Gabriele ^{[1, 2, 3]} ; Perathoner, Siglinda ^{[1, 2, 3]}

Affiliation

^[1] Univ Messina, ERIC Aisbl, Viale F Stagno dAlcontres 31, I-98166 Messina - Italy

^[2] Univ Messina, CASPE INSTM, Dept ChiBioFarAm, Viale F Stagno dAlcontres 31, I-98166 Messina - Italy

^[3] Univ Messina, CASPE INSTM, Dept MIFT, Viale F Stagno dAlcontres 31, I-98166 Messina - Italy

^[4] Univ Estadual Paulista UNESP, Inst Chem Araraquara, Rua Francisco Degni 55, BR-14800900 Araraquara, SP - Brazil

• Document type: Journal article
• Source: CHEMSUSCHEM; v. 12, n. 18 AUG 2019.
• Web of Science Citations: 1

Abstract

Cu2O/gas diffusion layer (GDL) electrodes prepared by electrodeposition were studied for the electrocatalytic reduction of CO2. The designed electrode was also tested in solar-light-induced CO2 conversion in combination with a CuO/NtTiO(2) photoanode using a compact photoelectrocatalytic (PEC) cell. Both PEC cell electrodes were prepared using non-critical raw materials and low cost, easily scalable procedures. In the PEC experiments, a total carbon faradaic selectivity of about 90 % to formate and about 75 % to acetate was obtained after 24 h of operations without application of potential/current or using sacrificial agents. In electrocatalytic tests of CO2 reduction at -1.5 V, the same electrode yielded high total faradaic selectivity (>95 %) but formed selectively formate (about 80 % selectivity) rather than acetate. The in situ transformation of the Cu2O/GDL electrode leads to the formation of a hybrid Cu2O-Cu/GDL system. Cyclic voltammetry data indicate that the potential and the presence of CO2 (not only of HCO3- species) are both important elements in this transformation. Data also indicate that the surface concentration of CO2 (or of its products of transformation) on the electrode is an important factor to determine performance in the conversion of CO2. (AU)

• FAPESP's process: 16/07895-1 - CO2 reduction in gas phase on carbon based GDL with different non-noble metal catalysts applying a specific photoelectrocatalysis designed reactor
• Grantee: Juliana Ferreira de Brito
• Support Opportunities: Scholarships abroad - Research Internship - Doctorate