| Full text | |
| Author(s): |
Herbert Winnischofer
[1]
;
Elizangela C. Cesca
[2]
;
Alejandro E. P. Mendoza
[3]
;
Iolanda P. Araújo
[4]
;
Eduard Westphal
;
Daniela Z. Mezalira
[6]
;
Débora T. Balogh
[7]
;
Osvaldo N. Oliveira Jr.
[8]
Total Authors: 8
|
| Affiliation: | [1] Universidade Federal do Paraná. Departamento de Química - Brasil
[2] Universidade Federal do Paraná. Departamento de Química - Brasil
[3] Universidade Federal do Paraná. Departamento de Química - Brasil
[4] Universidade Federal do Paraná. Departamento de Química - Brasil
[6] Universidade Federal de Santa Catarina. Departamento de Química - Brasil
[7] Universidade de São Paulo. Instituto de Física de São Carlos - Brasil
[8] Universidade de São Paulo. Instituto de Física de São Carlos - Brasil
Total Affiliations: 8
|
| Document type: | Journal article |
| Source: | Journal of the Brazilian Chemical Society; v. 31, n. 11, p. 2371-2384, 2020-10-30. |
| Abstract | |
The molecular control in Langmuir-Blodgett (LB) films may be exploited in charge storage electrodes provided a suitable choice of molecular architecture and components is made. In this paper, we employed a naphtyl-1,3,4-oxadiazole amphiphile (NFT1) and its complex [Ru(bpy)2NFT1]PF6 (RuNFT1) (bpy = 2,2’-bipyridine) in heterostructured LB films in a proof-of-principle production of charge storage. The optimized architecture contained a one-layer RuNFT1 deposited on a 9-layer NFT1 LB film, where the efficient packing of NFT1 inferred from spectroscopic measurements and Brewster angle microscopy (BAM) images was considered as relevant for ion diffusion. This packing was achieved owing to the π-stacking warranted by the planarity of the NFT1 naphtyl 1,3,4-oxadiazole ring, as confirmed with density functional theory (DFT) calculations. The top layer of the redox-active RuNFT1 provided an additional contribution with its Faradaic charge storage to the double layer capacitance of NFT1. Taken together, these results demonstrate that synergy may be achieved in combining distinct compounds in LB films toward efficient charge storage. (AU) | |
| FAPESP's process: | 13/14262-7 - Nanostructured films from biologically-relevant materials |
| Grantee: | Osvaldo Novais de Oliveira Junior |
| Support Opportunities: | Research Projects - Thematic Grants |