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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Enantioselective Heck-Matsuda Reactions: From Curiosity to a Game-Changing Methodology

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Oliveira, Caio C. [1] ; Duarte Correia, Carlos Roque [1]
Total Authors: 2
[1] Univ Estadual Campinas, Inst Chem, BR-10384612 Sao Paulo - Brazil
Total Affiliations: 1
Document type: Journal article
Source: CHEMICAL RECORD; v. 21, n. 10, SI, p. 2688-2701, OCT 2021.
Web of Science Citations: 0

The enantioselective palladium-catalyzed Heck arylation of olefins using arenediazonium salts is one of the last features in the evolution of a synthetic method known as the Heck-Matsuda reaction. This personal account highlights the development of the enantioselective Heck-Matsuda reaction in its initial stages, the challenges faced along the way, and the interesting findings that opened new synthetic opportunities, mainly from our laboratory, featuring the Heck-Matsuda reaction as a central player in the synthesis of bioactive and functional molecules. (AU)

FAPESP's process: 18/01669-5 - New quiral metal catalysts and their applications in asymmetric catalysis
Grantee:Caio Costa Oliveira
Support type: Research Grants - Young Investigators Grants
FAPESP's process: 13/07600-3 - CIBFar - Center for Innovation in Biodiversity and Drug Discovery
Grantee:Glaucius Oliva
Support type: Research Grants - Research, Innovation and Dissemination Centers - RIDC
FAPESP's process: 14/25770-6 - New frontiers in cross-coupling reactions promoted by palladium: combining enantioselective catalysis, C-H activations, new materials and in flux reactions aiming at high efficiency and sustainability in synthetic processes
Grantee:Carlos Roque Duarte Correia
Support type: Research Projects - Thematic Grants