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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

symmetric transformations from sulfoxonium ylide

Full text
Author(s):
Caiuby, Clarice A. D. [1] ; Furniel, Lucas G. [1] ; Burtoloso, Antonio C. B. [1]
Total Authors: 3
Affiliation:
[1] Univ Sao Paulo, Sao Carlos Inst Chem, BR-13560970 Sao Carlos, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: CHEMICAL SCIENCE; v. 13, n. 5 DEC 2021.
Web of Science Citations: 0
Abstract

Sulfoxonium ylides are important surrogates for diazo compounds, and their use in industry as safer alternatives has been evaluated during recent years. Beyond the known classical transformations, these ylides have also been used in a surprising plethora of novel and intrinsic chemical reactions, especially in recent years. Bench stability and handling are also an advantage of this class of organosulfur molecules. Despite this, efficient asymmetric transformations, specifically catalytic enantioselective versions, have only recently been reported, and there are specific reasons for this. This perspective article covers this topic from the first studies up to the latest advances, giving personal perspectives and showing the main challenges in this area in the coming years. (AU)

FAPESP's process: 18/17800-3 - New methodologies using sulfur ylides for the enantioselective alpha-Heterofunctionalization of carbonyl compounds
Grantee:Lucas Giani Furniel
Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
FAPESP's process: 20/07147-0 - Enantioselective alpha-heterofunctionalization of carbonyl compounds using sulfoxonium ylides
Grantee:Antonio Carlos Bender Burtoloso
Support Opportunities: Regular Research Grants
FAPESP's process: 20/11955-5 - Imidoyl sulfoxonium ylides as new precursors of a-imino metal-carbene complexes in organic synthesis
Grantee:Clarice Alves Dale Caiuby
Support Opportunities: Scholarships abroad - Research Internship - Doctorate
FAPESP's process: 17/23837-4 - Exploring the application of diazocarbonyl compounds and sulfur ylides in the asymmetric ring opening reactions with epoxides for the synthesis of oxetanes and functionalized alcohols
Grantee:Clarice Alves Dale Caiuby
Support Opportunities: Scholarships in Brazil - Doctorate