| Full text | |
| Author(s): |
Rodrigues, Joao Elias F. S.
;
Costa, Renilton C.
;
Pizani, Paulo S.
;
Hernandes, Antonio C.
;
Alonso, Jose A.
Total Authors: 5
|
| Document type: | Journal article |
| Source: | Journal of Raman Spectroscopy; v. N/A, p. 9-pg., 2022-05-03. |
| Abstract | |
The structural ordering process in complex perovskites has a pivotal role for tuning many physical properties for broad applications, ranging from microwave technology, proton-conduction, multiferroicity, and so on. Therefore, the characterization of order type in these materials is essential for designing new devices with high-performance. Here, the coexistence of B-site 1:1 and 1:2 order types in mixed ordered A(3)CaNb(2)O(9) (A = Ba, Sr) perovskite was investigated by combining Raman spectroscopy and high-resolution synchrotron X-ray powder diffraction. High-wavenumber interval 700-825 cm(-1) exhibits two bands concerning the symmetric breathing modes of [NbO6] octahedra in A(3)CaNb(2)O(9), which were ascribed to the 1:1 and 1:2 domain regions in coexistence. This model was fully corroborated using two phases for describing the synchrotron X-ray pattern of the Ba3CaNb2O9 sample. Therefore, the Raman spectroscopy can be indeed applied as a rapid tool for probing the achievement of ordered, partially ordered, or disordered structures in complex perovskites. For the first time, BaLaCaNbO6 was synthesized and structural characterized, being indexed by the monoclinic unit cell belonging to the space group I2/m$$ I2/m $$. (AU) | |
| FAPESP's process: | 13/07793-6 - CEPIV - Center for Teaching, Research and Innovation in Glass |
| Grantee: | Edgar Dutra Zanotto |
| Support Opportunities: | Research Grants - Research, Innovation and Dissemination Centers - RIDC |