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Unconventional magnetic ferroelectricity in the quadruple perovskite NaMn7O12

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Author(s):
Gastaldo, Vinicius Pascotto ; Klein, Yannick ; Baptiste, Benoit ; Cabassi, Riccardo ; Gilioli, Edmondo ; Gauzzi, Andrea ; de Oliveira, Adilson J. A.
Total Authors: 7
Document type: Journal article
Source: PHYSICAL REVIEW B; v. 102, n. 16, p. 5-pg., 2020-10-30.
Abstract

By means of magnetic, specific heat, and pyroelectric measurements, we report on magnetic ferroelectricity in the quadruple perovskite NaMn7O12, characterized by a canted antiferromagnetic (AFM) CE structure. Surprisingly, ferroelectricity is concomitant to a dramatic broadening of the magnetic hysteresis loop, well below the AFM ordering temperature. This unconventional behavior shows that the formation of ferroelectric domains is induced by the symmetric exchange interaction in the local scale, e.g., at magnetic domain boundaries or defects. The value of electric polarization, P = 0.027 mu C cm(2), measured in polycrystalline samples is comparatively large as compared to other magnetic multiferroics, suggesting that the above scenario is promising indeed for the rational design of practical multiferroic materials. (AU)

FAPESP's process: 17/24995-2 - Magnetism in multifunctional materials
Grantee:Adilson Jesus Aparecido de Oliveira
Support Opportunities: Regular Research Grants
FAPESP's process: 13/07296-2 - CDMF - Center for the Development of Functional Materials
Grantee:Elson Longo da Silva
Support Opportunities: Research Grants - Research, Innovation and Dissemination Centers - RIDC
FAPESP's process: 13/27097-4 - Magnetic and electrical properties of multiferroic systems: single-phase and composites
Grantee:Vinicius Pascotto Gastaldo
Support Opportunities: Scholarships in Brazil - Doctorate (Direct)
FAPESP's process: 15/21206-1 - Growth of thin films of quadruple multiferroic perovskite and investigation of the electron-phonon coupling using thermal and optics measurements.
Grantee:Vinicius Pascotto Gastaldo
Support Opportunities: Scholarships abroad - Research Internship - Doctorate (Direct)
FAPESP's process: 12/21171-5 - Study of the magnetoelectric coupling in quadruple perovskites
Grantee:Adilson Jesus Aparecido de Oliveira
Support Opportunities: Research Grants - Visiting Researcher Grant - International