Exploring the potential of cellulose autofluorescence for optical detection of tannin in red wines

Author(s)

Teodoro, Kelcilene B. R. ; Silva, Maycon J. ; Andre, Rafaela S. ; Schneider, Rodrigo ; Martins, Maria A. ; Mattoso, Luiz H. C. ; Correa, Daniel S.

• Document type: Journal article
• Source: Carbohydrate Polymers; v. 324, p. 11-pg., 2023-10-19.

Abstract

The growing demand for opto-electronic devices within an automated landscape has opened up new opportunities for harnessing sustainable cellulose materials for sensors technology. Cellulose, a versatile material, enables its combination with other materials, but in most of these applications, cellulose is typically employed as support or substrate, while its inherent autofluorescence remains largely underexplored for sensors. In light of this context, this study delves into the autofluorescence characteristics of pristine cellulose nanocrystals extracted from wood via enzymatic route for optical sensors tailored to detect tannins. By fine-tuning the experimental setup, photoluminescence (PL) emission bands were scrutinized across three distinct spectral regions, namely 300-400 nm, 400-500 nm and 550-700 nm. The proposed mechanism reveals the occurrence of dynamic fluorescence quenching, which enabled the selective monitoring of tannins in red wines across a dynamic range spanning from 10 to 1060 mu g mL-1. This sensing platform provided a limit of detection (LoD) of 6.1 mu g mL-1. Notably, the sensing platform's efficacy was validated with remarkable recovery rates of 99.7 % and 95.3 % when subjected to testing with cabernet sauvignon and tannat wines. These findings emphasize the sensing platform's potential for monitoring tannic acids in beverages and food products. (AU)

• FAPESP's process: 18/18468-2 - Molybdenum disulphide (MoS2) nanostructures syntheses methodologies and evaluation of their potential application in pollutants adsorption systems
• Grantee: Rodrigo Schneider
• Support Opportunities: Scholarships in Brazil - Doctorate