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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Extremely Efficient Alkane Oxidation by a New Catalytic Reagent H2O2/Os-3(CO)(12)/Pyridine

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Author(s):
Shul'pin, Georgiy B. [1] ; Kozlov, Yuriy N. [1] ; Shul'pina, Lidia S. [2] ; Kudinov, Alexander R. [2] ; Mandelli, Dalmo [3]
Total Authors: 5
Affiliation:
[1] Russian Acad Sci, NN Semenov Chem Phys Inst, Moscow 119991 - Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991 - Russia
[3] Pontificia Univ Catolica Campinas, Fac Quim, BR-13086900 Campinas, SP - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Inorganic Chemistry; v. 48, n. 22, p. 10480-10482, NOV 16 2009.
Web of Science Citations: 106
Abstract

Triosmium dodecacarbonyl catalyzes a very efficient oxidation of alkanes by H(2)O(2) in MeCN to afford alkyl hydroperoxides (primary products) as well as alcohols and ketones (aldehydes) at 60 degrees C if pyridine is added in a low concentration. Turnover numbers attain 60 000, and turnover frequencies are up to 24 000 h(-1). (AU)

FAPESP's process: 06/03996-6 - Oxidation of organic compounds including natural products catalysed by transitions metals: Mn, Os and Cu
Grantee:Dalmo Mandelli
Support Opportunities: Regular Research Grants