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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Electrochemical behavior of a glassy-carbon electrode chemically modified with cadmium pentacyanonitrosylferrate in the presence of tetrahydrothiophene

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Author(s):
Paim, Leonardo L. [1] ; Stradiotto, Nelson R. [1]
Total Authors: 2
Affiliation:
[1] Univ Estadual Paulista UNESP, Inst Chem, Dept Analyt Chem, BR-14801970 Araraquara, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: JOURNAL OF ELECTROANALYTICAL CHEMISTRY; v. 663, n. 1, p. 43-47, DEC 1 2011.
Web of Science Citations: 1
Abstract

A glassy-carbon electrode was modified with cadmium pentacyanonitrosylferrate film using cyclic voltammetry. The voltammetry behavior of the cadmium pentacyanonitrosylferrate on the glassy-carbon electrode shows a redox couple (Fe(III)/Fe(II)) with E of 593 mV (I(pa)/I(pc) = 0.96) and Delta E(p), of 34 mV in 0.5 mol dm(-3) KNO(3) (nu = 100 mV s(-1)) with an adsorption-controlled process. The anodic-peak currents of the film decreased in the presence of tetrahydrothiophene clue to a reaction of the precipitation on the film surface by a nucleophilic attack. (C) 2011 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 07/07700-7 - Development of sensors based on modified electrodes with pentacyanonitrosylferrates for determination of sulphur components in natural gas
Grantee:Leonardo Lataro Paim
Support type: Scholarships in Brazil - Doctorate