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(Reference retrieved automatically from SciELO through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Evaluation of a PVC Sensing Phase for Determination of Chlorinated Hydrocarbons in Water by Mid-Infrared Spectroscopy

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Author(s):
Andréa Monteiro S. Silva ; Eduardo de Araujo Viana ; Maria Fernanda Pimentel ; Yeda M. B. Almeida ; Ivo M. Raimundo Jr
Total Authors: 5
Document type: Journal article
Source: Journal of the Brazilian Chemical Society; v. 22, n. 8, p. 1470-1477, Ago. 2011.
Web of Science Citations: 1
Abstract

In this work, mid-infrared spectroscopy has been employed to investigate the effect of amount (25 or 40%) and type of plasticiser (di-2-ethylhexyl sebacate (DOS), di-2-ethylhexyl phthalate (DOP) and 2-nitrophenyl octyl ether (NPOE)) on the analytical response of a poly(vinylchloride) (PVC) sensing phase for the determination of the chlorinated hydrocarbons (chlorobenzene (ClB), trichloroethylene (TCE) and trichlorobenzene (TCB)) in water. It was observed that films with 40% of plasticiser provided higher sensitivity and lower limits of detection than those with 25%, although the later films are easier to handle. A similar behaviour was also observed for sensing phases prepared with the plasticisers NPOE and DOS. By employing a DOS-based PVC sensing phase and extraction time of 60 min, limits of detection of 0.3, 0.6, and 0.5 mg L-1 were obtained for chlorobenzene, trichloroethylene and trichlorobenzene, respectively. (AU)

FAPESP's process: 08/57808-1 - National Institute of Advanced Analytical Science and Technology
Grantee:Celio Pasquini
Support type: Research Projects - Thematic Grants