Recuperação de íons metálicos nobres e íons terras-raras presentes em soluções aquosas por bioadsorção em partículas de blenda de sericina e alginato

• Processo: 17/18236-1
• Modalidade de apoio: Auxílio à Pesquisa - Regular
• Vigência: 01 de junho de 2018 - 30 de novembro de 2020
• Área do conhecimento: Engenharias - Engenharia Química - Operações Industriais e Equipamentos para Engenharia Química
• Pesquisador responsável: Melissa Gurgel Adeodato Vieira
• Beneficiário: Melissa Gurgel Adeodato Vieira
• Instituição Sede: Faculdade de Engenharia Química (FEQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brasil
• Pesquisadores associados: Marcelino Luiz Gimenes ; Meuris Gurgel Carlos da Silva ; Thiago Lopes da Silva
• Assunto(s): Sericina Engenharia ambiental Alginatos Terras raras Reticulação
• Palavra(s)-Chave do Pesquisador: alginato | bioadsorção | metais nobres | Reticulação | sericina | Terras-Raras | Tratamento e recuperação de íons metálicos | Engenharia Ambiental

Resumo

A sericina é uma proteína globular hidrossolúvel, que reveste externamente o fio de seda (fibroína) e que apresenta grande capacidade de absorção de água, além das propriedades antioxidantes, antibactericidas e de resistência a radiação UV. Apesar de tratada como resíduo do processo industrial da fiação da seda, as propriedades físicas e químicas desta proteína possibilitam sua utilização em diversos materiais. A recuperação e desenvolvimento de produtos a partir desta proteína podem representam minimização da carga poluidora dos efluentes dos processos de fiação além de promover benefícios econômicos e sociais significativos a toda cadeia sericultora. Esta proposta objetiva investigar o desenvolvimento de partículas de sericina e alginato a partir do método de gelificação iônica para serem utilizadas em processos de adsorção de íons metálicos nobres e íons terras-raras. A sericina será extraída dos casulos por via física em autoclave e após o fracionamento da proteína por congelamento, soluções ajustadas serão utilizadas no preparo da blenda com alginato e produção de partículas, avaliando-se ainda diferentes agentes reticulantes. O estudo de afinidade metálica das partículas obtidas pelos metais nobres e terras-raras e os estudos cinético e de equilíbrio da adsorção dos adsorbatos de maior afinidade com as partículas mais promissoras fazem parte do escopo deste projeto, bem como a sua caracterização antes e pós-processo. Estudos de reuso dos materiais visando à recuperação dos íons metálicos e de comparação de eficiência de adsorção com outros adsorventes alternativos e de baixo custo serão efetuados. (AU)

Publicações científicas

(47)

(Referências obtidas automaticamente do Web of Science e do SciELO, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores)

DAS GRACAS SANTOS, NILZA TATIANE; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Development of novel sericin and alginate-based biosorbents for precious metal removal from wastewater. Environmental Science and Pollution Research, v. 26, n. 28, SI, p. 28455-28469, OCT 2019. (17/18236-1)

DO NASCIMENTO JUNIOR, WELENILTON JOSE; LANDERS, RICHARD; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Equilibrium and desorption studies of the competitive binary biosorption of silver(I) and copper(II) ions on brown algae waste. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 1, FEB 2021. (17/18236-1, 19/11353-8)

DE SA COSTA, HELOISA PEREIRA; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Application of alginate extraction residue for Al(III) ions biosorption: a complete batch system evaluation. Environmental Science and Pollution Research, MAY 2021. (17/18236-1, 19/11353-8)

DA SILVA, THIAGO LOPES; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Palladium adsorption on natural polymeric sericin-alginate particles crosslinked by polyethylene glycol diglycidyl ether. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 4, AUG 2021. (17/18236-1)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Recovery of rare-earth metals from aqueous solutions by bio/adsorption using non-conventional materials: a review with recent studies and promising approaches in column applications. JOURNAL OF RARE EARTHS, v. 38, n. 4, p. 339-355, APR 2020. (17/18236-1)

VITORINO DE FARIAS, ANA BEATRIZ; DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Cerium recovery from aqueous solutions by bio/adsorption: A review in a circular economy context. JOURNAL OF CLEANER PRODUCTION, v. 326, DEC 1 2021. (17/18236-1)

DE CARVALHO NEVES, HENRIQUE SANTANA; DA SILVA, THIAGO LOPES; CARLOS DA SILVA, MEURIS GURGEL; GUIRARDELLO, REGINALDO; ADEODATO VIEIRA, MELISSA GURGEL. Ion exchange and adsorption of cadmium from aqueous media in sodium-modified expanded vermiculite. Environmental Science and Pollution Research, v. N/A, p. 17-pg., 2022-01-16. (17/18236-1)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Biosorption of rare-earth and toxic metals from aqueous medium using different alternative biosorbents: evaluation of metallic affinity. Environmental Science and Pollution Research, SEP 2021. (17/18236-1)

DAS GRACAS SANTOS, NILZA TATIANE; LANDERS, RICHARD; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Adsorption of Gold Ions onto Sericin and Alginate Particles Chemically Crosslinked by Proanthocyanidins: a Complete Fixed-Bed Column Study. Industrial & Engineering Chemistry Research, v. 59, n. 1, p. 318-328, JAN 8 2020. (17/18236-1)

DIAS COSTA, CAMILA STEFANNE; BERTAGNOLLI, CAROLINE; BOOS, ANNE; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Application of a dealginated seaweed derivative for the simultaneous metal ions removal from real and synthetic effluents. JOURNAL OF WATER PROCESS ENGINEERING, v. 37, p. 11-pg., 2020-10-01. (14/04050-5, 17/18236-1)

BRIAO, GIANI DE VARGAS; DE ANDRADE, JULIA RESENDE; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Removal of toxic metals from water using chitosan-based magnetic adsorbents. A review. ENVIRONMENTAL CHEMISTRY LETTERS, v. 18, n. 4, p. 1145-1168, JUL 2020. (17/18236-1)

COSTA, HELOISA PEREIRA DE SA; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Fixed bed biosorption and ionic exchange of aluminum by brown algae residual biomass. JOURNAL OF WATER PROCESS ENGINEERING, v. 42, AUG 2021. (17/18236-1)

BRIAO, GIANI DE VARGAS; DA SILVA, MEURIS GURGEL; VIEIRA, MELISSA GURGEL ADEODATO. Adsorption potential for the concentration and recovery of rare earth metals from NdFeB magnet scrap in the hydrometallurgical route: A review in a circular economy approach. JOURNAL OF CLEANER PRODUCTION, v. 380, p. 17-pg., 2022-12-20. (17/18236-1)

PAIXAO, GUSTAVO ROCHA; CAMPAROTTO, NATALIA GABRIELE; BRIAO, GIANI DE VARGAS; OLIVEIRA, RAFAEL DE LIMA; COLMENARES, JUAN CARLOS; PREDIGER, PATRICIA; VIEIRA, MELISSA GURGEL ADEODATO. Synthesis of mesoporous P-doped carbon and its application in propranolol drug removal: Characterization, kinetics and isothermal studies. CHEMICAL ENGINEERING RESEARCH & DESIGN, v. 187, p. 15-pg., 2022-11-01. (19/07822-2, 17/18236-1)

BRIAO, GIANI DE VARGAS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Efficient and Selective Adsorption of Neodymium on Expanded Vermiculite. Industrial & Engineering Chemistry Research, v. 60, n. 13, p. 4962-4974, APR 7 2021. (17/18236-1)

BRIAO, GIANI DE VARGAS; DA SILVA, MEURIS GURGEL; VIEIRA, MELISSA GURGEL ADEODATO. Expanded vermiculite as an alternative adsorbent for the dysprosium recovery. Journal of the Taiwan Institute of Chemical Engineers, v. 127, p. 228-235, OCT 2021. (17/18236-1)

BRIAO, GIANI DE VARGAS; AGOSTINHO, FERNANDO ANTONIO; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Renewable and Selective Vermiculite Fixed Bed for the Rare-Earth Dysprosium Recovery. Industrial & Engineering Chemistry Research, v. 61, n. 25, p. 10-pg., 2022-06-10. (17/18236-1)

NISHIKAWA, EMILY; CARDOSO, SAULO LUIZ; DIAS COSTA, CAMILA STEFANNE; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. New perception of the continuous biosorption of cadmium on a seaweed derivative waste. JOURNAL OF WATER PROCESS ENGINEERING, v. 36, AUG 2020. (17/18236-1)

DA COSTA, TALLES BARCELOS; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Equilibrium, Thermodynamic, Reuse, and Selectivity Studies for the Bioadsorption of Lanthanum onto Sericin/Alginate/Poly(vinyl alcohol) Particles. POLYMERS, v. 13, n. 4, FEB 2021. (17/18236-1)

DE SA COSTA, HELOISA PEREIRA; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Biosorption of aluminum ions from aqueous solutions using non-conventional low-cost materials: A review. JOURNAL OF WATER PROCESS ENGINEERING, v. 40, APR 2021. (17/18236-1)

DA COSTA, TALLES BARCELOS; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Recovery of dysprosium by biosorption onto a biocomposite from sericin and alginate. JOURNAL OF WATER PROCESS ENGINEERING, v. 44, DEC 2021. (17/18236-1)

DE FREITAS, GEOVANI ROCHA; ADEODATO VIEIRA, MELISSA GURGEL; CARLOS DA SILVA, MEURIS GURGEL. Characterization and biosorption of silver by biomass waste from the alginate industry. JOURNAL OF CLEANER PRODUCTION, v. 271, p. 8-pg., 2020-10-20. (17/18236-1, 16/06173-2, 14/04050-5)

DE FREITAS, GEOVANI ROCHA; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Biosorption technology for removal of toxic metals: a review of commercial biosorbents and patents. Environmental Science and Pollution Research, v. 26, n. 19, SI, p. 19097-19118, JUL 2019. (16/06173-2, 17/18236-1, 14/04050-5)

DO NASCIMENTO JUNIOR, WELENILTON JOSE; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Competitive biosorption of Cu2+ and Ag+ ions on brown macro-algae waste: kinetic and ion-exchange studies. Environmental Science and Pollution Research, v. 26, n. 23, p. 23416-23428, AUG 2019. (17/18236-1)

VIEIRA, WEDJA TIMOTEO; FARIAS, MARINA BARBOSA DE; SPAOLONZI, MARCELA PIRES; SILVA, MEURIS GURGEL CARLOS DA; VIEIRA, MELISSA GURGEL ADEODATO. Endocrine-disrupting compounds: Occurrence, detection methods, effects and promising treatment pathways-A critical review. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 1, FEB 2021. (17/18236-1, 19/11353-8)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Crosslinked alginate/sericin particles for bioadsorption of ytterbium: Equilibrium, thermodynamic and regeneration studies. International Journal of Biological Macromolecules, v. 165, n. B, p. 1911-1923, DEC 15 2020. (17/18236-1, 19/11353-8)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Lanthanum biosorption using sericin/alginate particles crosslinked by poly (vinyl alcohol): Kinetic, cation exchange, and desorption studies. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 4, AUG 2021. (17/18236-1)

VIEIRA, WEDJA TIMOTEO; DE FARIAS, MARINA BARBOSA; SPAOLONZI, MARCELA PIRES; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Latest advanced oxidative processes applied for the removal of endocrine disruptors from aqueous media - A critical report. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 4, AUG 2021. (17/18236-1)

BRIAO, GIANI DE VARGAS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Neodymium recovery from aqueous solution through adsorption/desorption onto expanded vermiculite. APPLIED CLAY SCIENCE, v. 198, NOV 15 2020. (17/18236-1)

DAS GRACAS SANTOS, NILZA TATIANE; MORAES, LUIZA FERNANDES; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Recovery of gold through adsorption onto sericin and alginate particles chemically crosslinked by proanthocyanidins. JOURNAL OF CLEANER PRODUCTION, v. 253, APR 20 2020. (17/18236-1)

DE FREITAS, GEOVANI ROCHA; ADEODATO VIEIRA, MELISSA GURGEL; CARLOS DA SILVA, MEURIS GURGEL. Fixed bed biosorption of silver and investigation of functional groups on acidified biosorbent from algae biomass. Environmental Science and Pollution Research, v. 26, n. 36, NOV 2019. (17/18236-1, 16/06173-2)

BRIAO, GIANI DE VARGAS; FRANCO, DISON STRACKE PFINGSTEN; DA SILVA, FLAVIO VASCONCELOS; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Critical rare earth metal adsorption onto expanded vermiculite: Accurate modeling through response surface methodology and machine learning techniques. SUSTAINABLE CHEMISTRY AND PHARMACY, v. 31, p. 15-pg., 2023-04-01. (17/18236-1)

NASCIMENTO JUNIOR, W. J.; SILVA, M. G. C.; VIEIRA, M. G. A.. Competitive fixed -bed biosorption of Ag(I) and Cu(II) ions on Sargassum fi lipendula seaweed waste. JOURNAL OF WATER PROCESS ENGINEERING, v. 36, AUG 2020. (17/18236-1)

DAS GRACAS SANTOS, NILZA TATIANE; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Development of novel sericin and alginate-based biosorbents for precious metal removal from wastewater. Environmental Science and Pollution Research, v. 26, n. 28, p. 15-pg., 2019-10-01. (17/18236-1)

DO NASCIMENTO JUNIOR, WELENILTON JOSE; LANDERS, RICHARD; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Equilibrium and desorption studies of the competitive binary biosorption of silver(I) and copper(II) ions on brown algae waste. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 1, p. 10-pg., 2021-02-01. (17/18236-1)

DE FREITAS, GEOVANI ROCHA; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Biosorption technology for removal of toxic metals: a review of commercial biosorbents and patents. Environmental Science and Pollution Research, v. 26, n. 19, p. 22-pg., 2019-07-01. (14/04050-5, 17/18236-1, 16/06173-2)

DE FARIAS, ANA BEATRIZ VITORINO; DA COSTA, TALLES BARCELOS; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Development of novel composite adsorbents based on biopolymers/vermiculite using the ionic imprinting technique for cerium biosorption. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 10, n. 6, p. 12-pg., 2022-10-12. (17/18236-1)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Crosslinked alginate/sericin particles for bioadsorption of ytterbium: Equilibrium, thermodynamic and regeneration studies. International Journal of Biological Macromolecules, v. 165, p. 13-pg., 2020-12-15. (17/18236-1)

VIEIRA, WEDJA TIMOTEO; FARIAS, MARINA BARBOSA DE; SPAOLONZI, MARCELA PIRES; SILVA, MEURIS GURGEL CARLOS DA; VIEIRA, MELISSA GURGEL ADEODATO. Endocrine-disrupting compounds: Occurrence, detection methods, effects and promising treatment pathways-A critical review. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 9, n. 1, p. 18-pg., 2021-01-24. (17/18236-1)

BRIAO, GIANI DE VARGAS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Reusable and efficient clay material for the fixed-bed neodymium recovery. SUSTAINABLE CHEMISTRY AND PHARMACY, v. 25, p. 14-pg., 2022-04-01. (17/18236-1)

DE FARIAS, ANA BEATRIZ VITORINO; DA COSTA, TALLES BARCELOS; DA SILVA, MEURIS GURGEL CARLOS; VIEIRA, MELISSA GURGEL ADEODATO. Cerium biosorption onto alginate/vermiculite-based particles functionalized with ionic imprinting: Kinetics, equilibrium, thermodynamic, and reuse studies. International Journal of Biological Macromolecules, v. 241, p. 11-pg., 2023-06-30. (17/18236-1)

DO NASCIMENTO JUNIOR, WELENILTON JOSE; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Competitive biosorption of Cu²⁺ and Ag⁺ ions on brown macro-algae waste: kinetic and ion-exchange studies. Environmental Science and Pollution Research, v. 26, n. 23, p. 13-pg., 2019-08-01. (17/18236-1)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Effective recovery of ytterbium through biosorption using crosslinked sericin-alginate beads: A complete continuous packed-bed column study. JOURNAL OF HAZARDOUS MATERIALS, v. 421, JAN 5 2022. (17/18236-1)

BRIAO, GIANI VARGAS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Dysprosium adsorption on expanded vermiculite: Kinetics, selectivity and desorption. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, v. 630, DEC 5 2021. (17/18236-1)

DA COSTA, TALLES BARCELOS; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Biosorption of lanthanum using sericin/alginate/polyvinyl alcohol beads as a natural cation exchanger in a continuous fixed-bed column system. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, v. 627, OCT 20 2021. (17/18236-1)

DE SA COSTA, HELOISA PEREIRA; CARLOS DA SILVA, MEURIS GURGEL; ADEODATO VIEIRA, MELISSA GURGEL. Application of alginate extraction residue for Al(III) ions biosorption: a complete batch system evaluation. Environmental Science and Pollution Research, v. 28, n. 37, p. 51826-51840, OCT 2021. (17/18236-1)

DE FARIAS, M. B.; SILVA, M. G. C.; VIEIRA, M. G. A.. Adsorption of bisphenol A from aqueous solution onto organoclay: Experimental design, kinetic, equilibrium and thermodynamic study. Powder Technology, v. 395, p. 695-707, JAN 2022. (17/18236-1)

Patente(s) depositada(s) como resultado deste projeto de pesquisa