Química supramolecular e nanotecnologia

• Processo: 13/24725-4
• Linha de fomento: Auxílio à Pesquisa - Temático
• Vigência: 01 de maio de 2014 - 30 de abril de 2019
• Área do conhecimento: Ciências Exatas e da Terra - Química - Química Inorgânica
• Pesquisador responsável: Henrique Eisi Toma
• Beneficiário: Henrique Eisi Toma
• Instituição-sede: Instituto de Química (IQ). Universidade de São Paulo (USP). São Paulo , SP, Brasil
• Pesquisadores principais: Koiti Araki
• Auxílios(s) vinculado(s): 17/50129-0 - Hybrid nanomaterials and nanosystems for solar fuel production, AP.R SPRINT
• Bolsa(s) vinculada(s): 18/25974-1 - Fotoquímica, fotofísica e fotoeletroquímica do íon ranelato, BP.DD; 18/04523-1 - Ativação de catalisadores para oxidação da água baseados em complexos binucleares de rutênio por grupos formadores de ligação de hidrogênio, BP.PD; 16/10406-2 - Desenvolvimento de nanopartículas superparamagnéticas funcionalizadas com complexantes seletivos para captura de metais visando aplicações analíticas e hidrometalúrgicas, BP.IC; 15/01271-3 - Desenvolvimento de Máquinas Moleculares Baseadas na Proteína Motora Cinesina, BP.PD
• Assunto(s): Nanotecnologia Nanopartículas Química supramolecular Eletroquímica Hidrometalurgia

Resumo

O projeto, voltado para a Nanotecnologia Molecular, tem como estratégia a química supramolecular, explorando as interações cooperativas e os efeitos de organização na geração de nanossistemas automontados funcionais. Em seu escopo está a elaboração de interfaces moleculares capazes de promover a separação de cargas, transporte de íons e a transferência vetorial de elétrons ou de energia. Os sistemas em desenvolvimento também contemplam a associação de moléculas com nanopartículas, proporcionando nanomateriais heterohíbridos funcionais. Novos sensores amperométricos estão sendo projetados com nanomateriais automontados sobre a superfície de eletrodos, assim como dispositivos mais eficientes para fotoconversão de energia. No global estão envolvidas 6 linhas de pesquisas envolvendo: i) novos sistemas supramoleculares e hetero-híbridos, ii) novos dispositivos eletroquímicos e fotoeletroquímicos de alto desempenho, iii) sensoriamento plasmônico e SERS iv) magneto-eletroquímica e nanohidrometalurgia, v) captura de íons metálicos e remediação ambiental e vi) catálise e nanobiocatálise magnética. Além das novas arquiteturas moleculares geradas, os estudos ampliarão o conhecimento e as aplicações da espectroscopia eletrônica e vibracional, eletroquímica, espectroeletroquímica, fotoquímica/fotofísica, SPR, fotoeletroquímica, e microscopias AFM/STM, Raman confocal e Hiperespectral. Patentes e transferência de tecnologia também estão na meta do projeto, visando as áreas de petróleo, energia solar, biotecnologia e mineração. (AU)

Publicações científicas

(46)

(Referências obtidas automaticamente do Web of Science e do SciELO, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores)

CANEVARI, THIAGO C.; CINCOTTO, FERNANDO H.; GOMES, DELMARCIO; LANDERS, RICHARD; TOMA, HENRIQUE E.. Magnetite Nanoparticles Bonded Carbon Quantum Dots Magnetically Confined onto Screen Printed Carbon Electrodes and their Performance as Electrochemical Sensor for NADH. Electroanalysis, v. 29, n. 8, p. 1968-1975, AUG 2017. (16/12519-9, 16/16565-5, 13/24725-4)

GONCALVES, JOSUE M.; GUIMARAES, ROBSON R.; BRANDAO, BRUNO B. N. S.; SARAVIA, LUCAS P. H.; ROSSINI, PAMELA O.; NUNES, JR., CICERO V.; BERNARDES, JULIANA S.; BERTTOTI, MAURO; ANGNES, LUCIO; ARAKI, KOITI. Nanostructured Alpha-NiCe Mixed Hydroxide for Highly Sensitive Amperometric Prednisone Sensors. Electrochimica Acta, v. 247, p. 30-40, SEP 1 2017. (13/24725-4)

CONDOMITTI, ULISSES; SILVEIRA JUNIOR, ALCEU T.; MATTIONI, JOAO V.; HASIMOTO, LEONARDO H.; TOMA, HENRIQUE E.. Bisphenol-A electronalysis employing carbon coated superparamagnetic nanoparticles for adsorption and magnetic concentration onto screen-printed electrodes. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 799, p. 299-303, AUG 15 2017. (13/24725-4)

SIHN, LUCA MICHAEL; DE MELO, FERNANDO MENEGATTI; TOMA, HENRIQUE EISI; PIRES SERRANO, SILVIA HELENA; ESPOSITO, BRENO PANNIA. A new ferrous diflunisal complex and its effects on biopools of labile iron. JOURNAL OF TRACE ELEMENTS IN MEDICINE AND BIOLOGY, v. 51, p. 65-72, 2019. (16/03709-9, 13/24725-4)

DE MELO, FERNANDO MENEGATTI; UCHIYAMA, MAYARA KLIMUK; NAKAMURA, MARCELO; KAWASSAKI, RODRIGO KEN; TABORDA, CARLOS PELLESCHI; TOMA, HENRIQUE EISI. Unravelling the nature of the spongy dark material in aged Turkevich gold 10 nanoparticles colloidal solutions by CytoViva (R) dark-field imaging and HRTEM analysis. Micron, v. 121, p. 21-25, JUN 2019. (13/24725-4, 17/09469-2)

BENAVIDES, PAOLA A.; MATIAS, TIAGO A.; ARAKI, KOITI. Unexpected lability of the [Ru-III(phtpy)Cl-3] complex. DALTON TRANSACTIONS, v. 46, n. 44, p. 15567-15572, NOV 28 2017. (13/24725-4)

GRASSESCHI, DANIEL; ZAMARION, VITOR M.; TOMA, HENRIQUE E.. Probing the dynamics of dithiooxamide coordinated to gold nanoparticles using SERS. Journal of Raman Spectroscopy, v. 49, n. 9, p. 1478-1486, SEP 2018. (13/24725-4, 17/09469-2)

CANEVARI, T. C.; CINCOTTO, F. H.; NAKAMURA, M.; MACHADO, S. A. S.; TOMA, H. E.. Efficient electrochemical biosensors for ethynylestradiol based on the laccase enzyme supported on single walled carbon nanotubes decorated with nanocrystalline carbon quantum dots. ANALYTICAL METHODS, v. 8, n. 39, p. 7254-7259, 2016. (12/18339-1, 13/24725-4)

AGUIRRE-ARAQUE, JUAN S.; ROCHA, REGINALDO C.; TOMA, HENRIQUE E.. Electrostatic bending and outer-sphere intervalence transfer in a flexible ligand-bridged ruthenium(III)-iron(II) complex. Journal of Coordination Chemistry, v. 71, n. 11-13, SI, p. 1778-1790, 2018. (13/24725-4)

HUILA, MANUEL F. G.; PARUSSULO, ANDRE L. A.; ARMAS, LUIS E. G.; PERES, HENRIQUE E. M.; SEABRA, ANTONIO C.; RAMIREZ-FERNANDEZ, FRANCISCO J.; ARAKI, KOITI; TOMA, HENRIQUE E.. Laser Patterning a Chem-FET Like Device on a V2O5 Xerogel Film. IEEE SENSORS JOURNAL, v. 18, n. 4, p. 1358-1363, FEB 15 2018. (13/24725-4)

DE MELO, FERNANDO MENEGATTI; ALMEIDA, SABRINA DA NOBREGA; UEZU, NOEMI SAORI; OSPINA RAMIREZ, CARLOS ALBERTO; DOS SANTOS, ANTONIO DOMINGUES; TOMA, HENRIQUE EISI. Extraction of Dysprosium Ions with DTPA Functionalized Superparamagnetic Nanoparticles Probed by Energy Dispersive X-ray Fluorescence and TEM/High-Angle Annular Dark Field Imaging. Journal of Nanoscience and Nanotechnology, v. 18, n. 6, p. 4155-4159, JUN 2018. (13/24725-4)

GONCALVES, JOSUE M.; MARTINS, PAULO R.; ARAKI, KOITI; ANGNES, LUCIO. Recent progress in water splitting and hybrid supercapacitors based on nickel-vanadium layered double hydroxides. JOURNAL OF ENERGY CHEMISTRY, v. 57, p. 496-515, JUN 2021. (18/16896-7, 13/24725-4, 18/21489-1)

GONCALVES, JOSUE M.; DA SILVA, MATHEUS I.; HASHEMINEJAD, MEISAM; TOMA, HENRIQUE E.; ARAKI, KOITI; MARTINS, PAULO R.; ANGNES, LUCIO. Recent Progress in Core@Shell Sulfide Electrode Materials for Advanced Supercapacitor Devices. BATTERIES & SUPERCAPS, v. 4, n. 9, p. 1397-1427, SEP 2021. (18/21489-1, 18/16896-7, 14/50867-3, 13/24725-4, 17/13137-5)

ALMEIDA, SABRINA DA N.; TOMA, HENRIQUE E.. Lanthanide ion processing from monazite based on magnetic nanohydrometallurgy. HYDROMETALLURGY, v. 189, NOV 2019. (13/24725-4)

GONCALVES, JOSUE M.; ALVES, KAMILLA M.; GONZALEZ-HUILA, MANUEL F.; DUARTE, ALFREDO; MARTINS, PAULO R.; ARAKI, KOITI. Unexpected Stabilization of alpha-Ni(OH)(2) Nanoparticles in GO Nanocomposites. Journal of Nanomaterials, 2018. (13/24725-4)

GARCIA-OSORIO, DANIEL; HIDALGO-FALLA, PILAR; PERES, HENRIQUE E. M.; GONCALVES, JOSUE M.; ARAKI, KOITI; GARCIA-SEGURA, SERGI; PICASSO, GINO. Silver Enhances Hematite Nanoparticles Based Ethanol Sensor Response and Selectivity at Room Temperature. SENSORS, v. 21, n. 2, JAN 2021. (13/24725-4, 18/16896-7)

JULIANA B. PARRA; KARINA C. SILVA; PEDRO A. S. VALEZIN; RAPHAEL G. MARTINS; RODOLFO R. GOMES; RAFAEL S. PEREIRA; FERNANDO M. DE MELO; ANDREIA DE A. MORANDIM-GIANNETTI; RONALDO G. DOS SANTOS; LUZ CONSUELO G. A. PANZARINI; et al. Preparation of Fluorescent Carbon-Based Dots from Waste Tire Pyrolysis. Journal of the Brazilian Chemical Society, v. 31, n. 11, p. 2224-2231, 2020-10-30. (17/09469-2, 13/24725-4)

HENRIQUE E. TOMA. AITP 2019 - ANO INTERNACIONAL DA TABELA PERIÓDICA DOS ELEMENTOS QUÍMICOS. Química Nova, v. 42, n. 4, p. 468-472, 2019-05-27. (13/24725-4)

GONCALVES, JOSUE M.; MATIAS, TIAGO A.; ANGNES, LUCIO; MARTINS, PAULO R.; ARAKI, KOITI. Review-Tetraruthenated Porphyrins and Composites as Catalysts and Sensor Materials: A Short Review. ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, v. 9, n. 6, JAN 8 2020. (13/24725-4, 18/16896-7, 17/13137-5, 18/21489-1, 17/50129-0, 14/50867-3)

CARDOSO, ROBERTA M.; DEDA, DAIANA K.; TOMA, SERGIO H.; BAPTISTA, MAURICIO S.; ARAKI, KOITI. Beyond electrostatic interactions: Ligand shell modulated uptake of bis-conjugated iron oxide nanoparticles by cells. COLLOIDS AND SURFACES B-BIOINTERFACES, v. 186, FEB 2020. (13/24725-4)

CAICEDO-REINA, MAURICIO; GUIMARAES, ROBSON R.; ORTIZ, ALEJANDRO; ARAKI, KOITI; INSUASTY, BRAULIO. New organic photosensitizers based on triphenylamine and hydantoin as anchoring group onto TiO2 Surface. Journal of Molecular Structure, v. 1251, MAR 5 2022. (13/24725-4)

GONCALVES, JOSUE M.; MARTINS, PAULO R.; ANGNES, LUCIO; ARAKI, KOITI. Recent advances in ternary layered double hydroxide electrocatalysts for the oxygen evolution reaction. NEW JOURNAL OF CHEMISTRY, v. 44, n. 24, p. 9981-9997, JUN 28 2020. (18/16896-7, 13/24725-4, 18/21489-1)

DA SILVA, DELMARCIO GOMES; TOMA, SERGIO HIROSHI; DE MELO, FERNANDO MENEGATTI; CARVALHO, LARISSA VIEIRA C.; MAGALHAES, ALVICLER; SABADINI, EDVALDO; DOS SANTOS, ANTONIO DOMINGUES; ARAKI, KOITI; TOMA, HENRIQUE E.. Direct synthesis of magnetite nanoparticles from iron(II) carboxymethylcellulose and their performance as NMR contrast agents. Journal of Magnetism and Magnetic Materials, v. 397, p. 28-32, JAN 1 2016. (13/24725-4)

ALMEIDA, SABRINA DA N.; TOMA, HENRIQUE E.. Neodymium(III) and lanthanum(III) separation by magnetic nanohydrometallurgy using DTPA functionalized magnetite nanoparticles. HYDROMETALLURGY, v. 161, p. 22-28, MAY 2016. (13/24725-4)

TOMA, HENRIQUE E.. Magnetic nanohydrometallurgy: a nanotechnological approach to elemental sustainability. GREEN CHEMISTRY, v. 17, n. 4, p. 2027-2041, 2015. (13/24725-4)

SILVA, JOSE LUIS; UNGER, ISAAK; MATIAS, TIAGO ARAUJO; FRANCO, LEANDRO REZENDE; DAMAS, GIANE; COSTA, LUCIANO T.; TOLEDO, KALIL C. F.; ROCHA, TULIO C. R.; DE BRITO, ARNALDO NAVES; SAAK, CLARA-MAGDALENA; et al. X-ray Photoelectron Fingerprints of High-Valence Ruthenium-Oxo Complexes along the Oxidation Reaction Pathway in an Aqueous Environment. Journal of Physical Chemistry Letters, v. 10, n. 24, p. 7636-7643, DEC 19 2019. (18/04523-1, 17/11986-5, 13/24725-4, 17/11631-2, 17/50129-0)

SANTOS, MOLIRIA V.; BARUD, HERNANE S.; ALENCAR, MONICA A. S.; NALIN, MARCELO; TOMA, SERGIO H.; ARAKI, KOITI; BENEDETTI, ASSIS V.; MACIEL, INDHIRA O.; FRAGNEAUD, BENJAMIN; LEGNANI, CRISTIANO; et al. Self-Supported Smart Bacterial Nanocellulose-Phosphotungstic Acid Nanocomposites for Photochromic Applications. FRONTIERS IN MATERIALS, v. 8, MAY 13 2021. (14/12424-2, 13/07793-6, 16/11591-8, 13/24725-4, 18/25512-8, 20/04509-9)

DA SILVA, DELMARCIO GOMES; DE MELO, FERNANDO MENEGATTI; SILVEIRA, JR., ALCEU TOTTI; DA CRUZ, BRUNO CONSTANCIO; PESTANA PRADO, CAIO CESAR; PEREIRA DE VASCONCELOS, LUANA CRISTINA; SANCHES LUCAS, VITOR AMARAL; TOMA, HENRIQUE EISI. Introducing Environmental and Sustainable Chemistry Topics Using a Nanotechnology Approach: Removing Hazardous Metal Ions by Means of Humic-Acid-Modified Superparamagnetic Nanoparticles. Journal of Chemical Education, v. 93, n. 11, p. 1929-1934, NOV 2016. (13/24725-4)

PARUSSULO, ANDRE L. A.; MATIAS, TIAGO A.; GUIMARAES, ROBSON R.; TOMA, SERGIO H.; ARAKI, KOITI; TOMA, HENRIQUE E.. Accessing the charge separation effects in dye-sensitized solar cells based on a vectorial planning of supramolecular ruthenium dyes. Inorganica Chimica Acta, v. 453, p. 764-770, NOV 1 2016. (13/24725-4)

CANEVARI, THIAGO C.; NAKAMURA, MARCELO; CINCOTTO, FERNANDO H.; DE MELO, FERNANDO M.; TOMA, HENRIQUE E.. High performance electrochemical sensors for dopamine and epinephrine using nanocrystalline carbon quantum dots obtained under controlled chronoamperometric conditions. Electrochimica Acta, v. 209, p. 464-470, AUG 10 2016. (13/24725-4)

CINCOTTO, FERNANDO H.; CARVALHO, DANIEL A. S.; CANEVARI, THIAGO C.; TOMA, HENRIQUE E.; FATIBELLO-FILHO, ORLANDO; MORAES, FERNANDO C.. A nano-magnetic electrochemical sensor for the determination of mood disorder related substances. RSC ADVANCES, v. 8, n. 25, p. 14040-14047, 2018. (16/12519-9, 16/12926-3, 16/16565-5, 13/24725-4, 11/13312-5)

MELO, FERNANDO M.; SILVEIRA, ALCEU T.; QUARTAROLLI, LUCAS F.; KAID, FELIPE F.; CORNEJO, DANIEL R.; TOMA, HENRIQUE E.. Magnetic behavior of superparamagnetic nanoparticles containing chelated transition metal ions. Journal of Magnetism and Magnetic Materials, v. 487, OCT 1 2019. (13/24725-4)

DE MELO, FERNANDO MENEGATTI; FANTE, ALLEF SOARES; ZAMARION, VITOR DE M.; TOMA, HENRIQUE EISI. SERS-active carboxymethyl cellulose-based gold nanoparticles: high-stability in hypersaline solution and selective response in the Hofmeister series. NEW JOURNAL OF CHEMISTRY, v. 43, n. 21, p. 8093-8100, JUN 7 2019. (17/09469-2, 13/24725-4)

DE MELO, FERNANDO MENEGATTI; GRASSESCHI, DANIEL; BRANDAO, BRUNO B. N. S.; FU, YING; TOMA, HENRIQUE E.. Superparamagnetic Maghemite-Based CdTe Quantum Dots as Efficient Hybrid Nanoprobes for Water-Bath Magnetic Particle Inspection. ACS APPLIED NANO MATERIALS, v. 1, n. 6, p. 2858-2868, JUN 2018. (13/24725-4)

CORREA, ANABEL LAZA; GONCALVES, JOSUE M.; ROSSINI, PAMELA O.; BERNARDES, JULIANA S.; NEVES, CARLOS A.; ARAKI, KOITI; ANGNES, LUCIO. Fast and reliable BIA/amperometric quantification of acetylcysteine using a nanostructured double hydroxide sensor. Talanta, v. 186, p. 354-361, AUG 15 2018. (13/24725-4)

OLIVEIRA, DANIEL; DE MELO, FERNANDO MENEGATTI; TOMA, HENRIQUE E.. One-pot single step to label microtubule with MPA-capped CdTe quantum dots. Micron, v. 108, p. 19-23, MAY 2018. (13/24725-4, 15/01271-3)

MARQUES NETTO, CATERINA G. C.; ANDRADE, LEANDRO H.; TOMA, HENRIQUE E.. Carbon dioxide/methanol conversion cycle based on cascade enzymatic reactions supported on superparamagnetic nanoparticles. Anais da Academia Brasileira de Ciências, v. 90, n. 1, 1, p. 593-606, 2018. (08/10177-7, 13/24725-4)

KUMAR, ABHISHEK; GONCALVES, JOSUE M.; SELVA, JESSICA S. G.; ARAKI, KOITI; BERTOTTIZ, MAURO. Correlating Selective Electrocatalysis of Dopamine and Ascorbic Acid Electrooxidation at Nanoporous Gold Surfaces with Structural-Defects. Journal of the Electrochemical Society, v. 166, n. 14, p. H704-H711, SEP 30 2019. (18/08782-1, 13/24725-4)

AGUIRRE-ARAQUE, JUAN S.; GONCALVES, JOSUE M.; NAKAMURA, MARCELO; ROSSINI, PAMELA O.; ANGNES, LUCIO; ARAKI, KOITI; TOMA, HENRIQUE E.. GO composite encompassing a tetraruthenated cobalt porphyrin-Ni coordination polymer and its behavior as isoniazid BIA sensor. Electrochimica Acta, v. 300, p. 113-122, MAR 20 2019. (13/24725-4, 17/13137-5)

DA SILVA, MARIA ROSANA E.; AUVRAY, THOMAS; LARAMEE-MILETTE, BAPTISTE; FRANCO, MAURICIO P.; BRAGA, ATAUALPA A. C.; TOMA, HENRIQUE E.; HANAN, GARRY S.. Unusual Photooxidation of S-Bonded Mercaptopyridine in a Mixed Ligand Ruthenium(II) Complex with Terpyridine and Bipyridine Ligands. Inorganic Chemistry, v. 57, n. 9, p. 4898-4905, MAY 7 2018. (13/24725-4, 14/25770-6, 15/01491-3)

HUILA, MANUEL F. G.; TOMA, HENRIQUE E.. Spectroelectrochemical study of the lithium insertion in vanadium(V) oxide xerogels. Electrochimica Acta, v. 278, p. 236-244, JUL 10 2018. (13/24725-4)

MATIAS, TIAGO A.; PARUSSULO, ANDRE L. A.; BENAVIDES, PAOLA A.; GUIMARAES, ROBSON R.; DOURADO, ANDRE H. B.; NAKAMURA, MARCELO; CORDOBA DE TORRESI, SUSANA I.; BERTOTTI, MAURO; ARAKI, KOITI. Polymeric binuclear ruthenium complex as efficient electrocatalyst for oxygen evolution reaction. Electrochimica Acta, v. 283, p. 18-26, SEP 1 2018. (13/25592-8, 13/24725-4, 15/26308-7)

GRASSESCHI, DANIEL; TOMA, HENRIQUE E.. The SERS effect in coordination chemistry. Coordination Chemistry Reviews, v. 333, p. 108-131, FEB 15 2017. (13/24725-4)

CAICEDO, MAURICIO; ECHEVERRY, CARLOS A.; GUIMARAES, ROBSON R.; ORTIZ, ALEJANDRO; ARAKI, KOITI; INSUASTY, BRAULIO. Microwave assisted synthesis of a series of charge-transfer photosensitizers having quinoxaline-2(1H)-one as anchoring group onto TiO2 surface. Journal of Molecular Structure, v. 1133, p. 384-391, APR 5 2017. (13/24725-4)

NOGUEIRA, HELTON P.; TOMA, SERGIO H.; SILVEIRA, ALCEU T.; CARVALHO, ALEXANDRINA A. C.; FIOROTO, ALEXANDRE M.; ARAKI, KOITI. Efficient Cr(VI) removal from wastewater by activated carbon superparamagnetic composites. Microchemical Journal, v. 149, SEP 2019. (13/24725-4)

DA SILVA, I, MATHEUS; MACHADO, ITALO R.; TOMA, HENRIQUE E.; ARAKI, KOITI; ANGNES, LUCIO; GONCALVES, JOSUE M.. Recent progress in water-splitting and supercapacitor electrode materials based on MOF-derived sulfides. JOURNAL OF MATERIALS CHEMISTRY A, v. 10, n. 2, NOV 2021. (13/24725-4, 18/21489-1, 18/16896-7)

Patente(s) depositada(s) como resultado deste projeto de pesquisa