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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Effects of Nanostructure and Dipolar Interactions on Magnetohyperthermia in Iron Oxide Nanoparticles

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Autor(es):
Orozco-Henao, J. M. [1] ; Coral, D. F. [2] ; Muraca, D. [1] ; Moscoso-Londono, O. [1] ; Mendoza Zelis, P. [2] ; Fernandez van Raap, M. B. [2] ; Sharma, S. K. [3] ; Pirota, K. R. [1] ; Knobel, M. [1, 4]
Número total de Autores: 9
Afiliação do(s) autor(es):
[1] Univ Estadual Campinas, Inst Fis Gleb Wataghin, UNICAMP, BR-13083970 Campinas, SP - Brazil
[2] UNLP, Fac Ciencias Exactas, Dept Fis, IFLP, CONICET, CC 67, RA-1900 La Plata, Buenos Aires - Argentina
[3] Univ Fed Maranhao, CCET, Dept Phys, BR-65080805 Sao Luis, Maranhao - Brazil
[4] CNPEM, Lab Nacl Nanotecnol LNNano, Rua Giuseppe Maximo Scolfaro 10000, BR-13083100 Campinas, SP - Brazil
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: Journal of Physical Chemistry C; v. 120, n. 23, p. 12796-12809, JUN 16 2016.
Citações Web of Science: 25
Resumo

Magnetohyperthermia properties of magnetic nanoparticle colloids are strongly affected by their intrinsic magnetic properties and dipolar interactions among themselves. The intrinsic magnetic properties are related to the nanoparticle (NP) size, geometry, phase composition, magnetic anisotropy, and saturation magnetization. The dipole-dipole interactions are determined by colloid nanoparticle concentrations and the possible existence of clustering on the colloidal suspension. Here we have observed that oxygen atmosphere and pressure changes during the final stage of thermal decomposition are critical to modify the size of the iron oxide NPs from 8 to near 20 nm, and consequently their overall magnetic properties. Size-dependent magnetic parameters such as anisotropy, magnetic moment per particle, blocking temperature, and dipolar interaction energy were inferred using different phenomenological approaches. A detailed magnetohyperthermia analysis was performed by applying the linear response theory. A good correlation between experimental and theoretical specific absorption rate values was obtained for a frequency of 260 kHz and applied field of 52 kA/m. These results were observed for the different sizes of nanoparticles, and disagreement between the experimental results and the model increases at lower frequencies. (AU)

Processo FAPESP: 14/26672-8 - Efeitos de interface e superfície em nanoheteroestruturas magnético-metálicas
Beneficiário:Oscar Moscoso Londono
Linha de fomento: Bolsas no Brasil - Pós-Doutorado
Processo FAPESP: 11/01235-6 - Estudo de sistemas granulares magnéticos: efeitos de interações dipolares e de superfície em nanopartículas magnéticas e ferrogel
Beneficiário:Diego Muraca
Linha de fomento: Bolsas no Brasil - Pós-Doutorado