Busca avançada
Ano de início
Entree
(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Evaluation of AgPd Nanoshells in Dual Catalysis: One-Pot Silane Oxidation and Reduction of Organic Compounds

Texto completo
Autor(es):
Kisukuri, Camila M. ; Reis, Joao L. M. S. ; Rodrigues, Thenner S. ; Camargo, Pedro H. C. ; Andrade, Leandro H.
Número total de Autores: 5
Tipo de documento: Artigo Científico
Fonte: CHEMCATCHEM; v. 8, n. 23, p. 3657-3662, DEC 7 2016.
Citações Web of Science: 0
Resumo

AgPd nanoshells (AgPd NSs) were used as dual catalysts for hydrogen production and reduction of organic compounds in a one-pot protocol. AgPd NSs were very efficient catalysts for the reduction of several functional groups, including alkenes, alkynes, imines, nitro compounds, and azides. Excellent chemoselectivities were observed for a, b-unsaturated ketones, esters, and cinnamonitrile. Also, deuterium-labeled compounds were prepared by using D2O instead of H2O. A packed-bed reactor containing the immobilized AgPd NSs in silica (AgPd/SiO2) was designed to be used in continuous-flow conditions. An optimized flow system with AgPd NSs was able to give the desired compounds in high conversions with 30-60 min residence time (tR). (AU)

Processo FAPESP: 14/22457-5 - Desenvolvimento de sistemas biocatalíticos para reações de oxidação e redução
Beneficiário:Leandro Helgueira de Andrade
Linha de fomento: Auxílio à Pesquisa - Regular