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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Mercury Amalgam Diffusion in Human Teeth Probed Using Femtosecond LIBS

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Autor(es):
Bello, Liciane Toledo ; da Ana, Patricia Aparecida ; Santos, Jr., Dario ; Krug, Francisco Jose ; Zezell, Denise Maria ; Vieira, Jr., Nilson Dias ; Samad, Ricardo Elgul
Número total de Autores: 7
Tipo de documento: Artigo Científico
Fonte: Applied Spectroscopy; v. 71, n. 4, p. 659-669, APR 2017.
Citações Web of Science: 3
Resumo

In this work the diffusion of mercury and other elements from amalgam tooth restorations through the surrounding dental tissue (dentin) was evaluated using femtosecond laser-induced breakdown spectroscopy (fs-LIBS). To achieve this, seven deciduous and eight permanent extracted human molar teeth with occlusal amalgam restorations were half-sectioned and analyzed using pulses from a femtosecond laser. The measurements were performed from the amalgam restoration along the amalgam/dentin interface to the apical direction. It was possible to observe the presence of metallic elements (silver, mercury, copper and tin) emission lines, as well as dental constituent ones, providing fingerprints of each material and comparable data for checking the consistence of the results. It was also shown that the elements penetration depth values in each tooth are usually similar and consistent, for both deciduous and permanent teeth, indicating that all the metals diffuse into the dentin by the same mechanism. We propose that this diffusion mechanism is mainly through liquid dragging inside the dentin tubules. The mercury diffused further in permanent teeth than in deciduous teeth, probably due to the longer diffusion times due to the age of the restorations. It was possible to conclude that the proposed femtosecond-LIBS system can detect the presence of metals in the dental tissue, among the tooth constituent elements, and map the distribution of endogenous and exogenous chemical elements, with a spatial resolution that can be brought under 100 mu m. (AU)

Processo FAPESP: 06/06746-0 - Consolidação de metodologia para avaliação dos efeitos da irradiação laser na prevenção da cárie radicular
Beneficiário:Patricia Aparecida da Ana
Linha de fomento: Bolsas no Brasil - Pós-Doutorado
Processo FAPESP: 04/15965-2 - Implantação e desenvolvimento de espectrometria de emissão óptica com plasma induzido por laser
Beneficiário:Francisco José Krug
Linha de fomento: Auxílio à Pesquisa - Temático
Processo FAPESP: 05/51689-2 - Centro de Pesquisa em Óptica e Fotônica - UNICAMP (CEPOF-UNICAMP)
Beneficiário:Hugo Luis Fragnito
Linha de fomento: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs