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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Recoupling dipolar interactions with multiple I=1 quadrupolar nuclei: A B-11[(6)Lil and P-31[Li-6] rotational echo double resonance study of lithium

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Autor(es):
Funke, Lena Marie ; Bradtmueller, Henrik ; Eckert, Hellmut
Número total de Autores: 3
Tipo de documento: Artigo Científico
Fonte: SOLID STATE NUCLEAR MAGNETIC RESONANCE; v. 84, n. SI, p. 143-150, JUL-AUG 2017.
Citações Web of Science: 1
Resumo

The case of rotational echo double resonance (REDOR) experiments on the observe nuclei B-11 and P-31 interacting with multiple I=1 quadrupolar nuclei is analyzed in detail by SIMPSON simulations and experimental studies. The simulations define the region within the parameter space spanned by nutation frequency, quadrupolar coupling constant and spinning frequency where the parabolic analysis of the initial REDOR curve in terms of dipolar second moments has validity. The predictions are tested by experimental studies on the crystalline model compounds lithium diborate and lithium pyrophosphate, which are subsequently extended to measure dipolar second moments M-2[B-11[Li-6]) and M-2[P-31[Li-6]) in three borophosphate glasses. The data indicate that the lithium cations interact significantly more strongly with the phosphate than with the borate species, despite the formally anionic character of four-coordinate boron and the formally neutral character of the ultraphosphate (P-(3)) units to which they are linked. (AU)

Processo FAPESP: 13/07793-6 - CEPIV - Centro de Ensino, Pesquisa e Inovação em Vidros
Beneficiário:Edgar Dutra Zanotto
Linha de fomento: Auxílio à Pesquisa - Centros de Pesquisa, Inovação e Difusão - CEPIDs