Direct dry transfer of CVD graphene to an optical substrate by in situ photo-polymerization

Autor(es)

Kessler, Felipe ^{[1, 2]} ; Munoz, Pablo A. R. ^[1] ; Phelan, Ciaran ^[1] ; Romani, Eric C. ^[3] ; Larrude, Dunieskys R. G. ^[1] ; Freire Junior, Fernando L. ^[3] ; de Souza, Eunezio A. Thoroh ^[1] ; de Matos, Christiano J. S. ^[1] ; Fechine, Guilhermino J. M. ^[1]

Afiliação do(s) autor(es)

^[1] Univ Prebiteriana Mackenzie, MackGraphe Graphene & Nanomat Res Ctr, Sao Paulo - Brazil

^[2] Fed Univ Rio Grande, Lab Appl & Technol Phys Chem, Rio Grande - Brazil

^[3] Pontifical Catholic Univ Rio de Janeiro PUC Rio, Dept Phys, Rio De Janeiro - Brazil

• Tipo de documento: Artigo Científico
• Fonte: Applied Surface Science; v. 440, p. 55-60, MAY 15 2018.
• Citações Web of Science: 3

Resumo

Here, we report on a method that allows graphene produced by chemical vapor deposition (CVD) to be directly transferred to an optically transparent photo resin, by in situ photo-polymerization of the latter, with high efficiency and low contamination. Two photocurable resins, A and B, with different viscosities but essentially the same chemical structure, were used. Raman spectroscopy and surface energy results show that large continuous areas of graphene were transferred with minimal defects to the lower viscosity resin (B), due to the better contact between the resin and graphene. As a proof-of-principle optical experiment, graphene on the polymeric substrate was subjected to high-intensity femtosecond infrared pulses and third-harmonic generation was observed with no noticeable degradation of the sample. A sheet third-order susceptibility chi((3)) = 0.71 x 10(-28) m(3) V-2 was obtained, matching that of graphene on a glass substrate. These results indicate the suitability of the proposed transfer method, and of the photo resin, for the production of nonlinear photonic components and devices. (C) 2018 Elsevier B.V. All rights reserved. (AU)

• Processo FAPESP: 12/50259-8 - Grafeno: fotônica e opto-eletrônica: colaboração UPM-NUS
• Beneficiário: Antonio Helio de Castro Neto
• Linha de fomento: Auxílio à Pesquisa - Programa SPEC
• Processo FAPESP: 15/11779-4 - Efeitos plasmônicos e não-lineares em grafeno acoplado a guias de onda ópticos
• Beneficiário: Christiano José Santiago de Matos
• Linha de fomento: Auxílio à Pesquisa - Temático
• Processo FAPESP: 14/22840-3 - Transferência direta a seco de grafeno-CVD para substratos poliméricos bidimensionais e tridimensionais
• Beneficiário: Guilhermino José Macêdo Fechine
• Linha de fomento: Auxílio à Pesquisa - Regular
• Processo FAPESP: 15/12734-4 - Design, fabricação e caracterização dos guias de onda ópticos para excitação plasmônica em grafeno
• Beneficiário: Ciaran Phelan
• Linha de fomento: Bolsas no Brasil - Pós-Doutorado
• Processo FAPESP: 15/16591-3 - Geração de pulsos ultracurtos em lasers Raman com modos acoplados por absorvedores saturáveis de grafeno
• Beneficiário: Pablo Andrés Riveros Muñoz
• Linha de fomento: Bolsas no Brasil - Pós-Doutorado