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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Synthesis of Chelating Agent Free-Solid Phase Extractor (CAF-SPE) Based on New SiO2/Al2O3/SnO2 Ternary Oxide and Application for Online Preconcentration of Pb2+ Coupled with FAAS

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Autor(es):
Tarley, Cesar R. T. [1, 2] ; Scheel, Guilherme L. [1] ; Ribeiro, Emerson S. [3, 4] ; Zappielo, Caroline D. [1] ; Suquila, Fabio A. C. [1]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] Univ Estadual Londrina, Dept Quim, BR-86051990 Londrina, PR - Brazil
[2] Univ Estadual Campinas, Inst Nacl Ciencia & Tecnol INCT Bioanalit, Dept Quim Analit, Inst Quim, UNICAMP, Campinas, SP - Brazil
[3] Univ Fed Rio de Janeiro, UFRJ, Inst Quim, Grp LaDANM, BR-21941909 Rio De Janeiro, RJ - Brazil
[4] Univ Estadual Paulista, Unesp, Inst Nacl Tecnol Alternat Deteccao Avaliacao Toxi, Inst Quim, CP 355, BR-14800900 Araraquara, SP - Brazil
Número total de Afiliações: 4
Tipo de documento: Artigo Científico
Fonte: Journal of the Brazilian Chemical Society; v. 29, n. 6, p. 1225-1236, JUN 2018.
Citações Web of Science: 2
Resumo

A new online solid phase preconcentration method using the new SiO2/Al2O3/SnO2 ternary oxide (designated as SiAlSn) as chelating agent free-solid phase extractor (CAF-SPE) coupled to flame atomic absorption spectrometry (FAAS) for Pb2+ determination at trace levels in different kind of samples is proposed. The solid adsorbent has been characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron miscroscopy (SEM). energy dispersive X-ray spectroscopy (EDS). X-ray fluorescence spectroscopy (XRF) and textural data. The method involves the preconcentration using time-based sampling of Pb2+ solution at pH 4.3 through 100.0 mg of packed adsorbed into a mini-column under flow rate of 4.0 mL min(-1) during 5 min. The elution step was accomplished by using 1.0 mol L-1 HCl. A wide range of analytical curve (5.0-400.0 mu g L-1). high enrichment factor (40.5), low consumption index (0.5 ml.) and low limits of quantification and detection, 5.0 and 1.5 mu g L-1, respectively, were obtained with the developed method. Practical application of method was tested on water samples, chocolate powder, Ginkgo biloba and sediment (certified reference material). On the basis of the results, the SiAlSn can be considered an effective adsorbent belonging to the class of CAF-SPE for Pb2+ determination from different matrices. (AU)

Processo FAPESP: 14/50867-3 - INCT 2014: Instituto Nacional de Ciência e Tecnologia de Bioanalítica
Beneficiário:Lauro Tatsuo Kubota
Linha de fomento: Auxílio à Pesquisa - Temático