| Texto completo | |
| Autor(es): |
Sanches de Menezes, Davi Eber
[1]
;
Ralha, Thiago Waldowski
[1]
;
Mercier Franco, Luis Fernando
[2, 1]
;
Pessoa Filho, Pedro de Alcantara
[1]
;
Robustillo Fuentes, Maria Dolores
[1]
Número total de Autores: 5
|
| Afiliação do(s) autor(es): | [1] Univ Sao Paulo, Engn Sch, Dept Chem Engn, BR-05424970 Sao Paulo, SP - Brazil
[2] Univ Estadual Campinas, Sch Chem Engn, BR-13083852 Campinas, SP - Brazil
Número total de Afiliações: 2
|
| Tipo de documento: | Artigo Científico |
| Fonte: | Brazilian Journal of Chemical Engineering; v. 35, n. 2, p. 403-414, APR-JUN 2018. |
| Citações Web of Science: | 3 |
| Resumo | |
Binary and ternary systems composed of methane-water and methane-propane-water, respectively, were studied using high pressure differential scanning calorimetry. The methodology was validated by comparing results for the binary system to experimental data obtained in the literature. The hydrate dissociation temperatures for the ternary system (methane-propane-water) at 21 MPa were experimentally determined for different compositions of the gas mixture and mole fractions of propane higher than 0.1 in the ternary system. Our results are in good agreement with the values predicted by applying the Cubic Plus Association (CPA) equation of state coupled with van der Waals-Platteeuw model for the hydrate phase. Although experimental results are considered satisfactory for both binary and ternary systems, higher deviations between our values and the simulated ones for the ternary system, considering peak temperature instead of the extrapolated onset as the hydrate dissociation temperature, are believed to be a consequence of dynamic effects that promote the formation of a heterogeneous hydrate and are negligible for the binary system. (AU) | |
| Processo FAPESP: | 14/25740-0 - Estudo da formação e dissociação de hidratos de gás em altas pressões |
| Beneficiário: | Maria Dolores Robustillo Fuentes |
| Linha de fomento: | Bolsas no Brasil - Jovens Pesquisadores |
| Processo FAPESP: | 15/23148-9 - Estudo termodinâmico da formação e dissociação de hidratos de gás |
| Beneficiário: | Davi Éber Sanches de Menezes |
| Linha de fomento: | Bolsas no Brasil - Doutorado Direto |
| Processo FAPESP: | 14/02140-7 - Estudo da formação e dissociação de hidratos de gás |
| Beneficiário: | Maria Dolores Robustillo Fuentes |
| Linha de fomento: | Auxílio à Pesquisa - Jovens Pesquisadores |