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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Reprocessing and Solid State Polymerization on Contaminated Post-consumer PET: Thermal and Crystallization Behavior

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Autor(es):
Fitaroni, Lays B. [1] ; de Oliveira, Eder C. [1] ; Marcomini, Andre L. [2] ; Paranhos, Caio M. [3] ; Freitas, Flavia L. [1] ; Cruz, Sandra A. [3]
Número total de Autores: 6
Afiliação do(s) autor(es):
[1] Fed Univ ABC, Ave Estados 5001, Santo Andre, SP - Brazil
[2] Univ Fed Sao Carlos, Dept Mat Engn, Rodovia Washington Luis, Km 235, SP-310, Sao Carlos, SP - Brazil
[3] Univ Fed Sao Carlos, Dept Chem, Rodovia Washington Luis, Km 235, SP-310, Sao Carlos, SP - Brazil
Número total de Afiliações: 3
Tipo de documento: Artigo Científico
Fonte: JOURNAL OF POLYMERS AND THE ENVIRONMENT; OCT 2019.
Citações Web of Science: 0
Resumo

This investigation deals with the exposition of poly (ethylene terephthalate) to a series of surrogates following protocol recommended by United States Food and Drugs Administration. The samples presented different molecular characteristics associated to the type of process, such as reprocessing by extrusion and solid state polymerization (SSP). The nonisothermal, quiescent and shear flow crystallization for these samples were studied using differential scanning calorimetry, polarized light optical microscopy and rheometry technique. The quiescent results show that the higher the molar mass, the slower is the rate of the crystallization process. The samples that undergone the SSP process do not have influence with the presence of contaminants as this process results in higher level of decontamination. The shear-induced crystallization show that the presence of contaminants significantly reduces the number of entanglements, increasing mobility of the chains and thus the entropy of the system. Despite the significant change in the crystallization behavior, the results of the nonisothermal analysis corroborate the effects of the contamination, recycling and SSP processes on the crystalline nature of PET. The evaluation of the crystallization characteristics, especially in non-quiescent conditions, is extremely important for the prediction of the physicochemical properties and can modify the processing characteristics and the final applicability. (AU)

Processo FAPESP: 13/21272-9 - Reciclagem de PET pós-consumo: avaliação da degradação na presença de contaminantes
Beneficiário:Sandra Andrea Cruz
Linha de fomento: Auxílio à Pesquisa - Regular