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(Referência obtida automaticamente do Web of Science, por meio da informação sobre o financiamento pela FAPESP e o número do processo correspondente, incluída na publicação pelos autores.)

Spectroscopic characterization of cadion: UVvis, resonance Raman and DFT calculations of a versatile metal complexing agent

Texto completo
Autor(es):
Lepre, Luiz F. [1] ; Inoue, Fabiana [1] ; Corio, Paola [1] ; Santos, Paulo S. [1] ; Ando, Romulo A. [1]
Número total de Autores: 5
Afiliação do(s) autor(es):
[1] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Lab Espect Mol, BR-05508000 Sao Paulo - Brazil
Número total de Afiliações: 1
Tipo de documento: Artigo Científico
Fonte: Journal of Raman Spectroscopy; v. 44, n. 4, p. 567-572, APR 2013.
Citações Web of Science: 1
Resumo

The spectroscopic characterization of cadion or 1-(4-nitrophenyl)-3-(4-phenylazophenyl)triazene, its anionic species and its complexes with Hg2+, Cd2+ and Ni2+ in DMSO solution is presented. Resonance Raman (RR) and UVvis spectroscopy were the techniques of choice with results supported by density functional theory calculations. As previously reported, the UVvis data indicate distinct absorption spectra for the five species mentioned, allowing for spectrophotometric metal differentiation. In order to understand the electronic spectra of such species, we performed a detailed RR investigation, where the spectral profiles revealed the vibrational modes mainly involved in the chromophoric moieties. The distinct enhancement profile observed for each species suggests that the charge transfer from the -system to the electron withdrawing NO2 group is modulated by the electron donating triazene moiety, depending on the metal attached. The results reported herein show that RR spectroscopy can be potentially used in the metal detection of multicomponent samples by the proper choice of the excitation wavelength. Copyright (c) 2012 John Wiley \& Sons, Ltd. (AU)

Processo FAPESP: 11/22263-8 - Absorção de CO2 por líquidos iônicos
Beneficiário:Rômulo Augusto Ando
Linha de fomento: Auxílio à Pesquisa - Regular
Processo FAPESP: 06/58748-7 - Reatividade, dinâmica e espectroscopia de sistemas complexos
Beneficiário:Marcia Laudelina Arruda Temperini
Linha de fomento: Auxílio à Pesquisa - Temático