| Texto completo | |
| Autor(es): |
De Jesus, Jessica C.
;
Noguchi, Henrique K.
;
Toledo, Monica F. Z. J.
;
Burrow, Robert A.
;
Pimenta, Daniel C.
;
Stefani, Helio A.
Número total de Autores: 6
|
| Tipo de documento: | Artigo Científico |
| Fonte: | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY; v. 2022, n. 30, p. 7-pg., 2022-08-12. |
| Resumo | |
Glycal amides were prepared for the first time by reacting 2-iodo-D-glycals with L-amino acid esters via a Pd-catalyzed carbonylative cross-coupling reaction, by using Mo(CO)(6) as the carbon monoxide source. Glycal amides were synthesized in moderate to good yields under our optimized conditions. In addition, the acetyl groups of the glucal amides could be readily removed to obtain the corresponding trihydroxy derivatives in good yields. (AU) | |
| Processo FAPESP: | 20/00295-4 - Funcionalização de D-glucal e análogos via reação de acoplamento carbonbilativo |
| Beneficiário: | Helio Alexandre Stefani |
| Modalidade de apoio: | Auxílio à Pesquisa - Regular |