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High Temperature FeB-type Phases in the Systems Ta-{Ti, Zr, Hf}-B

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Autor(es):
Failamani, F. ; Goschl, K. ; Reisinger, G. ; Nunes, C. A. ; Coelho, G. C. ; Machado, A. J. S. ; Correa, L. E. ; dosSantos, J. C. P. ; Giester, G. ; Rogl, P.
Número total de Autores: 10
Tipo de documento: Artigo Científico
Fonte: JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION; v. 36, n. 6, p. 12-pg., 2015-12-01.
Resumo

Novel FeB-type phases have been evaluated in the systems Ta-{Ti, Zr, Hf}-B either from as cast or arc treated samples by x-ray powder and single crystal diffraction as well as electron probe microanalysis. In each of the three systems the formation of the FeB-type phase suggests a high temperature stabilization of a binary group IV metal monoboride with FeB-type. This holds true for Ti and Hf, while for Zr the single crystal study of (Ta,Zr)B proves that it is a true ternary phase, as no stable monoboride exists in the binary Zr-B system. EPMA analyses reveal that the FeB-type phases Ta{Ti, Zr, Hf} B are formed by substitution of Ta in TaB by rather small amounts of group IV elements (similar to 3 at.% of Zr, similar to 7 at.% Hf, and similar to 10 at.% Ti). (AU)

Processo FAPESP: 97/06348-4 - Estudo de estabilidade de fases em ligas Nb-B-Si ricas em Nb
Beneficiário:Carlos Angelo Nunes
Modalidade de apoio: Auxílio à Pesquisa - Jovens Pesquisadores