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The performance of Pt nanoparticles supported on Sb(2)O(5 center dot)Sno(2), on carbon and on physical mixtures of Sb2O5 center dot SnO2 and carbon for ethanol electro-oxidation

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Autor(es):
Oliveira Neto, A. ; Brandalise, M. ; Dias, R. R. ; Ayoub, J. M. S. ; Silva, A. C. ; Penteado, J. C. ; Linardi, M. ; Spinace, E. V.
Número total de Autores: 8
Tipo de documento: Artigo Científico
Fonte: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY; v. 35, n. 17, p. 5-pg., 2010-09-01.
Resumo

Pt nanoparticles were supported on Sb2O5 center dot SnO2 (ATO), on carbon and on physical mixtures of ATO and carbon by an alcohol-reduction process using ethylene glycol as reducing agent. The obtained materials were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Their performance for ethanol oxidation was investigated at room temperature by chronoamperometry and in a direct ethanol fuel cell (DEFC) at 100 degrees C. Pt nanoparticles supported on a physical mixture of ATO and carbon showed a significant increase of performance for ethanol oxidation compared to Pt nanoparticles supported on ATO or on carbon. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved. (AU)

Processo FAPESP: 07/07898-1 - Preparação e caracterização de sistemas PtRu/C + Terras Raras e PtSn/C + Terras Raras para emprego em células a combustível do tipo eletrólito polimérico sólido alimentadas diretamente por etanol
Beneficiário:Almir Oliveira Neto
Modalidade de apoio: Auxílio à Pesquisa - Regular