Optimization of Biomass Circulating Fluidized Bed Gasifier for Synthesis Applications using Simulation and Response Surface Methodology

Autor(es)

Motta, Ingrid L. ; Marchesan, Andressa N. ; Maciel Filho, Rubens ; Wolf Maciel, Maria Regina ; Pierucci, S ; Manenti, F ; Bozzano, GL ; Manca, D

• Tipo de documento: Artigo Científico
• Fonte: 30TH EUROPEAN SYMPOSIUM ON COMPUTER AIDED PROCESS ENGINEERING, PTS A-C; v. 48, p. 6-pg., 2020-01-01.

Resumo

Biomass gasification is a complex process that uses heat and catalysts to convert biomass into syngas, which can be applied in Fischer-Tropsch (FT) synthesis to produce liquid fuels. As FT requires specific syngas compositions, this work performs an optimization of the operating conditions of a pressurized circulating fluidized bed (CFB) gasifier for such purposes. The CFB operated with sugarcane bagasse as a feedstock and steam as a gasifying agent and was simulated in Aspen Plus v8.6 based on Gibbs free energy minimization with restricted equilibrium. The optimization followed the response surface methodology (RSM), consisting of central composite designs performed in Statistica 7.0 at a 99.0 % confidence level to obtain simplified mathematical models between input factors (temperature, T; steam-to-biomass ratio, S/B; and moisture content, MC) and output factors (cold gas efficiency, CGE; H-2/CO ratio; gasifier heat duty, Q(gasifier); higher heating value, HHV; and H-2, CO, CO2, and CH4 contents). The models were used to generate four optimized cases of pressurized CFBs that returned H-2/CO ratios of 2.15, required for FT reactors. The optimized CFB operates at 916 degrees C, 15 bar, S/B of 1.12, and 10 wt.% moisture, generating a syngas stream of low CO2 and CH4 contents, which may reduce the syngas cleaning and conditioning costs downstream the gasifier. The results agree with optimizations using other feedstocks and sets of objectives, showing the validity of the models. (AU)

• Processo FAPESP: 15/20630-4 - Desenvolvimento integrado de biorrefinaria e planta de bioetanol de cana-de-açúcar com emissão zero de CO2: rotas para converter recursos renováveis em bioprodutos e bioeletricidade
• Beneficiário: Rubens Maciel Filho
• Modalidade de apoio: Auxílio à Pesquisa - Temático