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Electrochemical system of nitrogen-doped TiO2, Fe-N-C, and copper hexacyanoferrate electrodes for photo-assisted energy conversion in acidic wastewater treatment

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Autor(es):
Ferreira, Bianca Taina ; Martins, Matheus ; Huguenin, Fritz
Número total de Autores: 3
Tipo de documento: Artigo Científico
Fonte: Physical Chemistry Chemical Physics; v. 26, n. 43, p. 12-pg., 2024-10-21.
Resumo

This study explores the electrochemical behavior of nitrogen-doped TiO2 (TiO2-yNy), iron-nitrogen-carbon (Fe-N-C), and copper hexacyanoferrate (CuHCF) electrodes for energy conversion during acidic solution neutralization under visible light. The materials were characterized for particle size, morphology, and structural properties. Time and frequency domain models were applied to determine kinetic parameters and propose reaction mechanisms. Fe-N-C electrodes demonstrated catalytic activity through both direct 4-electron reduction and hydrogen peroxide formation during the oxygen reduction reaction in acidic solution. Nitrogen doping extended the absorption range of TiO2 to visible light, enabling photoelectrooxidation at low potentials and improving energy conversion efficiency. The CuHCF electrode demonstrated low charge transfer resistance associated with sodium ion insertion/deinsertion, with sufficient ionic mobility to ensure minimal energy loss. This characteristic is essential for the integration of half-reactions in full cells operating in acidic and neutral electrolytes. Under the employed experimental conditions, 62.9 kJ per mole of protons produced or consumed was captured after the first cycle. These findings emphasize the potential of these materials for enhanced, sustainable energy harvesting in acid wastewater treatment. (AU)

Processo FAPESP: 17/11986-5 - Geração e Armazenamento de Novas Energias: trazendo desenvolvimento tecnológico para o país
Beneficiário:Ana Flávia Nogueira
Modalidade de apoio: Auxílio à Pesquisa - Programa Centros de Pesquisa em Engenharia
Processo FAPESP: 21/12735-1 - Sistemas fotoeletroquímicos de dessalinização sob fluxo contínuo
Beneficiário:Fritz Cavalcante Huguenin
Modalidade de apoio: Auxílio à Pesquisa - Regular